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公开(公告)号：US20110144403A1
公开(公告)日：2011-06-16
申请号：US12639968
申请日：2009-12-16
IPC分类号： C07C2/66
CPC分类号： B01J29/088 , B01J29/087 , C07C2/66 , C07C2529/08 , C07C15/107
摘要： A process is disclosed using a new catalyst for use in the alkylation of benzene with a substantially linear olefin. The catalyst allows for cation exchange with a rare earth element to increase the alkylation of benzene, while reducing the amount of isomerization of the alkyl group. This is important for increasing the quality of the alkylbenzene by increasing the linearity of the alkylbenzene.
摘要翻译： 公开了一种使用用于烷基化苯和基本上线性烯烃的新催化剂的方法。 催化剂允许与稀土元素进行阳离子交换以增加苯的烷基化，同时减少烷基的异构化。 这对于通过增加烷基苯的线性来提高烷基苯的质量是重要的。
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公开(公告)号：US09126184B2
公开(公告)日：2015-09-08
申请号：US12639968
申请日：2009-12-16
CPC分类号： B01J29/088 , B01J29/087 , C07C2/66 , C07C2529/08 , C07C15/107
摘要： A process is disclosed using a new catalyst for use in the alkylation of benzene with a substantially linear olefin. The catalyst allows for cation exchange with a rare earth element to increase the alkylation of benzene, while reducing the amount of isomerization of the alkyl group. This is important for increasing the quality of the alkylbenzene by increasing the linearity of the alkylbenzene.
摘要翻译： 公开了一种使用用于烷基化苯和基本上线性烯烃的新催化剂的方法。 催化剂允许与稀土元素进行阳离子交换以增加苯的烷基化，同时减少烷基的异构化。 这对于通过增加烷基苯的线性来提高烷基苯的质量是重要的。
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3.发明申请AROMATIC ALKYLATION PROCESS USING UZM-5, UZM-5P AND UZM-6 ZEOLITES 审中-公开使用UZM-5，UZM-5P和UZM-6沸石的芳族烷基化方法公开(公告)号：US20120142987A1
公开(公告)日：2012-06-07
申请号：US13330014
申请日：2011-12-19
IPC分类号： C07C15/04
CPC分类号： C07C2/66 , B01J29/70 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/08 , B01J37/30 , B01J2229/42 , C01B39/48 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： A process for alkylating aromatic compounds using a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula: Mmn+Cgh+Rrp+Al(1-x)ExSiyOz where M is an alkali or alkaline earth metal, E is an optional framework element, C organic nitrogen containing cation template, and R is an organic cation crystallization template. The zeolites have at least two x-ray diffraction peaks, one at a d-spacing of 3.9±0.12 Å and one at a d-spacing 8.6±0.20 Å; a tetragonal unit cell; and a micropore volume ranging from about 0.10 cc/g to about 0.18 cc/g.
摘要翻译： 使用一系列沸石烷基化芳族化合物的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并且由经验式：Mmn + Cgh + Rrp + Al（1-x） ExSiyOz其中M是碱金属或碱土金属，E是可选的骨架元素，C有机氮阳离子模板，R是有机阳离子结晶模板。 沸石具有至少两个x射线衍射峰，一个在d-间隔为3.9±0.12A处，一个在d-间隔为8.6±0.20处; 四方晶胞; 和微孔体积为约0.10cc / g至约0.18cc / g。
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4.发明授权Hydrocarbon conversion processes using catalysts comprising UZM-8 and UZM-8HS compositions 有权使用包含UZM-8和UZM-8HS组合物的催化剂的烃转化方法公开(公告)号：US07091390B2
公开(公告)日：2006-08-15
申请号：US10828989
申请日：2004-04-21
申请人： Deng-Yang Jan , Raelynn M. Miller , Mathias P. Koljack , John E. Bauer , Paula L. Bogdan , Gregory J. Lewis , Gregory J. Gajda , Susan C. Koster , Michael G. Gatter , Jaime G. Moscoso
发明人： Deng-Yang Jan , Raelynn M. Miller , Mathias P. Koljack , John E. Bauer , Paula L. Bogdan , Gregory J. Lewis , Gregory J. Gajda , Susan C. Koster , Michael G. Gatter , Jaime G. Moscoso
CPC分类号： C07C2/66 , B01J29/06 , B01J29/70 , B01J29/7007 , B01J29/74 , B01J2229/42 , C01B39/026 , C01B39/06 , C01B39/065 , C01B39/48 , C01P2002/72 , C07C5/2708 , C07C6/126 , C07C2529/70 , C10G29/205 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G47/14 , C10G47/20 , C10G49/06 , C10G49/08 , Y02P20/52 , C07C15/073 , C07C15/085 , C07C15/08
摘要： Hydrocarbon conversion processes using a new family of zeolites identified as UZM-8 and UZM-8HS are described. The UZM-8 and UZM-8HS are related in that the UZM-8HS are derived from the UZM-8 zeolite by treating the UZM-8 with a fluoro-silicate salt, an acid, etc. The UZM-8 and -8HS have unique x-ray diffraction patterns. These zeolites can be used in alkylation of aromatics, transalkylation of aromatics, isomerization of aromatics and alkylation of isoparaffins.
