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    Coating apparatus, method of coating glass, compounds and compositions for coating glasss and coated glass substrates
    5.
    发明授权
    Coating apparatus, method of coating glass, compounds and compositions for coating glasss and coated glass substrates 失效
    涂布装置，玻璃涂覆方法，用于涂覆玻璃和涂覆的玻璃基板的化合物和组合物

    公开(公告)号：US5356718A

    公开(公告)日：1994-10-18

    申请号：US17930

    申请日：1993-02-16

    申请人： Patricia R. Athey ,  Douglas S. Dauson ,  David E. Lecocq ,  George A. Neuman ,  John F. Sopko ,  Royann L. Stewart-Davis

    发明人： Patricia R. Athey ,  Douglas S. Dauson ,  David E. Lecocq ,  George A. Neuman ,  John F. Sopko ,  Royann L. Stewart-Davis

    IPC分类号： B32B9/00 ,  B32B17/06 ,  C03C17/00 ,  C03C17/23 ,  C03C17/245 ,  C03C17/30 ,  C03C17/34 ,  C07C7/04 ,  C23C16/40 ,  C23C16/44 ,  C23C16/453 ,  C23C16/455 ,  C23C16/54

    CPC分类号： C03C17/245 ,  C03C17/002 ,  C03C17/2453 ,  C03C17/3417 ,  C23C16/401 ,  C23C16/4412 ,  C23C16/453 ,  C23C16/545 ,  C03C2217/211 ,  C03C2217/212 ,  C03C2217/213 ,  C03C2217/215 ,  C03C2217/216 ,  C03C2217/218 ,  C03C2217/219 ,  C03C2217/228 ,  C03C2217/23 ,  C03C2217/241 ,  C03C2217/244 ,  C03C2218/152

    摘要： An apparatus for coating a glass ribbon has an exhaust on each side of a coating unit at different distances therefrom. With this arrangement, portions of the ribbon upstream and downstream of the coating unit are exposed to coating vapors from the coating unit for different periods of time. A coating mixture includes tin containing precursors and a silicon containing precursor. The silicon containing precursor has the structural formula ##STR1## where R.sub.1 is a group which does not have an oxygen available to form a peroxide, R.sub.2 is a functional group giving the silicon containing precursor the ability to be easily converted to silicon oxide coating, R.sub.3 is a bridging group to provide for multiple silicon atoms and R.sub.4 completes the bonding on the foundation silicon atom. An accelerant e.g. a phosphorus containing precursor may be used with the metal containing precursors to increase the deposition rate of the coating. The coating deposited on the glass has regions of continuously varying weight percent of silicon oxide and tin oxide as the distance from the glass-coating interface increases, with the surface of the coating farthest from the glass-coating interface being predominantly tin oxide. The regions within the coating provide the coating with different indices of refraction to eliminate iridescence resulting from increased thickness of the tin oxide at the outer coating surface and to provide the coated glass article with a neutral color. When phosphorus is used as the accelerant, the percent of crystallinity is reduced and approaches O, thereby reducing or eliminating the coating haze.

    摘要翻译： 用于涂覆玻璃带的设备在与其不同的距离处的涂布单元的每一侧上具有排气。 通过这种布置，涂层单元的上游和下游的部分部分暴露于来自涂覆单元的涂覆蒸气不同的时间段。 涂料混合物包括含锡前体和含硅前体。 含硅前体具有结构式“IMAGE”，其中R1是不具有可用于形成过氧化物的氧的基团，R2是赋予含硅前体的能够容易地转化为氧化硅涂层的功能，R3 是提供多个硅原子的桥接基团，R4完成了在基础硅原子上的键合。 加速剂例如 可以将含磷前体与含金属的前体一起使用以增加涂层的沉积速率。 随着玻璃 - 涂层界面的距离增加，沉积在玻璃上的涂层具有连续变化重量百分比的氧化硅和氧化锡的区域，其中最远离玻璃 - 涂层界面的涂层的表面主要是氧化锡。 涂层中的区域为涂层提供不同的折射率，以消除由外涂层表面上的氧化锡厚度增加而产生的虹彩，并为涂覆的玻璃制品提供中性色。 当磷用作促进剂时，结晶度的百分比降低并接近O，从而减少或消除涂层雾度。

    Aqueous suspension for pyrolytic spray coating
    6.
    发明授权
    Aqueous suspension for pyrolytic spray coating 有权
    用于热解喷涂的水悬浮液

    公开(公告)号：US08197940B2

    公开(公告)日：2012-06-12

    申请号：US12179669

    申请日：2008-07-25

    申请人： John F. Sopko ,  Patricia R. Athey

    发明人： John F. Sopko ,  Patricia R. Athey

    IPC分类号： B32B15/00

    CPC分类号： C03C17/25 ,  C03C2217/217 ,  C03C2217/219 ,  C03C2217/23 ,  C03C2218/112

    摘要： The durability of a transparent pyrolytic spray applied coating is improved by providing a spray solution of metal acetylacetonates having different particle size distribution. More particularly, the particle size distribution of each of the metal acetylacetonates is a function of its melting temperature, and optionally of its melting temperature and solubility.

