公开(公告)号：US08628684B2

公开(公告)日：2014-01-14

申请号：US13318513

申请日：2010-05-19

申请人： Frank Mrzena ,  Hans-Juergen Kinder ,  Michael Schoenherr ,  Gerhard Cox ,  Thomas Schmidt ,  Volker Huett

发明人： Frank Mrzena ,  Hans-Juergen Kinder ,  Michael Schoenherr ,  Gerhard Cox ,  Thomas Schmidt ,  Volker Huett

IPC分类号： C09K3/00 ,  C07C61/08

CPC分类号： C07C229/24 ,  C07B2200/13 ,  C07C227/42 ,  C07C229/16

摘要： A process is proposed for the preparation of a powder comprising one or more derivatives of glycine-N,N-diacetic acid and/or one or more derivatives of glutamine-N,N-diacetic acid with a degree of crystallinity of ≧30%,starting from an aqueous solution comprising the one or more derivatives of glycine-N,N-diacetic acid and/or the one or more derivatives of glutamine-N,N-diacetic acid in a concentration range from 20 to 60% by weight, based on the total weight of the aqueous solution, where the aqueous solution is concentrated in a first process step in an evaporator with rotating internals, which are arranged at a distance relative to the inside wall of the evaporator of ≦1% of the diameter of the evaporator, to give a crystal slurry with a solids concentration in the range from 60 to 85% by weight, based on the total weight of the crystal slurry, and where in a second process step the crystal slurry is left to ripen in a paste bunker and then in a thin-film contact dryer, and where the residence time in the paste bunker and in the thin-film contact dryer is in total ≧15 minutes.

摘要翻译： 提出了制备包含一种或多种甘氨酸-N，N-二乙酸衍生物和/或谷氨酰胺-N，N-二乙酸衍生物的结晶度> 30％的粉末的方法， 从包含甘氨酸-N，N-二乙酸的一种或多种衍生物和/或浓度为20至60重量％的谷氨酰胺-N，N-二乙酸的一种或多种衍生物的水溶液开始， 基于所述水溶液的总重量，其中所述水溶液在具有旋转内部件的蒸发器中的第一工艺步骤中被浓缩，所述蒸发器相对于所述蒸发器的内壁相对于所述蒸发器的所述内壁的一定距离设置， 蒸发器，得到基于晶体浆料的总重量的固体浓度为60至85重量％的晶体浆料，并且其中在第二工艺步骤中，使晶体浆料以糊状物成熟 地堡，然后在薄膜接触式烘干机中，以及哪里 在糊状掩模和薄膜接触式干燥器中的停留时间总共> = 15分钟。

公开(公告)号：US20120046491A1

公开(公告)日：2012-02-23

申请号：US13318513

申请日：2010-05-19

申请人： Frank Mrzena ,  Hans-Juergen Kinder ,  Michael Schoenherr ,  Gerhard Cox ,  Thomas Schmidt ,  Volker Huett

发明人： Frank Mrzena ,  Hans-Juergen Kinder ,  Michael Schoenherr ,  Gerhard Cox ,  Thomas Schmidt ,  Volker Huett

IPC分类号： C07C229/24

CPC分类号： C07C229/24 ,  C07B2200/13 ,  C07C227/42 ,  C07C229/16

摘要： A process is proposed for the preparation of a powder comprising one or more derivatives of glycine-N,N-diacetic acid and/or one or more derivatives of glutamine-N,N-diacetic acid with a degree of crystallinity of ≧30%,starting from an aqueous solution comprising the one or more derivatives of glycine-N,N-diacetic acid and/or the one or more derivatives of glutamine-N,N-diacetic acid in a concentration range from 20 to 60% by weight, based on the total weight of the aqueous solution, where the aqueous solution is concentrated in a first process step in an evaporator with rotating internals, which are arranged at a distance relative to the inside wall of the evaporator of ≦1% of the diameter of the evaporator, to give a crystal slurry with a solids concentration in the range from 60 to 85% by weight, based on the total weight of the crystal slurry, and where in a second process step the crystal slurry is left to ripen in a paste bunker and then in a thin-film contact dryer, and where the residence time in the paste bunker and in the thin-film contact dryer is in total ≧15 minutes.

