公开(公告)号：US06503574B1

公开(公告)日：2003-01-07

申请号：US08362050

申请日：1994-12-22

申请人： David William Skelly ,  Bangalore Aswatha Nagaraj ,  David John Wortman ,  David Vincent Rigney ,  Seetha Ramaiah Mannava ,  Rudolfo Viguie ,  Robert William Bruce ,  Warren Arthur Nelson ,  Curtis Alan Johnson ,  Bhupendra Kumar Gupta

发明人： David William Skelly ,  Bangalore Aswatha Nagaraj ,  David John Wortman ,  David Vincent Rigney ,  Seetha Ramaiah Mannava ,  Rudolfo Viguie ,  Robert William Bruce ,  Warren Arthur Nelson ,  Curtis Alan Johnson ,  Bhupendra Kumar Gupta

IPC分类号： B32B904

CPC分类号： F01D5/288 ,  C23C4/02 ,  Y02T50/67 ,  Y02T50/671 ,  Y10T428/12472 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/12993 ,  Y10T428/24521 ,  Y10T428/24545 ,  Y10T428/24612

摘要： An article having a substrate is protected by a thermal barrier coating system. An interfacial layer contacts the upper surface of the substrate. The interfacial layer may comprise a bond coat only, or a bond coat and an overlay coat. The interfacial layer has on its upper surface a preselected, controllable pattern of three-dimensional features, such as grooves in a parallel array or in two angularly offset arrays. The features are formed by an ablation process using an ultraviolet laser such as an excimer laser. A ceramic thermal barrier coating is deposited over the pattern of features on the upper surface of the interfacial layer.

摘要翻译： 具有基底的制品由热障涂层系统保护。 界面层接触基板的上表面。 界面层可以仅包含粘结层，或者粘合涂层和覆盖层。 界面层在其上表面上具有三维特征的预选的可控模式，例如平行排列的凹槽或两个角度偏移的阵列。 特征通过使用诸如准分子激光器的紫外激光的消融处理形成。 陶瓷热障涂层沉积在界面层上表面上的特征图案上。

公开(公告)号：US06589351B1

公开(公告)日：2003-07-08

申请号：US09624808

申请日：2000-07-24

申请人： Robert William Bruce ,  Antonio Frank Maricocchi ,  John Douglas Evans, Sr. ,  Rudolfo Viguie ,  David Vincent Rigney ,  David John Wortman ,  William Seth Willen

发明人： Robert William Bruce ,  Antonio Frank Maricocchi ,  John Douglas Evans, Sr. ,  Rudolfo Viguie ,  David Vincent Rigney ,  David John Wortman ,  William Seth Willen

IPC分类号： C23C1600

CPC分类号： C23C14/30 ,  C23C14/246 ,  C23C14/56 ,  C23C14/564

摘要： An electron beam physical vapor deposition (EBPVD) apparatus and a method for using the apparatus to produce a coating material (e.g., a ceramic thermal barrier coating) on an article. The EBPVD apparatus generally includes a coating chamber that is operable at elevated temperatures and subatmospheric pressures. An electron beam gun projects an electron beam into the coating chamber and onto a coating material within the chamber, causing the coating material to melt and evaporate. An article is supported within the coating chamber so that vapors of the coating material deposit on the article. The operation of the EBPVD apparatus is enhanced by the inclusion of a crucible that supports the coating material and is configured to be efficiently cooled so as to reduce the rate at which the process temperature increases within the coating chamber.

摘要翻译： 电子束物理气相沉积（EBPVD）装置和使用该装置在制品上制备涂层材料（例如，陶瓷热障涂层）的方法。 EBPVD设备通常包括可在升高的温度和低于大气压的压力下操作的涂覆室。 电子束枪将电子束投射到涂层室中并且涂覆在腔室内的涂层材料上，导致涂层材料熔化和蒸发。 在涂层室内支撑制品，使得涂层材料的蒸气沉积在制品上。 通过包括支撑涂层材料的坩埚来增强EBPVD装置的操作，并且被配置为被有效地冷却，以便降低涂覆室内工艺温度升高的速度。