    摘要翻译： 通过提供具有不同粒度分布的金属乙酰丙酮化物的喷雾溶液来改善透明热解喷涂涂层的耐久性。 更具体地，每个金属乙酰丙酮化物的粒度分布是其熔融温度，以及任选其熔融温度和溶解度的函数。

    Non-orthogonal coater geometry for improved coatings on a substrate
    8.
    发明授权
    Non-orthogonal coater geometry for improved coatings on a substrate 有权
    用于改善衬底上涂层的非正交涂布机几何形状

    公开(公告)号：US08557328B2

    公开(公告)日：2013-10-15

    申请号：US12572317

    申请日：2009-10-02

    申请人： James W. McCamy ,  John F. Sopko

    发明人： James W. McCamy ,  John F. Sopko

    IPC分类号： C23C16/448 ,  C23C16/40

    CPC分类号： C23C16/4401 ,  C23C16/4412 ,  C23C16/45502 ,  C23C16/45563 ,  C23C16/45578 ,  C23C16/45587 ,  C23C16/54

    摘要： A coating apparatus includes non-orthogonal coater geometry to improve coatings on a glass ribbon, and to improve yields of such coatings. The apparatus includes a first arrangement to move the ribbon along a first imaginary straight line through a coating zone provided in a glass forming chamber. The coater has a coating nozzle and an exhaust slot, each have a longitudinal axis. The coating nozzle directs coating vapors toward the coating zone, and the exhaust slot removes vapors from the coating zone. A second arrangement mounts the coater in spaced relation to the path with the coating nozzle and the exhaust slot facing the coating zone. A second imaginary straight line is normal to the longitudinal axis of the coating nozzle, and the first imaginary line and the second imaginary line subtend an angle in the range of greater than zero degrees to 90 degrees.

    摘要翻译： 涂覆设备包括非正交涂布机几何形状以改善玻璃带上的涂层，并提高这种涂层的产量。 该装置包括第一装置，用于沿着第一假想直线穿过设置在玻璃形成室中的涂布区域移动色带。 涂布机具有涂覆喷嘴和排气槽，每个具有纵向轴线。 涂层喷嘴将涂层蒸气引导到涂层区域，排气槽从涂层区域去除蒸汽。 第二布置将涂布机以与涂布喷嘴和排气槽相对的涂布区域的路径间隔开来安置。 第二假想直线垂直于涂覆喷嘴的纵向轴线，并且第一假想线和第二假想线对准大于零度至90度范围内的角度。

    NON-ORTHOGONAL COATER GEOMETRY FOR IMPROVED COATINGS ON A SUBSTRATE
    9.
    发明申请
    NON-ORTHOGONAL COATER GEOMETRY FOR IMPROVED COATINGS ON A SUBSTRATE 有权
    用于改善基材上涂层的非正交涂层几何

    公开(公告)号：US20110081486A1

    公开(公告)日：2011-04-07

    申请号：US12572317

    申请日：2009-10-02

    申请人： James W. McCamy ,  John F. Sopko

    发明人： James W. McCamy ,  John F. Sopko

    IPC分类号： C23C16/448 ,  C23C16/40

    CPC分类号： C23C16/4401 ,  C23C16/4412 ,  C23C16/45502 ,  C23C16/45563 ,  C23C16/45578 ,  C23C16/45587 ,  C23C16/54

    摘要： A coating apparatus includes non-orthogonal coater geometry to improve coatings on a glass ribbon, and to improve yields of such coatings. The apparatus includes a first arrangement to move the ribbon along a first imaginary straight line through a coating zone provided in a glass forming chamber. The coater has a coating nozzle and an exhaust slot, each have a longitudinal axis. The coating nozzle directs coating vapors toward the coating zone, and the exhaust slot removes vapors from the coating zone. A second arrangement mounts the coater in spaced relation to the path with the coating nozzle and the exhaust slot facing the coating zone. A second imaginary straight line is normal to the longitudinal axis of the coating nozzle, and the first imaginary line and the second imaginary line subtend an angle in the range of greater than zero degrees to 90 degrees.

    摘要翻译： 涂覆设备包括非正交涂布机几何形状以改善玻璃带上的涂层，并提高这种涂层的产量。 该装置包括第一装置，用于沿着第一假想直线穿过设置在玻璃形成室中的涂布区域移动色带。 涂布机具有涂覆喷嘴和排气槽，每个具有纵向轴线。 涂层喷嘴将涂层蒸气引导到涂层区域，排气槽从涂层区域去除蒸汽。 第二布置将涂布机以与涂布喷嘴和排气槽相对的涂布区域的路径间隔开来安置。 第二假想直线垂直于涂覆喷嘴的纵向轴线，并且第一假想线和第二假想线对准大于零度至90度范围内的角度。

    AQUEOUS SUSPENSION FOR PYROLYTIC SPRAY COATING
    10.
    发明申请
    AQUEOUS SUSPENSION FOR PYROLYTIC SPRAY COATING 有权
    水性喷雾涂料的水性悬浮液

    公开(公告)号：US20100021746A1

    公开(公告)日：2010-01-28

    申请号：US12179669

    申请日：2008-07-25

    申请人： John F. Sopko ,  Patricia R. Athey

    发明人： John F. Sopko ,  Patricia R. Athey

    IPC分类号： C23C14/54 ,  B01F13/00

    CPC分类号： C03C17/25 ,  C03C2217/217 ,  C03C2217/219 ,  C03C2217/23 ,  C03C2218/112

    摘要： The durability of a transparent pyrolytic spray applied coating is improved by providing a spray solution of metal acetylacetonates having different particle size distribution. More particularly, the particle size distribution of each of the metal acetylacetonates is a function of its melting temperature, and optionally of its melting temperature and solubility.

    摘要翻译： 通过提供具有不同粒度分布的金属乙酰丙酮化物的喷雾溶液来改善透明热解喷涂涂层的耐久性。 更具体地，每个金属乙酰丙酮化物的粒度分布是其熔融温度，以及任选其熔融温度和溶解度的函数。