摘要翻译： 提出了制备包含一种或多种甘氨酸-N，N-二乙酸衍生物和/或一种或多种结晶度为≥30％的谷氨酰胺-N，N-二乙酸衍生物的粉末的方法， 从包含甘氨酸-N，N-二乙酸的一种或多种衍生物和/或浓度范围为20至60重量％的谷氨酰胺-N，N-二乙酸的一种或多种衍生物的水溶液开始，基于 在水溶液的总重量中，其中水溶液在具有旋转内部件的蒸发器中的第一工艺步骤中被浓缩，所述蒸发器相对于蒸发器的内壁设置一定距离，其直径为 蒸发器，得到基于晶体浆料的总重量的固体浓度为60至85重量％的晶体浆料，并且其中在第二工艺步骤中，使晶体浆料以糊状物成熟 然后在薄膜接触式干燥器中，并且w 这里在糊状物掩体和薄膜接触式干燥器中的停留时间总共≥15分钟。

公开(公告)号：US09540597B2

公开(公告)日：2017-01-10

申请号：US13501390

申请日：2010-10-11

申请人： Frank Mrzena ,  Ullrich Menge ,  Michael Schoenherr ,  Thomas Heidenfelder

发明人： Frank Mrzena ,  Ullrich Menge ,  Michael Schoenherr ,  Thomas Heidenfelder

IPC分类号： C11D11/02 ,  C11D3/33 ,  C11D17/06 ,  C07C227/42 ,  C07C229/24 ,  C11D11/00

CPC分类号： C11D3/33 ,  C07C227/42 ,  C07C229/24 ,  C11D11/0088 ,  C11D11/02 ,  C11D17/06

摘要： A process for the preparation of a powder comprising one or more complexing agent salts of the general formula comprises atomizing an aqueous solution comprising the one or more complexing agent salts in the presence of a crystalline fine dust of the same complexing agent salts and a drying step, wherein the concentration of the one or more complexing agent salt is from 10 to 80% by weight, based on the total weight of the aqueous solution, with an upper limit for the average particle diameter of the crystalline fine dust which is lower by at least a factor of 2 than the lower limit of the average particle diameter of the powder obtained after the process, and the fraction of the crystalline fine dust is from 0.1 to 20% by weight, based on the weight of the powder obtained after the process.

摘要翻译： 提出了一种制备包含一种或多种通式络合剂盐的粉末的方法，其起始于包含浓度为10-80重量％的一种或多种络合剂盐的水溶液，基于总量 在喷雾干燥过程中，包括雾化步骤和干燥步骤，其中所述雾化步骤是通过加入与存在于所述雾化步骤中的相同络合剂盐的结晶细粉末来进行的 水溶液或一种或多种与其不同的络合剂盐，结晶细粉尘的平均粒径的上限比所得粉末的平均粒径的下限低至少2倍 在该方法之后，以0.1至20重量％的比例，基于该方法后获得的粉末的重量。

公开(公告)号：US08748366B2

公开(公告)日：2014-06-10

申请号：US13321713

申请日：2010-05-19

申请人： Frank Mrzena ,  Michael Schoenherr ,  Robert Heinz ,  Thomas Heidenfelder

发明人： Frank Mrzena ,  Michael Schoenherr ,  Robert Heinz ,  Thomas Heidenfelder

IPC分类号： C11D11/02 ,  C11D3/33 ,  C11D7/32 ,  B29B9/00

CPC分类号： C11D3/33 ,  C11D3/3707 ,  C11D17/0091 ,  C11D17/06

摘要： A process for the preparation of a spray-dried powder containing at least one glycine-N,N-diacetic acid compound of a formula MOOC—CHR—N(CH2COOM)2, where R is a C1-12-alkyl and M is an alkali metal, the process including: preparing an aqueous solution containing the glycine-N,N-diacetic acid compound; concurrently passing the aqueous solution and air into a spray-drying apparatus; atomizing the aqueous solution by feeding the aqueous solution onto a rotating disk or by compressing the aqueous solution with a pump to a pressure of ≧20 bar absolute, to obtain fine liquid droplets; and drying the droplets, to obtain the spray-dried powder, where a temperature gradient between the aqueous solution and the air is in a range from 70 to 350° C., and a content of the glycine-N,N-diacetic acid compound in the aqueous solution is ≧84% by weight, based on a total weight of the dry mass.

摘要翻译： 一种制备含有至少一种式MOOC-CHR-N（CH 2 COOM）2的甘氨酸-N，N-二乙酸化合物的喷雾干燥粉末的方法，其中R是C1-12烷基，M是 碱金属，该方法包括：制备含有甘氨酸-N，N-二乙酸化合物的水溶液; 同时将水溶液和空气通入喷雾干燥装置; 通过将水溶液供给到旋转盘上或通过将水溶液压缩至≥20巴绝对压力来雾化水溶液，以获得精细的液滴; 并干燥液滴，得到喷雾干燥的粉末，其中水溶液和空气之间的温度梯度为70-350℃，甘氨酸-N，N-二乙酸化合物的含量 在水溶液中，基于干质量的总重量为≥84重量％。

