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1.发明授权
公开(公告)号：US4032429A
公开(公告)日：1977-06-28
申请号：US635917
申请日：1975-11-28
IPC分类号： C10G1/08
CPC分类号： C10G1/086
摘要： A process for the liquefaction of coal in the presence of hydrogen and a solid supported catalyst containing a hydrogenation component and wherein the support comprises an amorphous aluminum phosphate.
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公开(公告)号：US4104200A
公开(公告)日：1978-08-01
申请号：US707521
申请日：1976-08-06
IPC分类号： C10G1/06 , B01J21/00 , B01J21/06 , B01J21/10 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/74 , B01J23/78 , B01J23/85 , B01J23/88 , B01J23/883 , C10G1/08 , B01J21/04
CPC分类号： B01J23/24 , B01J23/74 , B01J23/85 , C10G1/086 , B01J21/005 , B01J23/883 , Y10S502/524
摘要： A novel hydrogenation catalyst comprising a hydrogenation metal mounted on a magnesium-deficient magnesium aluminate spinel and a process for hydrogenating a carbonaceous material using such catalyst.
摘要翻译： 包含安装在缺镁镁铝尖晶石上的氢化金属和使用这种催化剂氢化含碳材料的方法的新型氢化催化剂。
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3.发明授权Process for hydrogenating a solid carbonaceous material with Ni/Ti/Mo on a mangesium-deficient magnesium aluminate spinel-as catalyst 失效在缺乏镁的镁酸镁尖晶石上作为催化剂用Ni / Ti / Mo将固体碳质材料氢化的方法
公开(公告)号：US4116808A
公开(公告)日：1978-09-26
申请号：US840899
申请日：1977-10-11
CPC分类号： C10G1/086 , B01J23/24 , B01J23/74 , B01J23/85 , B01J21/005 , B01J23/883 , Y10S502/524
摘要： A process for hydrogenating a carbonaceous material using a novel hydrogenation catalyst comprising a hydrogenation metal mounted on a magnesium-deficient magnesium aluminate spinel.
摘要翻译： 一种使用包含安装在镁缺乏的铝酸镁尖晶石上的氢化金属的新型氢化催化剂来氢化含碳材料的方法。
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4.发明授权Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst 失效煤液化过程中使用可溶性含钼有机二硫代磷酸酯催化剂
公开(公告)号：US5246570A
公开(公告)日：1993-09-21
申请号：US865837
申请日：1992-04-09
IPC分类号： C10G1/08
CPC分类号： C10G1/086
摘要： A coal liquefaction process employing a first stage liquefaction step catalyzed by a soluble molybdenum-containing organophosphorodithioate catalyst is disclosed. In some embodiments, two consecutive liquefaction steps employ a molybdenum-containing organophosphorodithioate catalyst operating at a relatively high liquefaction temperature. In other embodiments, a second liquefaction process step operating at a relatively low temperature employs a hydrocracking catalyst to upgrade materials obtained from the first soluble catalyst liquefaction step. In some embodiments, an interstage gas separator removes gases such as carbon dioxide produced in the first liquefaction step from a partially liquefied mixture prior to further liquefying the mixture in the second liquefaction step.
摘要翻译： 公开了采用由可溶性含钼有机二硫代磷酸酯催化剂催化的第一阶段液化步骤的煤液化方法。 在一些实施方案中，两个连续的液化步骤使用在较高液化温度下操作的含钼有机二硫代磷酸酯催化剂。 在其它实施方案中，在较低温度下操作的第二液化工艺步骤使用加氢裂化催化剂来升级从第一可溶性催化剂液化步骤获得的材料。 在一些实施例中，级间气体分离器在第二液化步骤中进一步液化混合物之前从部分液化的混合物中除去在第一液化步骤中产生的二氧化碳等气体。
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5.发明授权Process for producing a catalyst by depositing molybdenum removed from a waste catalyst 失效通过沉积从废催化剂中除去的钼来生产催化剂的方法
公开(公告)号：US4350609A
公开(公告)日：1982-09-21
申请号：US238538
申请日：1981-02-26
摘要： This invention relates to a method for selectively removing molybdenum values from a spent catalyst and producing a fresh molybdenum-containing catalyst. Such a method preferably contacts anhydrous gaseous hydrogen chloride at an elevated temperature with the metal containing catalyst which is substantially free of carbonaceous material to selectively remove molybdenum therefrom, and producing a fresh molybdenum-containing catalyst by depositing molybdenum from the vapor phase onto a fresh support in the presence of air. At least 50 weight percent and generally as much as 95 weight percent of the molybdenum is removed while other metals such as iron, titanium, cobalt and nickel along with the supporting alumina or silica are not affected.
摘要翻译： 本发明涉及从废催化剂中选择性除去钼值并生产新鲜的含钼催化剂的方法。 这种方法优选在高温下与含有金属的催化剂的无水氯化氢接触，所述催化剂基本上不含碳质材料以从其中选择性地除去钼，并通过将钼从气相沉积到新鲜载体上来生产新鲜的含钼催化剂 在有空气的情况下。 除去钼的至少50重量％和通常多达95重量％的钼，而其他金属如铁，钛，钴和镍以及支撑氧化铝或二氧化硅不受影响。
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公开(公告)号：US4238320A
公开(公告)日：1980-12-09
申请号：US031630
申请日：1979-04-19
摘要： A process for upgrading crude shale oil containing nitrogen which comprises contacting crude shale oil in a hydrogenation zone with hydrogen in the presence of a hydrogenation catalyst to remove a selected portion of the nitrogen and then contacting the resulting product with an ion exchange resin to obtain a shale oil of substantially lower nitrogen content.
