摘要:
Process for the preparation of an additive-containing anionic clay comprising the steps of (a) milling a physical mixture of a divalent metal compound and a trivalent metal compound, (b) calcining the physical mixture at a temperature in the range 200-800° C., and (c) rehydrating the calcined mixture in aqueous suspension, wherein an additive is present in the physical mixture and/or the aqueous suspension of step (c). With this process additive-containing anionic clays with a homogeneous additive distribution can be prepared.
摘要:
Process for the preparation of a metal-containing composition, which process comprises the steps of (a) calcining a physical mixture of an anionic clay and a metal additive at a temperature between 200 and 800° C., and (b) rehydrating the calcined product of step a). This process allows the use of insoluble metal additives. It does not require the use of soluble metal additives, which has economic and environmental advantages.
摘要:
The invention relates to an oxidic catalyst composition comprising 5-60 wt % of a divalent metal, 5-60 wt % of a trivalent metal, and 35-60 wt % of a rare earth metal, calculated as oxide and based on the total weight of the oxidic catalyst composition. The invention also relates to a process for preparing such an oxidic catalyst composition. This composition is suitable as metal trap in FCC processes.
摘要:
Process for the preparation of an oxidic catalyst composition consisting of one or more trivalent metals preferably aluminum, one or more divalent metals preferably magnesium and more than 18 wt % of one or more compounds selected from the group consisting of rare earth metal compounds, phosphorus compounds, and transition metal compounds, which process comprises the steps of preparing a precursor mixture consisting of (i) or more trivalent metal compounds, (ii) one or more divalent metal compounds, (iii) one or more compounds selected from the group consisting of rare earth metal compounds, and transition metal compounds, and (iv) optionally water, which precursor mixture is not a solution. The resulting oxidic catalyst composition is suitable as a metal trap and SOx sorbent FCC processes.
摘要:
Process for the preparation of an oxidic composition comprising a trivalent metal, a divalent metal and—calculated as oxide and based on the total composition—more than 18 wt % of one or more compounds selected from the group consisting of rare earth metal compounds, phosphorus compounds, and transition metal compounds, which process comprises the following steps: (a) preparing a precursor mixture comprising (i) a compound 1 being a trivalent metal compound, (ii) a compound 2 being a divalent metal compound, and (iii) a compound 3 being different from compounds 1 and 2 and being selected from the group consisting of rare earth metal compounds, phosphorus compounds, and transition metal compounds, (b) optionally aging the mixture, without anionic clay being formed, (c) drying the mixture, and (d) calcining the product of step c). The resulting oxidic composition is suitable as a metal trap and SOx sorbent FCC processes.
摘要翻译:用于制备包含三价金属,二价金属和以氧化物计算并基于总组合物的氧化组合物的方法 - 大于18重量%的一种或多种选自稀土金属化合物,磷 化合物和过渡金属化合物,该方法包括以下步骤:(a)制备前体混合物,其包含(i)化合物1为三价金属化合物,(ii)化合物2为二价金属化合物,和(iii) 化合物3不同于化合物1和2,并且选自稀土金属化合物,磷化合物和过渡金属化合物,(b)任选地老化该混合物,而不形成阴离子粘土,(c)干燥 混合物,和(d)煅烧步骤c)的产物。 所得的氧化物组合物适合用作金属捕集剂和SO x x吸附剂FCC方法。
摘要:
This patent describes economical and environment-friendly processes for the synthesis of anionic clays. It involves reacting a slurry comprising boehmite, which has been peptized with acid with a divalent metal source followed by addition of source of base. The slurry is then hydrothermally aged. There is no necessity to wash or filter the product and it can be spray dried directly to form microspheres, or can be extruded to form shaped bodies. The product can be combined with other ingredients in the manufacture of catalysts, absorbents, pharmaceuticals, cosmetics, detergents, polymeric nanocomposites and other commodity products that contain anionic clays.
摘要:
A process is described for pretreating lignocellulosic biomass. The process comprises swelling the lignocellulosic biomass with an aqueous liquid. The pretreated lignocellulosic biomass may be used as a feedstock for the enzymatic conversion to ethanol, or in a thermal conversion. process to produce bio-oil. The pretreatment results in a greater yield and, in the case of a thermal conversion process, a better quality of the bio-oil. The pretreatment process may be used to adjust the composition and amount of inorganic material present in the lignocellulosic biomass material.
摘要:
A process is disclosed for converting a biomass material to a stabilized bio-oil. The process comprises converting the biomass to a pyrolytic oil having suspended therein particles of metal compounds, and removing at least part of the suspended metal compounds to obtain a stabilized bio-oil.
摘要:
A method for reducing the mechanical strength of solid biomass material, in particular lignocellulosic biomass, comprises mixing the solid biomass material with an inorganic material and heating the solid biomass material mixture to a toasting temperature in the range of 105° C. to 140° C. during an exposure time of from 1 minute to 12 hours. Before or after the heat treatment, which is referred to as “toasting”, the biomass material mixture is subject to flash heating. The treatment significantly reduces the mechanical energy required for reducing the particle size of the solid biomass material and is suitable as a pretreatment prior to a conversion reaction of the solid biomass material.
摘要:
A process is disclosed for converting a particulate solid biomass material to a high quality bio-oil in high yield. The process comprises a pretreatment step and a pyrolysis step. The pretreatment comprises a step of at least partially demineralizing the solid biomass, and improving the accessibility of the solid biomass by opening the texture of the particles of the solid biomass. In a preferred embodiment the liquid pyrolysis product is separated into the bio-oil and an aqueous phase, and the aqueous phase is used as a solvent in the demineralization step and/or in the step of improving the accessibility of the solid biomass by opening the texture of the particles of the solid biomass.