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公开(公告)号：US07423088B2
公开(公告)日：2008-09-09
申请号：US10515900
申请日：2003-05-22
IPC分类号： C08F8/00
摘要： A composition containing (1) a crystalline polypropylene resin and (2) one or more β-nucleating agents of the formula (I), wherein R1, R2 and R3, independently of one another, are C1-C20alkyl, C2-Calkyl substituted by C1-C10alkylamino, di(C1-C10alkyl)amino, C1-C10alkyloxy or hydroxy; C3-C20alkenyl, C5-C12cycloalkyl, C5-C12Cycloalkyl substituted by 1, 2 or 3 C1-C10alkyl; cyclohexylmethyl; cyclohexylmethyl substituted by 1, 2 or 3 C1-C10alkyl; C5-C9cycloalkenyl, C5-C9cycloalkenyl substituted by 1, 2 or 3 C1-C10alkyl; phenyl substituted by 1, 2 or 3 radicals selected from the group consisting of C1-C10-oalkyl, C1-C10alkyloxy, hydroxy, halogen, trihalogenmethyl, trihalogenmethoxy, benzoyl, phenylamino, acylamino and phenylazo; C7-C9phenylalkyl, C7-C9phenylalkyl which is substituted on the phenyl by 1, 2 or 3 radicals selected from the group consisting of C1-C10alkyl, C1-C10alkoxy and hydroxy; naphthyl, naphthyl substituted by C1C10alkyl, adamantyl, or a 5 to 6 membered heterocyclic group; characterized in that the polypropylene resin has a content of β-form crystals of at least 10% calculated by means of the following equation β-form crystal content (%)=100×Pβ1,/(Pa1+Pa2+Pa3+Pβ1) where Pa1 to Pa3 are respective peak heights (maxima) of the a-form and Pβ1 is a peak height (maximum) of the β-form determined by wide angle X-ray scattering.
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公开(公告)号：US07375149B2
公开(公告)日：2008-05-20
申请号：US10526106
申请日：2003-09-02
申请人： Bruno Rotzinger , Kurt Hoffmann , Dietmar Mäder , Neil Dunski
发明人： Bruno Rotzinger , Kurt Hoffmann , Dietmar Mäder , Neil Dunski
IPC分类号： C08K5/15
CPC分类号： C08K5/005 , C08K5/0075 , C08K5/1545 , C08K5/17 , C08K5/20 , C08K5/32
摘要： The invention describes novel mixtures comprising i) a processing stabilizer selected from the group consisting of hydroxylamine stabilizers, nitrone stabilizers, benzofuran-2-one stabilizers and/or a compound of the formula I wherein R2 is C7-C30alkyl, R3 is C1-C30alkyl, and ii) an antistatic agent selected from the group consisting of an ethoxylated amine and/or an ethoxylated amide, as stabilizers for protecting organic materials, in particular synthetic polymers, against oxidative, thermal or lightinduced degradation
摘要翻译： 本发明描述了新的混合物，其包括i）选自羟胺稳定剂，硝酮稳定剂，苯并呋喃-2-酮稳定剂和/或式I化合物的加工稳定剂，其中R 2是C 其中R 3是C 1 -C 30烷基，R 3是C 1 -C 30烷基，R 3是C 1 -C 30烷基， ，和ii）选自乙氧基化胺和/或乙氧基化酰胺的抗静电剂作为用于保护有机材料，特别是合成聚合物的稳定剂，防止氧化，热或轻诱导的降解
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公开(公告)号：US20050203226A1
公开(公告)日：2005-09-15
申请号：US10515900
申请日：2003-05-22
摘要： A composition containing (1) a crystalline polypropylene resin and (2) one or more β-nucleating agents of the formula (I), wherein R1, R2 and R3, independently of one another, are C1-C20alkyl, C2-Calkyl substituted by C1-C10alkylamino, di(C1-C10alkyl)amino, C1-C10alkyloxy or hydroxy; C3-C20alkenyl, C5-C12cycloalkyl, C5-C12Cycloalkyl substituted by 1, 2 or 3 C1-C10alkyl; cyclohexylmethyl; cyclohexylmethyl substituted by 1, 2 or 3 C1-C10 alkyl; C5-C9cycloalkenyl, C5-C9cycloalkenyl substituted by 1, 2 or 3 C1-C10alkyl; phenyl substituted by 1, 2 or 3 radicals selected from the group consisting of C1-C10-alkyl, C1-C10alkyloxy, hydroxy, halogen, trihalogenmethyl, trihalogenmethoxy, benzoyl, phenylamino, acylamino and phenylazo; C7-C9phenylalkyl, C7-C9phenylalkyl which is substituted on the phenyl by 1, 2 or 3 radicals selected from the group consisting of C1-C10alkyl, C1-C10alkoxy and hydroxy; naphthyl, naphthyl substituted by C1C10alkyl, adamantyl, or a 5 to 6 membered heterocyclic group; characterized in that the polypropylene resin has a content of β-form crystals of at least 10% calculated by means of the following equation β-form crystal content (%)=100×P⊕1,/(Pa1+Pa2+Pa3+Pβ1) where Pa1 to Pa3 are respective peak heights (maxima) of the a-form and Pβ1 is a peak height (maximum) of the β-form determined by wide angle X-ray scattering.
