摘要:
There is disclosed herein an additive composition including a compound of formula (III): wherein R1, R2, R3, R4, R5, R6 , R7, R8, and R9are independently selected from the group consisting of hydrogen, cyano, and hydrocarbyl groups comprising from about 1 to about 30 carbon atoms.
摘要:
The present disclosure relates to a non-acidic, sulfur-containing, phosphorus-containing compound of the formula I where R1, R2, R3, R4, R5, R6, and R7 are as defined herein. Such a compound may exhibit improved antiwear performance and thermal stability in lubricating compositions.
摘要:
Polybutenyl substituted succinic acylating agents are formed by reacting (a) an acidic reactant represented by the general formulaR--CO--CH.dbd.CH--CO--R'wherein R and R' are independently --OH, --O-lower alkyl, a halogen atom, or taken together are a single oxygen atom, with (b) a polymer composed mainly or entirely of polyisobutene, at least 50% of the polyisobutene content of the polymer having an end group represented by the formula ##STR1## The mole ratio of acidic reactant:polymer is at least 1:1; and the reaction mixture is maintained under superatmospheric pressure during at least a substantial portion of the reaction period. The reaction rate is high, the yields of desired product are high, and despite the fact that superatmospheric pressures and elevated temperatures are used, the process forms only small amounts of tars or resinous co-products, even when employing as much as a 20% or more molar excess of maleic anhydride. Any unreacted acidic reactant such as maleic anhydride, maleic acid, fumaric acid, etc, can be, and preferably is, recovered from the reaction mixture, and thus is available for use either as recycle to the process or for other uses. Inasmuch as chlorine is not used in the process, the expense and difficulties associated with handling chlorine on a plant scale are eliminated, and the product is less corrosive than corresponding products formed by use of chlorine.
摘要:
Succinimides, succinic esters, and succinic ester-amides are formed by(A) reacting (i) at least one substantially aliphatic polymer of at least one lower olefin, and (ii) an acidic reactant or a mixture of two or more acidic reactants represented by the general formulaR--CO--CH.dbd.CH--CO--R' wherein R and R' are independently --OH, --O-lower alkyl, a halogen atom, or taken together are a single oxygen atom; the process being characterized in that:a) the substantially aliphatic polymer is comprised predominantly or entirely of polyisobutene, at least 50% of the polyisobutene content of such polymer having an end group represented by the formula ##STR1## b) the mole ratio of said acidic reactant(s): said polymer(s) is at least 1:1;c) the reaction mixture is maintained under superatomospheric pressure during at least a substantial portion of the reaction period; andd) said acylating agent is characterized by having an average total tar rating as determined by the method described in the specification hereof that is at least 25% lower than the average total tar rating of a corresponding product made in the same way under the same reaction conditions using a polyisobutene containing up to 10% of the above-depicted end group; and(B) reacting such acylating agent with at least one alcohol (preferably a polyhydric alcohol) or amine (preferably a polyamine having at least one primary amino group).
摘要:
Sulfurized olefins such as isobutylene which are soluble in hydrotreated oils are prepared by reacting a basic, aqueous alcoholic solution of sodium sulfide with an adduct formed by adding olefin to sulfur monochloride at low temperatures until the mole ratio of olefin to sulfur monochloride is between about 1.7-1.9 to 1.