摘要翻译： 描述了使用识别为UZM-8和UZM-8HS的新型沸石族的烃转化方法。 UZM-8和UZM-8HS与UZM-8HS衍生自UZM-8沸石相关，通过用氟硅酸盐，酸等处理UZM-8。UZM-8和-8HS具有 独特的X射线衍射图。 这些沸石可用于芳族化合物的烷基化，芳烃的烷基转移，芳族化合物的异构化和异构烷烃的烷基化。
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5.发明授权UZM-5, UZM-5P, and UZM-6 crystalline aluminosilicate zeolites and methods for preparing the same 有权UZM-5，UZM-5P和UZM-6结晶硅铝酸盐沸石及其制备方法公开(公告)号：US08747807B2
公开(公告)日：2014-06-10
申请号：US13171890
申请日：2011-06-29
CPC分类号： B01J29/70 , C01B39/48 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/23 , C07C5/2518 , C07C5/2737 , C07C2529/70 , C10G50/00 , Y02P20/52 , C07C15/08
摘要： A method for preparing a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula Mmn+Cgh+Rrp+Al(1-x)ExSiyOz The method includes forming a Charge Density Mismatch (CDM) reaction mixture comprising reactive sources of Al, Si, optionally a framework element, E, and at least one organic nitrogen containing cation template, C, in the hydroxide form. After the CDM mixture is mixed while aging, an organic cation crystallization template, R, and at least one alkali metal or alkaline earth metal, M, is added. The combined final reaction mixture is reacted with mixing to produce the zeolite, which may be used in various hydrocarbon conversion processes.
摘要翻译： 一种制备沸石族的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并由经验式Mmn + Cgh + Rrp + Al（1-x）ExSiyOz表示。该方法包括 形成电荷密度不匹配（CDM）反应混合物，其包含氢氧化物形式的Al，Si，任选的骨架元素E和至少一种含有机氮的阳离子模板C的反应源。 在老化之后混合CDM混合物后，加入有机阳离子结晶模板R和至少一种碱金属或碱土金属M。 将组合的最终反应混合物与混合反应以产生可用于各种烃转化方法的沸石。
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6.发明授权Aromatic alkylation process using UZM-5, UZM-5P and UZM-6 zeolites 有权使用UZM-5，UZM-5P和UZM-6沸石的芳香族烷基化方法公开(公告)号：US08212097B2
公开(公告)日：2012-07-03
申请号：US13172016
申请日：2011-06-29
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , B01J29/70 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/08 , B01J37/30 , B01J2229/42 , C01B39/48 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： A process for alkylating aromatic compounds using a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula: Mmn+Cgh+Rrp+Al(1-x)ExSiyOz where M is an alkali or alkaline earth metal, E is an optional framework element, C organic nitrogen containing cation template, and R is an organic cation crystallization template. The zeolites have at least two x-ray diffraction peaks, one at a d-spacing of 3.9±0.12 Å and one at a d-spacing 8.6±0.20 Å; a tetragonal unit cell; and a micropore volume ranging from about 0.10 cc/g to about 0.18 cc/g.
摘要翻译： 使用一系列沸石烷基化芳族化合物的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并且由经验式：Mmn + Cgh + Rrp + Al（1-x） ExSiyOz其中M是碱金属或碱土金属，E是可选的骨架元素，C有机氮阳离子模板，R是有机阳离子结晶模板。 沸石具有至少两个x射线衍射峰，一个在d-间隔为3.9±0.12A处，一个在d-间隔为8.6±0.20处; 四方晶胞; 和微孔体积为约0.10cc / g至约0.18cc / g。
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7.发明授权Hydrocarbon conversion processes using a catalyst comprising a UZM-8HS composition 有权使用包含UZM-8HS组合物的催化剂的烃转化方法公开(公告)号：US07638667B2
公开(公告)日：2009-12-29
申请号：US11457184
申请日：2006-07-13
申请人： Deng-Yang Jan , Raelynn M. Miller , Mathias P. Koljack , John E. Bauer , Paula L. Bogdan , Gregory J. Lewis , Gregory J. Gajda , Susan C. Koster , Michael G. Gatter , Jaime G. Moscoso
发明人： Deng-Yang Jan , Raelynn M. Miller , Mathias P. Koljack , John E. Bauer , Paula L. Bogdan , Gregory J. Lewis , Gregory J. Gajda , Susan C. Koster , Michael G. Gatter , Jaime G. Moscoso
IPC分类号： C07C2/66
CPC分类号： B01J29/06 , B01J29/70 , B01J29/7007 , B01J29/74 , B01J2229/42 , C01B39/026 , C01B39/06 , C01B39/065 , C01B39/48 , C01P2002/72 , C07C2/66 , C07C5/2708 , C07C6/126 , C07C2529/70 , C10G29/205 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G47/14 , C10G47/20 , C10G49/06 , C10G49/08 , Y02P20/52 , C07C15/073 , C07C15/085 , C07C15/08
摘要： Hydrocarbon conversion processes using a new family of zeolites identified as UZM-8HS are described. The UZM-8HS zeolite are derived from UZM-8 zeolites by treating the UZM-8 with a fluoro-silicate salt, an acid, etc. The UZM-8HS zeolites have unique x-ray diffraction patterns. These zeolites can be used in alkylation of aromatics, transalkylation of aromatics, isomerization of aromatics and alkylation of isoparaffins.