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公开(公告)号：US20090318593A1
公开(公告)日：2009-12-24
申请号：US11992175
申请日：2006-09-21
IPC分类号： C08L23/06 , C08K5/05 , C08K5/20 , C08K5/1575 , C08L23/12
CPC分类号： C08K5/20 , C08K5/1575 , C08K7/02
摘要： A process for improving the flow properties of a melt containing a thermoplastic polymer, which comprises incorporating 0.005% to 0.5% by weight, relative to the weight of the thermoplastic polymer, of one or more additives selected from the group consisting of organic and inorganic compounds with needle-like morphology in their solid state into said thermoplastic polymer prior to or during melt processing.
摘要翻译： 一种用于改善含有热塑性聚合物的熔体的流动性能的方法，其包括相对于热塑性聚合物的重量掺入0.005重量％至0.5重量％的一种或多种选自有机和无机化合物的添加剂 在熔融加工之前或期间，其固态的针状形态进入所述热塑性聚合物。
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公开(公告)号：US07470324B2
公开(公告)日：2008-12-30
申请号：US10522690
申请日：2003-07-29
申请人： Kurt Hoffmann
发明人： Kurt Hoffmann
IPC分类号： C30B29/58
摘要： A method for the crystallization of macromolecules in a three-phase system using a vessel containing a lower aqueous phase, a middle phase and an upper hydrophobic phase having a lower density than that of the lower aqueous phase, wherein an aqueous solution of the macromolecules is added to the middle phase to form a fourth phase, followed by incubation.
摘要翻译： 一种使用含有下水相，中相和上疏水相的容器在三相体系中结晶大分子的方法，所述容器的密度低于下水相的密度，其中大分子的水溶液为 加入中期形成第四期，随后孵育。
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公开(公告)号：US07300978B2
公开(公告)日：2007-11-27
申请号：US10785909
申请日：2004-02-23
IPC分类号： B32B21/08 , C08K5/20 , C08K5/36 , C08L101/00 , C08L51/06
CPC分类号： C08K5/005 , C08F8/00 , C08K5/0008 , C08K5/34 , Y10T428/31913 , Y10T428/31928 , C08F20/00 , C08F22/00 , C08F10/00
摘要： This invention relates to a process for stabilising and at the same time phase compatibilising plastics or plastic compositions by incorporating polymeric compounds obtainable by reacting a compound selected from the group consisting of the sterically hindered phenols, sterically hindered amines, lactones, sulfides, phosphites, benzotriazoles, benzophenones and 2-(2-hydroxyphenyl)-1,3,5-triazines, which compounds contain at least one reactive group, with a compatibilisator.
摘要翻译： 本发明涉及一种用于稳定并同时使相容相容化塑料或塑料组合物的方法，该方法是将通过使选自空间位阻酚，空间位阻胺，内酯，硫化物，亚磷酸酯，苯并三唑的化合物 ，二苯甲酮和2-（2-羟基苯基）-1,3,5-三嗪，该化合物含有至少一个反应性基团，和相容剂。
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公开(公告)号：US20060167146A1
公开(公告)日：2006-07-27
申请号：US10526106
申请日：2003-09-02
申请人： Bruno Rotzinger , Kurt Hoffmann , Dietmar Mader , Neil Dunski
发明人： Bruno Rotzinger , Kurt Hoffmann , Dietmar Mader , Neil Dunski
IPC分类号： C08K5/524
CPC分类号： C08K5/005 , C08K5/0075 , C08K5/1545 , C08K5/17 , C08K5/20 , C08K5/32
摘要： The invention describes novel mixtures comprising i) a processing stabilizer selected from the group consisting of hydroxylamine stabilizers, nitrone stabilizers, benzofuran-2-one stabilizers and/or a compound of the formula I wherein R2 is C7-C30alkyl, R3 is C1-C30alkyl, and ii) an antistatic agent selected from the group consisting of an ethoxylated amine and/or an ethoxylated amide, as stabilizers for protecting organic materials, in particular synthetic polymers, against oxidative, thermal or lightinduced degradation.