公开(公告)号：US06863937B2

公开(公告)日：2005-03-08

申请号：US10299646

申请日：2002-11-19

申请人： Robert William Bruce ,  Antonio Frank Maricocchi ,  Christopher Lee Lagemann ,  John Douglas Evans, Sr. ,  Keith Humphries Betscher ,  Rudolfo Viguie ,  David Vincent Rigney ,  David John Wortman ,  William Seth Willen

发明人： Robert William Bruce ,  Antonio Frank Maricocchi ,  Christopher Lee Lagemann ,  John Douglas Evans, Sr. ,  Keith Humphries Betscher ,  Rudolfo Viguie ,  David Vincent Rigney ,  David John Wortman ,  William Seth Willen

IPC分类号： F02C7/00 ,  C23C14/24 ,  C23C14/30 ,  C23C14/52 ,  C23C14/54 ,  C23C14/56 ,  H01J37/305

CPC分类号： C23C14/246 ,  C23C14/30 ,  C23C14/52 ,  C23C14/541 ,  C23C14/56 ,  H01J37/3053 ,  H01J2237/3132

摘要： An electron beam physical vapor deposition (EBPVD) apparatus and a method for using the apparatus to produce a coating material (e.g., a ceramic thermal barrier coating) on an article. The EBPVD apparatus generally includes a coating chamber that is operable at elevated temperatures and subatmospheric pressures. An electron beam gun projects an electron beam into the coating chamber and onto a coating material within the chamber, causing the coating material to melt and evaporate. An article is supported within the coating chamber so that vapors of the coating material deposit on the article. The operation of the EBPVD apparatus is enhanced by the inclusion or adaptation of one or more mechanical and/or process modifications, including those necessary or beneficial when operating the apparatus at coating pressures above 0.010 mbar.

摘要翻译： 电子束物理气相沉积（EBPVD）装置和使用该装置在制品上制备涂层材料（例如，陶瓷热障涂层）的方法。 EBPVD设备通常包括可在升高的温度和低于大气压的压力下操作的涂覆室。 电子束枪将电子束投射到涂层室中并且涂覆在腔室内的涂层材料上，导致涂层材料熔化和蒸发。 在涂层室内支撑制品，使得涂层材料的蒸气沉积在制品上。 EBPVD装置的操作通过包含或适应一种或多种机械和/或工艺改进而得到增强，包括在涂覆压力高于0.010mbar的条件下操作设备时必需或有益的修改。

公开(公告)号：US06946034B1

公开(公告)日：2005-09-20

申请号：US10643262

申请日：2003-08-19

申请人： Robert William Bruce ,  Antonio Frank Maricocchi ,  Christopher Lee Lagemann ,  John Douglas Evans, Sr. ,  Keith Humphries Betscher ,  Rudolfo Viguie ,  David Vincent Rigney ,  David John Wortman ,  William Seth Willen

发明人： Robert William Bruce ,  Antonio Frank Maricocchi ,  Christopher Lee Lagemann ,  John Douglas Evans, Sr. ,  Keith Humphries Betscher ,  Rudolfo Viguie ,  David Vincent Rigney ,  David John Wortman ,  William Seth Willen

IPC分类号： C23C14/00 ,  C23C14/24 ,  C23C14/30 ,  C23C14/52 ,  C23C14/54 ,  C23C14/56 ,  H01J37/305

CPC分类号： C23C14/52 ,  C23C14/246 ,  C23C14/30 ,  C23C14/541 ,  C23C14/56 ,  H01J37/3053

摘要： An electron beam physical vapor deposition (EBPVD) apparatus for producing a coating material (e.g., a ceramic thermal barrier coating) on an article. The EBPVD apparatus generally includes a coating chamber that is operable at elevated temperatures and subatmospheric pressures. An electron beam gun projects an electron beam into the coating chamber through an aperture in a wall of the chamber and onto a coating material within a coating region defined within the chamber, causing the coating material to melt and evaporate. An article is supported within the coating chamber so that vapors of the coating material deposit on the article. The operation of the EBPVD apparatus is enhanced by the inclusion within the coating chamber of a second chamber that encloses the aperture so as to separate the aperture from the coating region. The second chamber is maintained at a pressure lower than the coating region.

