摘要:
In the production of an S-substituted isothiourea including the function group ##STR1## in which R.sup.1 is an alkyl, alkenyl, aryl or aralkyl radical, wherein a thiourea including the functional group ##STR2## is reacted with an etherifying agent to replace H by R.sup.1, the improvement which comprises effecting the reaction in two steps, in the first step reacting the thiourea material with an etherifying agent including the radical Rin whichR is an alkyl, alkenyl aryl or aralkyl radical different from R.sup.1 thereby to produce the ether ##STR3## and in the second step reacting the ether with a compound of the formula R.sup.1 SH. The process is particularly applicable to the production of the known herbicide ##STR4## from the corresponding thiourea where in the first step methyl bromide or methyl iodide is used to form the S-methyl isothiourea which is then interchanged with ethyl mercaptan. Higher overall yields and/or economies are thereby achieved.
摘要:
In the production of an S-substituted isothiourea including the functional group ##STR1## in which R.sup.1 is an alkyl, alkenyl, aryl or aralkyl radical, wherein a thiourea including the functional group ##STR2## is reacted with an etherifying agent to replace H by R.sup.1, the improvement which comprises effecting the reaction in two steps, in the first step reacting the thiourea material with an etherifying agent including the radical Rin whichR is an alkyl, alkenyl aryl or aralkyl radical different from R.sup.1thereby to produce the ether ##STR3## and in the second step reacting the ether with a compound of the formula R.sup.1 SH. The process is particularly applicable to the production of the known herbicide ##STR4## from the corresponding thiourea where in the first step methyl bromide or methyl iodide is used to form the S-methyl isothiourea which is then interchanged with ethyl mercaptan. Higher overall yields and/or economies are thereby achieved.
摘要:
The present invention relates to a process for preparing sulfuric diamides of the general formula I R1R2N—S(O)2—NH2 (I) in which R1 and R2 are each independently a primary alkyl radical having from 1 to 8 carbon atoms, a secondary alkyl radical having from 3 to 8 carbon atoms or a cycloalkyl radical having from 5 to 8 carbon atoms, or, together with the nitrogen atom, form a 5- to 8-membered, saturated nitrogen heterocycle which, as well as the nitrogen atom, may have a further heteroatom selected from O and S as a ring member, where the nitrogen heterocycle is unsubstituted or may have 1, 2, 3 or 4 alkyl groups having in each case from 1 to 4 carbon atoms as substituents. The process comprises the following steps: i) the reaction of a secondary amine of the formula II R1R2NH (II) in which R1 and R2 are each as defined above with sulfuryl chloride in an inert solvent, especially an aromatic solvent, in the presence of a tertiary amine to give a sulfamoyl chloride of the formula III R1R2N—S(O)2—Cl (III) in which R1 and R2 are each as defined above, and ii) reaction of the sulfamoyl chloride of the formula III obtained in step i) with ammonia, the sulfamoyl chloride of the formula III being used in step ii) in the form of the solution obtained in step i) in the inert solvent, especially the aromatic solvent.
摘要:
A light-absorbing or light-emitting solar cell assembly comprises an electrical insulator disposed on an electrically conductive substrate and that is provided with a metallized surface and at least one solar cell connected to the electrically conductive substrate, wherein the solar cell includes refractive secondary optics and is disposed in a recess in the insulator. The solar cell is connected to the substrate by the side orientated towards the substrate via an electrically conductive connection and the recess is dimensioned such that an interspace is produced laterally between the solar cell and the electrical insulator, the interspace being filled with a coupling medium and the solar cell being connected to the metallized surface by at least one electrical contact.
摘要:
A tensioning device (10) for a seat belt, in particular in a motor vehicle, having a gas generator (17) and a piston (21) guided in a tube (16) that closes a pressure space (20) in the tube (16), whereas the pressure space (20) can be pressurized by the gas generator (17), as a result of which the piston (21) can be driven to perform a tensioning operation which can be transmitted to the seat belt by means of the force transmission means. The piston (21) having a closed or constricted opening (1, 1a), and the opening (1, 1a) can be enlarged and/or opened by the material erosion caused by the pressure and/or pressure conditions in the pressure space (20).
摘要:
A viscous clutch (30; 30′) includes a stationary journal bracket (32; 32′) defining a mounting shaft (32-1; 32-1′), an output member (34; 34′) rotatably supported on the mounting shaft about an axis (A), an input member (34; 34′) rotatably supported on the mounting shaft about the axis, and a working chamber (50; 50′) defined between the input member and the output member to selectively transmit torque there between when a shear fluid is present. The mounting shaft extends axially through the viscous clutch from a front face (62; 62′) of the viscous clutch to a rear face (56; 56′) of the viscous clutch, with the rear face defining a mounting surface for mounting the viscous clutch at a mounting location. The front and rear faces are located at opposite sides of the viscous clutch and face in opposite directions.
摘要:
The present invention relates to methods of reversibly staining a target cell. The invention also relates to methods of isolating a target cell or a target cell population that is defined by the presence of at least one common specific receptor molecule. The invention also provides kits that can be used to carry out the methods of the invention.
摘要:
A process is proposed for the preparation of a powder comprising one or more derivatives of glycine-N,N-diacetic acid and/or one or more derivatives of glutamine-N,N-diacetic acid with a degree of crystallinity of ≧30%,starting from an aqueous solution comprising the one or more derivatives of glycine-N,N-diacetic acid and/or the one or more derivatives of glutamine-N,N-diacetic acid in a concentration range from 20 to 60% by weight, based on the total weight of the aqueous solution, where the aqueous solution is concentrated in a first process step in an evaporator with rotating internals, which are arranged at a distance relative to the inside wall of the evaporator of ≦1% of the diameter of the evaporator, to give a crystal slurry with a solids concentration in the range from 60 to 85% by weight, based on the total weight of the crystal slurry, and where in a second process step the crystal slurry is left to ripen in a paste bunker and then in a thin-film contact dryer, and where the residence time in the paste bunker and in the thin-film contact dryer is in total ≧15 minutes.
摘要:
A method and a device operate a railroad security system having trackside devices for specific functions. In order to reduce the number of cable connections, control of a first trackside device is provided by a data message generated as required by a second trackside device, in particular a signal box, the data message being transmitted wirelessly.
摘要:
Methods and apparatus for providing content based on social networks are provided. In particular, a user's social relationships or activities on a social network may be utilized to determine content such as products and/or items of interest to present to the user.