摘要:
The invention relates to a fire resistant composition and a method of making fire resistant cellulosic materials comprising the fire resistant composition. More specifically, the invention relates to liquid compositions, including liquid compositions comprising urea and a boron-containing compound for imparting fire resistance to cellulosic products. The boron-containing compound typically comprises boric acids; borates (i.e., boric acid salts); boric oxides (i.e., any compound containing boron and oxygen), and mixtures thereof.
摘要:
A family of borate compounds containing an isolated (finite) nonaborate anion with the structural formula [B9O12(OH)6]3−. Preferred amine nonaborate compounds have a resolved oxide formula of A2O.3B2O3.2H2O, where A is the monovalent cation of an amine salt, such as guanidinium and imidazolium. Also provided is a method for preparing these compounds by crystallization from an aqueous solution under mild conditions without the formation of significant amounts of by-products. These compounds have potential application as precursors for the production of advanced boron nitride ceramic materials, and as flame retardants, corrosion inhibitors, and biocides.
摘要翻译:一种硼酸盐化合物,其含有具有结构式[B 9] 12(OH)6]的分离(有限)非硼酸阴离子 > 3 - SUP>。 优选的胺非硼酸化合物具有分解的氧化物分子式为A 2 O 3 B 2 O 3 N 2 O 2 B 2 O 2 其中A是胺盐的一价阳离子,例如胍和咪唑鎓。 还提供了一种通过在温和条件下从水溶液中结晶而制备这些化合物而不形成大量副产物的方法。 这些化合物可用作生产先进的氮化硼陶瓷材料以及作为阻燃剂,腐蚀抑制剂和杀生物剂的前体。
摘要:
The invention relates to a fire resistant composition and a method of making fire resistant cellulosic materials comprising the fire resistant composition. More specifically, the invention relates to liquid compositions, including liquid compositions comprising urea and a boron -containing compound for imparting fire resistance to cellulosic products. The boron-containing compound typically comprises boric acids; borates (i.e., boric acid salts); boric oxides (i.e., any compound containing boron and oxygen), and mixtures thereof.
摘要:
Systems and methods are provided for treating products containing wood fibers to provide protection against wood destroying organisms and fire, and resistance against leaching of the preservative from the wood by water in exposed environments such as exterior applications. The methods involve applying to a substrate a first aqueous composition containing a boron compound, a source of zinc, and ammonia, followed by application of a second aqueous composition containing an alkali metal silicate. The compositions may be applied by vacuum and/or pressure treatment or dip treatment under atmospheric pressure.
摘要:
An improved method is provided for producing crystalline calcium hexaborate tetrahydrate, synthetic nobleite, by the reaction of boric acid and lime in an aqueous slurry. Reaction conditions include boric acid to water molar ratios of greater than 0.25:1, lime to boric acid molar ratios in the range of 0.05-0.15:1 and temperatures in the range of 60.degree.-85.degree. C. A concentration of at least 25% by weight undissolved solids is in the aqueous product slurry.
摘要:
An improved method is provided for producing crystalline calcium hexaborate tetrahydrate, synthetic nobleite, by the reaction of boric acid and lime in an aqueous slurry. Reaction conditions include boric acid to water molar ratios of greater than 0.25:1, lime to boric acid molar ratios in the range of 0.05-0.15:1 and temperatures in the range of 85.degree.-105.degree. C. A novel crystalline product is produced having a unique crystal habit resulting in improved physical properties. Dehydration of this product produced a novel amorphous, anhydrous product having similar crystal habit and physical properties.
摘要:
Zinc borate compositions having a ZnO:B.sub.2 O.sub.3 ratio of 4:1. The hydrated zinc borate 4ZnO.B.sub.2 O.sub.3.H.sub.2 O and anhydrous zinc borate 4ZnO.B.sub.2 O.sub.3 are especially useful as fire-retardants and smoke-suppressant additives for polymeric compositions.
摘要:
Compositions and methods are provided for treating wood products to provide leach-resistant protection against fungal decay, termites and other wood destroying organisms. The preservative compositions provided include ammonia-stabilized solutions of zinc and boron, preferably in a molar ratio of Zn:B of between about 0.4:1 and 5:1, and are essentially copper free. The preservative may be applied by vacuum and/or pressure treatment or dip treatment under atmospheric pressure.
摘要:
A method for inhibiting the crystallization of boric acid is provided. Boric acid is dissolved in water and a vitrifying agent, such as an amino alcohol or amino acid, to form an aqueous mixture which is then dried to form a vitreous boric acid-containing residue. This mixture, when applied to a surface and allowed to dry on the surface, forms a vitreous boric acid-containing coating which is readily adherent to the surface, or if allowed to penetrate into a porous substrate, deposits a vitreous boric acid-containing residue within the substrate upon drying. The vitreous boric acid-containing residue provides beneficial properties, including for example improved fire retardancy and biocidal protection, to a variety of materials such as cotton batting, cellulose, and wood and paper products and gypsum wallboard.
摘要:
Compositions and methods are provided for treating wood products to provide leachresistant protection against fungal decay, termites and other wood destroying organisms. The preservative compositions provided include ammonia-stabilized solutions of zinc and boron, preferably in a molar ratio of Zn:B of between about 0.4:1 and 5:1, and are essentially copper free. The preservative may be applied by vacuum and/or pressure treatment or dip treatment under atmospheric pressure.