摘要翻译： 一种用于在制品上生产涂层材料（例如，陶瓷热障涂层）的电子束物理气相沉积（EBPVD）装置。 EBPVD设备通常包括可在升高的温度和低于大气压的压力下操作的涂覆室。 电子束枪将电子束通过腔室的孔中的电子束投射到涂覆室中，并且覆盖在腔室内限定的涂层区域内的涂层材料上，导致涂层材料熔化和蒸发。 在涂层室内支撑制品，使得涂层材料的蒸气沉积在制品上。 EBPVD装置的操作通过包围在包围孔的第二腔室的涂覆室内以便将孔与涂覆区域分开来增强。 第二室保持在比涂覆区域低的压力。

公开(公告)号：US20090162692A1

公开(公告)日：2009-06-25

申请号：US11963993

申请日：2007-12-24

申请人： Bangalore Aswatha Nagaraj ,  David John Wortman ,  Nicole Marie Polley ,  William Bryan Connor ,  Roger Dale Wustman

发明人： Bangalore Aswatha Nagaraj ,  David John Wortman ,  Nicole Marie Polley ,  William Bryan Connor ,  Roger Dale Wustman

IPC分类号： B32B15/01

CPC分类号： B32B15/01 ,  C22C19/05 ,  C22C19/057 ,  C23C4/073 ,  C23C4/134 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/3455 ,  F05B2230/312 ,  F05B2230/90 ,  Y02T50/67 ,  Y02T50/6765 ,  Y10T428/12944

摘要： Coated superalloy article includes a bond coat comprising an inner bond coat layer disposed on the first surface being formed by deposition of a bond coat composition comprising, in weight percent, 14-20% Cr, 5-8% Al, 8-12% Co, 3-7% Ta, 0.1-0.6% Hf, 0.1-0.5% Y, up to about 1% Si, 0.005-0.020% Zr, 0.04-0.08% C, 0.01-0.02% B, with a remainder including nickel (Ni) and incidental impurities, wherein the bond coating composition is substantially free of rhenium. An aluminum-containing layer overlies the inner bond coat layer. Optionally, a thermal barrier coating overlies the aluminum-containing layer, wherein the thermal barrier coating, if present, is formed by deposition of a thermal barrier coating composition.

摘要翻译： 涂覆的超合金制品包括粘合涂层，其包含通过沉积粘结涂层组合物形成的第一表面上的内粘合涂层，所述粘合涂层组合物包含重量百分比为14-20％的Cr，5-8％的Al，8-12％的Co ，3-7％Ta，0.1-0.6％Hf，0.1-0.5％Y，至多约1％Si，0.005-0.020％Zr，0.04-0.08％C，0.01-0.02％B，余量包括镍（ Ni）和杂质，其中粘合涂料组合物基本上不含铼。 含铝层覆盖在内粘合涂层上。 任选地，热障涂层覆盖在含铝层上，其中通过沉积热障涂层组合物形成热障涂层（如果存在）。

公开(公告)号：US20090162690A1

公开(公告)日：2009-06-25

申请号：US11963976

申请日：2007-12-24

申请人： Bangalore Aswatha Nagaraj ,  David John Wortman ,  Michael Patrick Maly

发明人： Bangalore Aswatha Nagaraj ,  David John Wortman ,  Michael Patrick Maly

IPC分类号： B32B15/04

CPC分类号： C22C19/056 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/3455 ,  Y02T50/67 ,  Y02T50/6765 ,  Y10T428/12549

摘要： Coating system for a metallic substrate includes a strengthened bond coat including a bond coat inner layer and an aluminum-containing layer overlying the bond coat inner layer. The bond coat inner layer is formed by deposition of a bond coat composition including, in weight percent, 14-20% Cr, 5-8% Al, 8-12% Co, 3-7% Ta, 0.1-0.6% Hf, 0.1-0.5% Y, up to about 1% Si, 0.005-0.020% Zr, 0.04-0.08% C, 0.01-0.02% B, with a remainder including Ni and incidental impurities, wherein the bond coat composition is substantially free of rhenium. The coating system includes an optional thermal barrier coating which may be a yttria-stabilized zirconia.