摘要翻译： 一种用于升级含有氮的粗页岩油的方法，该方法包括在氢化催化剂存在下将粗页岩油与氢气在氢化催化剂存在下接触以除去选定部分的氮气，然后使所得产物与离子交换树脂接触，得到 页岩油含氮量显着降低。
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公开(公告)号：US3957619A
公开(公告)日：1976-05-18
申请号：US482077
申请日：1974-06-24
CPC分类号： C10G1/083 , B01J8/02 , B01J8/06 , B01J2208/0053
摘要： A process is provided for the conversion (including upgrading) of solid carbonaceous materials, and in particular for the hydrogenation of coal slurries. The process comprises passing a slurry composed of solid carbonaceous material and solvent, together with hydrogen, through a reaction vessel that contains a plurality of reaction zones separated by porous partitions. A portion of said zones is adapted to contain a solid particulate hydrogenation catalyst which will not pass through said porous partitions. The remainder of said zones forms substantially unobstructed passageways through said reaction vessel. The volumetric proportion of substantially unobstructed passageways to catalyst zones is preferably from about 20:1 to about 1:10.
摘要翻译： 提供了用于固体碳质材料的转化（包括升级），特别是用于煤浆的氢化的方法。 该方法包括将由固体碳质材料和溶剂组成的浆料与氢气一起通过包含多个由多孔隔板隔开的多个反应区域的反应容器。 所述区域的一部分适于容纳固体颗粒氢化催化剂，其不会通过所述多孔隔板。 所述区域的其余部分形成通过所述反应容器的基本上无阻碍的通道。 基本上无障碍通道到催化剂区域的体积比例优选为约20:1至约1:10。
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公开(公告)号：US4121909A
公开(公告)日：1978-10-24
申请号：US855992
申请日：1977-11-30
CPC分类号： B01J35/10 , B01J23/85 , C10G1/06 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061
摘要： A catalytic reactor comprising an elongated reaction chamber and catalytic elements composed of alumina and a hydrogenation catalyst vertically disposed within the reaction chamber.
摘要翻译： 一种催化反应器，包括细长的反应室和由氧化铝组成的催化元素和垂直设置在反应室内的氢化催化剂。
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9.发明授权Catalytic reactor and process for hydrogenating solid-containing carbonaceous materials in said reactor 失效催化反应器和用于在所述反应器中氢化固体含碳材料的方法
公开(公告)号：US4080282A
公开(公告)日：1978-03-21
申请号：US704352
申请日：1976-07-12
CPC分类号： B01J35/10 , B01J23/85 , C10G1/06 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061
摘要： A novel catalytic reactor comprising an elongated reaction chamber and catalytic elements composed of alumina and a hydrogenation catalyst vertically disposed within the reaction chamber and a coal hydrogenation process using such reactor.
摘要翻译： 一种新颖的催化反应器，其包括细长反应室和由氧化铝组成的催化元素和垂直设置在反应室内的氢化催化剂和使用这种反应器的煤氢化方法。
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10.发明授权公开(公告)号：US09314770B2
公开(公告)日：2016-04-19
申请号：US13247759
申请日：2011-09-28
IPC分类号： C07C1/20 , B01J21/06 , C01G19/02 , C01G23/047 , B82Y30/00 , C07C1/12 , C01F17/00 , B01J37/08 , B01J37/14 , B01J23/06 , B01J23/10 , B01J23/14 , B01J23/745 , B01J35/00
CPC分类号： B01J21/063 , B01J23/06 , B01J23/10 , B01J23/14 , B01J23/745 , B01J35/0013 , B01J35/004 , B01J37/08 , B01J37/084 , B01J37/14 , B82Y30/00 , C01F17/0043 , C01G19/02 , C01G23/047 , C01P2002/54 , C01P2002/72 , C01P2002/82 , C01P2002/85 , C01P2004/04 , C01P2004/64 , C01P2006/80 , C07C1/12 , C07C2521/06 , C07C2523/06 , C07C2523/10 , C07C2523/14 , C07C2523/745 , Y02P20/52 , C07C9/04
摘要： In one preferred embodiment, a photocatalyst for conversion of carbon dioxide and water to a hydrocarbon and oxygen comprises at least one nanoparticulate metal or metal oxide material that is substantially free of a carbon coating, prepared by heating a metal-containing precursor compound in a sealed reactor under a pressure autogenically generated by dissociation of the precursor material in the sealed reactor at a temperature of at least about 600° C. to form a nanoparticulate carbon-coated metal or metal oxide material, and subsequently substantially removing the carbon coating. The precursor material comprises a solid, solvent-free salt comprising a metal ion and at least one thermally decomposable carbon- and oxygen-containing counter-ion, and the metal of the salt is selected from the group consisting of Mn, Ti, Sn, V, Fe, Zn, Zr, Mo, Nb, W, Eu, La, Ce, In, and Si.
摘要翻译： 在一个优选实施方案中，用于将二氧化碳和水转化为烃和氧的光催化剂包括至少一种基本上不含碳涂层的纳米颗粒金属或金属氧化物材料，其通过将密封的含金属的前体化合物 反应器在压力下通过在密封的反应器中在至少约600℃的温度下解离前体材料而产生的压力，以形成纳米颗粒碳涂覆的金属或金属氧化物材料，随后基本上除去碳涂层。 前体材料包含固体的无溶剂盐，其包含金属离子和至少一种可热分解的含碳和氧的反离子，并且所述盐的金属选自Mn，Ti，Sn， V，Fe，Zn，Zr，Mo，Nb，W，Eu，La，Ce，In和Si。
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