公开(公告)号：US20120202731A1

公开(公告)日：2012-08-09

申请号：US13501390

申请日：2010-10-11

申请人： Frank Mrzena ,  Ulrich Menge ,  Michael Schoenherr ,  Thomas Heidenfelder

发明人： Frank Mrzena ,  Ulrich Menge ,  Michael Schoenherr ,  Thomas Heidenfelder

IPC分类号： C11D17/00 ,  B29B9/00 ,  C11D3/33

CPC分类号： C11D3/33 ,  C07C227/42 ,  C07C229/24 ,  C11D11/0088 ,  C11D11/02 ,  C11D17/06

摘要： A process is proposed for the preparation of a powder comprising one or more complexing agent salts of the general formula starting from an aqueous solution comprising the one or more complexing agent salts in a concentration of from 10 to 80% by weight, based on the total weight of the aqueous solution, in a spray-drying process, comprising an atomization step and a drying step, wherein the atomization step is carried out with the addition of crystalline fine dust of the same complexing agent salt(s) as are present in the aqueous solution, or one or more complexing agent salts different therefrom, with an upper limit for the average particle diameter of the crystalline fine dust which is lower by at least a factor of 2 than the lower limit of the average particle diameter of the powder obtained after the process, in a fraction of from 0.1 to 20% by weight, based on the weight of the powder obtained after the process.

摘要翻译： 提出了一种制备包含一种或多种通式络合剂盐的粉末的方法，其起始于包含浓度为10-80重量％的一种或多种络合剂盐的水溶液，基于总量 在喷雾干燥过程中，包括雾化步骤和干燥步骤，其中所述雾化步骤是通过加入与存在于所述雾化步骤中的相同络合剂盐的结晶细粉末来进行的 水溶液或一种或多种与其不同的络合剂盐，结晶细粉尘的平均粒径的上限比所得粉末的平均粒径的下限低至少2倍 在该方法之后，以0.1至20重量％的比例，基于该方法后获得的粉末的重量。

公开(公告)号：US08554465B2

公开(公告)日：2013-10-08

申请号：US13383838

申请日：2010-05-25

申请人： Michael Schoenherr ,  Christian Pampus ,  Volker Niemz

发明人： Michael Schoenherr ,  Christian Pampus ,  Volker Niemz

IPC分类号： G06F17/00 ,  G01C21/00 ,  G05D1/0246 ,  G05D1/0272 ,  G08G1/14

CPC分类号： B62D15/027

摘要： A device for the supported parking of a vehicle in a parking space is disclosed. The device includes at least one sensor device allowing the detection of at least one object at a near range from the vehicle. The device is implemented for numerically determining the presence of at least one object at a far range from the vehicle, such that the numerical determining of the object in the far range takes place on the basis of the object detected in the near range.

摘要翻译： 公开了一种用于在停车位中支撑的车辆停放的装置。 该装置包括至少一个传感器装置，允许在距离车辆的近距离处检测至少一个物体。 该装置被实现为用于数字地确定距离车辆的远程范围内的至少一个物体的存在，使得远程范围内的物体的数值确定是基于在近距离内检测到的物体进行的。

公开(公告)号：US20120303258A1

公开(公告)日：2012-11-29

申请号：US13499410

申请日：2010-08-13

申请人： Christian Pampus ,  Dirk Schmid ,  Michael Scherl ,  Werner Urban ,  Meike Fehse ,  Uwe Zimmermann ,  Michael Schoenherr

发明人： Christian Pampus ,  Dirk Schmid ,  Michael Scherl ,  Werner Urban ,  Meike Fehse ,  Uwe Zimmermann ,  Michael Schoenherr

IPC分类号： G08G1/16 ,  B60W40/04

CPC分类号： G01S13/931 ,  B60R21/013 ,  B60T2201/10 ,  B60W30/0956 ,  B60W50/14 ,  B62D15/0285 ,  G01S2013/9314 ,  G01S2013/9353 ,  G01S2013/9364 ,  G01S2013/9389

摘要： A method for mapping surroundings of a vehicle, objects in the surroundings of the vehicle being detected with the aid of sensors and particular detected objects being described by two coordinate points and also by a position fuzziness assigned to the particular coordinate point, the coordinate points and the position fuzziness values being stored in an interface in the form of data which may be accessed by driver assistance systems of the vehicle. A method is also described for ascertaining the collision probability of a vehicle with an object, in which the surroundings of the vehicle are initially mapped using the method for mapping the surroundings of a vehicle, a travel path to be traveled by the vehicle is ascertained in a subsequent step, and the degree of overlap between the object and the travel path and also the collision probability are finally determined, taking the position fuzziness into account.