摘要翻译： 用于金属基材的涂布系统包括包含粘合涂层内层和覆盖在粘合涂层内层上的含铝层的强化粘合涂层。 粘结涂层内层通过沉积粘结涂层组合物形成，该组合物包含重量百分比为14-20％的Cr，5-8％的Al，8-12％的Co，3-7％的Ta，0.1-0.6％的Hf， 0.1-0.5％Y，至多约1％Si，0.005-0.020％Zr，0.04-0.08％C，0.01-0.02％B，余量包括Ni和杂质，其中粘合涂层组合物基本上不含铼 。 涂层系统包括可选的热障涂层，其可以是氧化钇稳定的氧化锆。

公开(公告)号：US20090162562A1

公开(公告)日：2009-06-25

申请号：US11963995

申请日：2007-12-24

申请人： Bangalore Aswatha Nagaraj ,  David John Wortman ,  Nicole Marie Polley ,  William Bryan Connor ,  Roger Dale Wustman

发明人： Bangalore Aswatha Nagaraj ,  David John Wortman ,  Nicole Marie Polley ,  William Bryan Connor ,  Roger Dale Wustman

IPC分类号： C23C16/00 ,  B05D3/02 ,  B05D1/36 ,  B05D1/38 ,  C23C4/08 ,  H05H1/24

CPC分类号： B32B15/017 ,  C22C19/056 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/3455 ,  Y02T50/67 ,  Y02T50/6765

摘要： Methods for coating a substrate includes depositing on the substrate, a inner bond coat layer of a bond coat composition comprising, in weight percent, 14-20% Cr, 5-8% Al, 8-12% Co, 3-7% Ta, 0.1-0.6% Hf, 0.1-0.5% Y, up to about 1% Si, 0.005-0.020% Zr, 0.04-0.08% C, 0.01-0.02% B, with a remainder including nickel (Ni) and incidental impurities, wherein the bond coat composition is substantially free of rhenium; forming an aluminum-containing layer overlying the inner bond coat layer; and, optionally, depositing a thermal barrier coating composition overlying the aluminum-containing layer.

摘要翻译： 用于涂覆基材的方法包括在基材上沉积粘合涂层组合物的内粘合涂层，其包含重量百分比为14-20％的Cr，5-8％的Al，8-12％的Co，3-7％的Ta ，0.1-0.6％Hf，0.1-0.5％Y，至多约1％Si，0.005-0.020％Zr，0.04-0.08％C，0.01-0.02％B，余量包括镍（Ni）和附带杂质， 其中所述粘合涂层组合物基本上不含铼; 形成覆盖在内粘合涂层上的含铝层; 以及任选地沉积覆盖在含铝层上的热障涂层组合物。

公开(公告)号：US06998172B2

公开(公告)日：2006-02-14

申请号：US10064791

申请日：2002-08-16

申请人： Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Ramgopal Darolia ,  Irene Spitsberg ,  Anthony Mark Thompson ,  Curtis Alan Johnson ,  David John Wortman

发明人： Boris A. Movchan ,  Yuriy E. Rudoy ,  Leonella M. Nerodenko ,  Ramgopal Darolia ,  Irene Spitsberg ,  Anthony Mark Thompson ,  Curtis Alan Johnson ,  David John Wortman

IPC分类号： B32B3/26

CPC分类号： C23C28/3215 ,  C23C8/02 ,  C23C14/06 ,  C23C28/321 ,  C23C28/345 ,  C23C28/3455 ,  F01D5/284 ,  F01D5/288 ,  F05D2300/2118 ,  F05D2300/224 ,  F05D2300/2285 ,  Y10T428/249954 ,  Y10T428/249956 ,  Y10T428/249957 ,  Y10T428/249967 ,  Y10T428/249976 ,  Y10T428/249986 ,  Y10T428/24999

摘要： A thermal barrier coating (TBC 26) and method for forming the TBC (26) on a component (10) characterized by a stabilized microstructure that resists grain growth, sintering and pore coarsening or coalescence during high temperature excursions. The TBC (26) contains elemental carbon and/or a carbon-containing gas that increase the amount of porosity (32) initially within the TBC (26) and form additional fine closed porosity (32) within the TBC (26) during subsequent exposures to high temperatures. A first method involves incorporating elemental carbon precipitates by evaporation into the TBC microstructure. A second method is to directly incorporate an insoluble gas, such as a carbon-containing gas, into an as-deposited TBC (26) and then partially sinter the TBC (26) to entrap the gas and produce fine stable porosity within the TBC (26).