摘要翻译： 描述了使用识别为UZM-8HS的新家族沸石的烃转化方法。 UZM-8HS沸石通过用氟硅酸盐，酸等处理UZM-8而衍生自UZM-8沸石.UZM-8HS沸石具有独特的x射线衍射图。 这些沸石可用于芳族化合物的烷基化，芳烃的烷基转移，芳族化合物的异构化和异构烷烃的烷基化。
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8.发明申请UZM-5, UZM-5P, AND UZM-6 CRYSTALLINE ALUMINOSILICATE ZEOLITES AND METHODS FOR PREPARING THE SAME 有权UZM-5，UZM-5P和UZM-6结晶铝酸钠沸石及其制备方法公开(公告)号：US20120004485A1
公开(公告)日：2012-01-05
申请号：US13171890
申请日：2011-06-29
CPC分类号： B01J29/70 , C01B39/48 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/23 , C07C5/2518 , C07C5/2737 , C07C2529/70 , C10G50/00 , Y02P20/52 , C07C15/08
摘要： A method for preparing a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula Mmn+Cgh+Rrp+Al(1-x)ExSiyOz The method includes forming a Charge Density Mismatch (CDM) reaction mixture comprising reactive sources of Al, Si, optionally a framework element, E, and at least one organic nitrogen containing cation template, C, in the hydroxide form. After the CDM mixture is mixed while aging, an organic cation crystallization template, R, and at least one alkali metal or alkaline earth metal, M, is added. The combined final reaction mixture is reacted with mixing to produce the zeolite, which may be used in various hydrocarbon conversion processes.
摘要翻译： 一种制备沸石族的方法，其实例被称为UZM-5，UZM-5P和UZM-6，并由经验式Mmn + Cgh + Rrp + Al（1-x）ExSiyOz表示。该方法包括 形成电荷密度不匹配（CDM）反应混合物，其包含氢氧化物形式的Al，Si，任选的骨架元素E和至少一种含有机氮的阳离子模板C的反应源。 在老化之后混合CDM混合物后，加入有机阳离子结晶模板R和至少一种碱金属或碱土金属M。 将组合的最终反应混合物与混合反应以产生可用于各种烃转化方法的沸石。
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公开(公告)号：US20120004483A1
公开(公告)日：2012-01-05
申请号：US13172016
申请日：2011-06-29
IPC分类号： C07C15/02
CPC分类号： C07C2/66 , B01J29/70 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/08 , B01J37/30 , B01J2229/42 , C01B39/48 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： A process for alkylating aromatic compounds using a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula: Mmn+Cgh+Rrp+Al(1-x)ExSiyOz where M is an alkali or alkaline earth metal, E is an optional framework element, C organic nitrogen containing cation template, and R is an organic cation crystallization template. The zeolites have at least two x-ray diffraction peaks, one at a d-spacing of 3.9±0.12 Å and one at a d-spacing 8.6±0.20 Å; a tetragonal unit cell; and a micropore volume ranging from about 0.10 cc/g to about 0.18 cc/g.
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10.发明授权公开(公告)号：US07888537B2
公开(公告)日：2011-02-15
申请号：US11959984
申请日：2007-12-19
IPC分类号： C07C37/08 , C07C27/00 , C07C45/53 , C07C1/24 , C07C407/00
CPC分类号： B01J29/40 , B01J29/06 , B01J29/082 , B01J29/7007 , B01J29/85 , B01J35/002 , B01J37/0009 , B01J37/0045 , B01J37/0221 , B01J37/0246 , B01J2229/36 , B01J2229/42 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , Y02P20/52 , C07C49/08 , C07C39/04
摘要： The present invention provides a process for decomposing a cumene hydroperoxide to produce phenol and acetone. The process utilizes a solid catalyst that can be non-layered or layered. The process includes: (1) introducing a process stream containing cumene hydroperoxide into a reaction vessel; (2) contacting the process stream with catalyst particles to form a process stream; and (3) withdrawing a portion of the product stream from the reactor and recovering phenol and acetone products.
摘要翻译： 本发明提供了分解氢过氧化枯烯以产生苯酚和丙酮的方法。 该方法使用可以是非层状或分层的固体催化剂。 该方法包括：（1）将含有氢过氧化枯烯的工艺流引入反应容器中; （2）使工艺流与催化剂颗粒接触以形成工艺流; 和（3）从反应器中取出一部分产物流并回收苯酚和丙酮产物。
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