摘要翻译： 一种用于映射车辆周围环境的方法，借助于由两个坐标点描述的传感器和特定检测对象以及分配给特定坐标点的位置模糊性，坐标点和 位置模糊值以数据的形式存储在接口中，该数据可由车辆的驾驶员辅助系统访问。 还描述了一种用于确定具有物体的车辆的碰撞概率的方法，其中使用用于映射车辆周围环境的方法首先映射车辆的周围，车辆行驶的行驶路径被确定在 考虑到位置模糊性，最终确定对象与行进路径之间的重叠程度以及碰撞概率。

公开(公告)号：US08048838B2

公开(公告)日：2011-11-01

申请号：US11571362

申请日：2005-07-01

申请人： Helmut Witteler ,  Michael Schoenherr ,  Markus Hartmann

发明人： Helmut Witteler ,  Michael Schoenherr ,  Markus Hartmann

IPC分类号： C11D7/26 ,  C11D7/32 ,  C11D7/50

CPC分类号： C11D3/33 ,  C11D1/66 ,  C11D1/72 ,  C11D1/825 ,  C11D3/3707 ,  C11D3/3753 ,  C11D3/3776

摘要： A mixed powder or mixed granule containing at east 80% by weight of a mixture of (a) from 5 to 95% by weight of at least one glycine-N,N-diacetic acid derivative of the general formula (I) MOOC—CHR—N(CH2COOM)2  (I) where R is C1-12-alkyl M is alkali metal, (b) from 5 to 95% by weight of at least one polyethylene glycol or of at least one nonionic surfactant or of a mixture thereof or of a polymer selected from the group consisting of polyvinyl alcohols, polyvinylpyrrolidones (PVP), polyalkylene glycols and derivatives thereof, processes for producing these mixed powders or mixed granules, the use of these mixed powders or mixed granules, and a solid laundry detergent and a solid dishwasher detergent comprising the inventive mixed powder or mixed granule are described.

摘要翻译： 含有（a）5-95重量％的至少一种通式（I）的甘氨酸-N，N-二乙酸衍生物的混合物，其中含有80重量％的混合粉末或混合颗粒MOOC-CHR -N（CH 2 COOM）2（I）其中R是C 1-12烷基M是碱金属，（b）5至95重量％的至少一种聚乙二醇或至少一种非离子表面活性剂或其混合物 或选自聚乙烯醇，聚乙烯吡咯烷酮（PVP），聚亚烷基二醇及其衍生物的聚合物的聚合物，制备这些混合粉末或混合颗粒的方法，使用这些混合粉末或混合颗粒，以及固体衣物洗涤剂和 描述了包含本发明的混合粉末或混合颗粒的固体洗碗机洗涤剂。

公开(公告)号：US20120191337A1

公开(公告)日：2012-07-26

申请号：US13383838

申请日：2010-05-25

申请人： Michael Schoenherr ,  Christian Pampus ,  Volker Niemz

发明人： Michael Schoenherr ,  Christian Pampus ,  Volker Niemz

IPC分类号： G06F17/00 ,  G01C21/00 ,  G08G1/16

CPC分类号： B62D15/027

摘要： A device for the supported parking of a vehicle in a parking space is disclosed. The device includes at least one sensor device allowing the detection of at least one object at a near range from the vehicle. The device is implemented for numerically determining the presence of at least one object at a far range from the vehicle, such that the numerical determining of the object in the far range takes place on the basis of the object detected in the near range.

摘要翻译： 公开了一种用于在停车位中支撑的车辆停放的装置。 该装置包括至少一个传感器装置，允许在距离车辆的近距离处检测至少一个物体。 该装置被实现为用于数字地确定距离车辆的远程范围内的至少一个物体的存在，使得远程范围内的物体的数值确定是基于在近距离内检测到的物体进行的。

公开(公告)号：US20080299194A1

公开(公告)日：2008-12-04

申请号：US12158236

申请日：2006-12-11

申请人： Karl Kolter ,  Marcus Wichtner ,  Michael Schoenherr ,  Jan-Peter Mittwollen

发明人： Karl Kolter ,  Marcus Wichtner ,  Michael Schoenherr ,  Jan-Peter Mittwollen

IPC分类号： A61K9/14 ,  A61K47/36 ,  A61K9/20

CPC分类号： A61K9/0056 ,  A61K9/2018

摘要： A pharmaceutical formulation in the form of agglomerates comprising a) 60-97% by weight of sugar or sugar alcohols, b) 1-25% by weight of crosslinked polyvinylpyrrolidone, c) 1-15% by weight of water-insoluble, film-forming polymers, d) 0-15% by weight of water-soluble polymers and e) 0-15% by weight of further pharmaceutically customary excipients, the sum of the components a) to e) being 100% by weight.

摘要翻译： 附聚物形式的药物制剂，其包含a）60-97重量％的糖或糖醇，b）1-25重量％的交联聚乙烯吡咯烷酮，c）1-15重量％的不溶于水的， 形成聚合物，d）0-15重量％的水溶性聚合物和e）0-15重量％的其它药学上常规的赋形剂，组分a）至e）的总和为100重量％。