摘要翻译： 本发明描述了新的混合物，其包括i）选自羟胺稳定剂，硝酮稳定剂，苯并呋喃-2-酮稳定剂和/或式I化合物的加工稳定剂，其中R 2是C 其中R 3是C 1 -C 30烷基，R 3是C 1 -C 30烷基，R 3是C 1 -C 30烷基， ，和ii）选自乙氧基化胺和/或乙氧基化酰胺的抗静电剂作为用于保护有机材料，特别是合成聚合物的稳定剂，防止氧化，热或轻诱导的降解。
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公开(公告)号：US20060111555A1
公开(公告)日：2006-05-25
申请号：US10522690
申请日：2003-07-29
申请人： Kurt Hoffmann
发明人： Kurt Hoffmann
摘要： A method for the crystallization of macromolecules in a three-phase system using a vessel containing a lower aqueous phase, a middle phase and an upper hydrophobic phase having a lower density than that of the lower aqueous phase, wherein an aqueous solution of the macromolecules is added to the middle phase to form a fourth phase, followed by incubation.
摘要翻译： 一种使用含有下水相，中相和上疏水相的容器在三相体系中结晶大分子的方法，所述容器的密度低于下水相的密度，其中大分子的水溶液为 加入中期形成第四期，随后孵育。
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公开(公告)号：US06706824B1
公开(公告)日：2004-03-16
申请号：US09703782
申请日：2000-11-01
申请人： Rudolf Pfaendner , Kurt Hoffmann , Heinz Herbst
发明人： Rudolf Pfaendner , Kurt Hoffmann , Heinz Herbst
IPC分类号： C08G6391
CPC分类号： C08L63/00 , C08G59/4014 , C08G59/4276 , C08G63/916 , C08G64/42 , C08G69/48 , C08G73/0655 , C08G85/00 , C08L77/00 , C08L2666/18 , C08L2666/14
摘要： By heating at above the melting point and/or glass transition point of the polycondensate and adding an aromatic dicyanate; or adding a mixture comprising an aromatic dicyanate and a polyfunctional compound selected from the class of sterically hindered hydroxyphenyl-alkyl-phosphonic esters and monoesters, diphosphonites and secondary aromatic amines; or adding a mixture comprising (i) an aromatic dicyanate, (ii) at least one polyfunctional compound selected from the class of sterically hindered hydroxyphenyl-alkyl-phosphonic esters and monoesters, diphosphonites and secondary amines, and (iii) a difunctional epoxide, it is possible to bring about an increase in the molecular weight and/or viscosity of virgin polycondensate and polycondensate recyclates.
摘要翻译： 通过在缩聚物的熔点和/或玻璃化转变点以上加热并加入芳香族二氰酸酯; 或添加包含芳族二氰酸酯和选自空间位阻羟基苯基 - 烷基 - 膦酸酯和单酯，二膦酸酯和仲芳族胺类的多官能化合物的混合物; 或添加包含（i）芳族二氰酸酯，（ii）至少一种选自空间位阻羟基苯基 - 烷基 - 膦酸酯和单酯，二亚膦酸酯和仲胺的多官能化合物和（iii）双官能环氧化物的混合物的混合物， 可能导致原始缩聚物和缩聚物回收物的分子量和/或粘度增加。
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10.发明授权Process for the stabilization of a stabilizer mixtures for recycled plastic mixtures 失效用于稳定再生塑料混合物稳定剂混合物的方法公开(公告)号：US06525158B1
公开(公告)日：2003-02-25
申请号：US08977110
申请日：1997-09-17
IPC分类号： C08J1104
CPC分类号： C08K5/524 , C08J11/06 , C08K3/22 , C08K3/26 , C08K5/005 , C08K5/13 , C08K5/521 , C08L23/02 , C08L25/06 , C08L27/06 , Y02W30/701 , C08L2666/04
摘要： Recycled mixtures of plastics, predominantly thermoplastics, as predominantly produced in the household, in commerce and also in industry and useful material collections, can be stabilized against thermooxidative degradation by adding a combination of a sterically hindered phenol with an organic phosphite or phosphonite and an inorganic compound from the series consisting of metal oxides, hydroxides and carbonates.
摘要翻译： 可以通过加入空间位阻酚与有机亚磷酸酯或亚膦酸酯和无机物的组合来稳定防止热氧化降解的塑料的主要是热塑性塑料的混合物，主要在家庭中，在商业中以及工业和有用的材料收集中主要生产， 由金属氧化物，氢氧化物和碳酸盐组成的系列的化合物。
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