摘要翻译： 一种隔热涂层（TBC26）和在组分（10）上形成TBC（26）的方法，其特征在于稳定的微结构，其在高温偏移期间抵抗晶粒生长，烧结和孔粗化或聚结。 TBC（26）含有元素碳和/或含碳气体，其最初在TBC（26）内增加孔隙率（32），并在随后的曝光期间在TBC（26）内形成额外的细闭孔率（32） 到高温。 第一种方法包括通过蒸发将元素碳沉淀物并入到TBC微结构中。 第二种方法是直接将诸如含碳气体的不溶性气体直接掺入沉积的TBC（26）中，然后部分烧结TBC（26）以截留气体并在TBC内产生精细的稳定孔隙（ 26）。

公开(公告)号：US08545185B2

公开(公告)日：2013-10-01

申请号：US11959595

申请日：2007-12-19

申请人： David John Wortman ,  Roger Dale Wustman ,  Nicole Marie Polley ,  Kathleen Diana Brammer ,  Brian Thomas Hazel

发明人： David John Wortman ,  Roger Dale Wustman ,  Nicole Marie Polley ,  Kathleen Diana Brammer ,  Brian Thomas Hazel

IPC分类号： F01D5/18

CPC分类号： F01D5/187 ,  F01D5/288 ,  F05D2230/30 ,  F05D2230/31 ,  F05D2230/80 ,  F05D2230/90 ,  Y02T50/67 ,  Y02T50/671 ,  Y02T50/676

摘要： Turbine airfoil components with protective layers and methods therefore. The components are each formed to have a platform, an airfoil extending upwardly from the platform, and a shank extending downwardly from the platform. The shank has an exterior wall and an internal passage, and the airfoil has a cooling flow channel inside the airfoil for flowing a cooling flow therethrough. The component has an interior chromide coating contacting at least a portion of an interior surface of the shank and interdiffused with a base metal thereof, and an exterior chromide coating contacting at least a portion of an exterior surface of the shank and interdiffused with the base metal thereof. The interior and exterior chromide coatings do not have an aluminide coating deposited thereon.

摘要翻译： 涡轮机翼部件具有保护层和方法。 这些部件各自形成为具有平台，从平台向上延伸的翼型件和从平台向下延伸的柄部。 柄具有外壁和内部通道，并且翼型件具有用于使冷却流通过其中的翼型件内的冷却流动通道。 该组件具有内部铬化物涂层，其接触柄的内表面的至少一部分并且与其基体金属相互扩散，并且外部铬化物涂层与柄的外表面的至少一部分接触并与基底金属相互扩散 其中。 内部和外部铬酸盐涂层不具有沉积在其上的铝化物涂层。

公开(公告)号：US09297089B2

公开(公告)日：2016-03-29

申请号：US13543423

申请日：2012-07-06

申请人： Charles Clifford Berger ,  David John Wortman

发明人： Charles Clifford Berger ,  David John Wortman

IPC分类号： C25D3/50 ,  C25D5/50 ,  C25D7/10

CPC分类号： C25D5/50 ,  C25D7/10

摘要： A gas turbine component for use in a gas turbine engine includes a substrate and a non-aluminide protective coating with a platinum-group metal. The platinum-group metal resides in a gamma-prime phase of the underlying material. The platinum-group metal can impart the protective coating with superior corrosion-resistance, while the absence of aluminide in the protective coating facilitates use of the protective coating at high-stress and/or high-fatigue portions of the component. The protective coating optionally includes chromide and can also be combined with aluminide at select portions of the component.

摘要翻译： 用于燃气涡轮发动机的燃气轮机部件包括基体和具有铂族金属的非铝化物保护涂层。 铂族金属位于下层材料的γ'相中。 铂族金属可以使保护涂层具有优异的耐腐蚀性，而保护涂层中不存在铝化物有助于在组件的高应力和/或高疲劳部分使用保护涂层。 保护涂层任选地包括铬化物，并且还可以在组分的选定部分与铝化物组合。