公开(公告)号：US11230650B2

公开(公告)日：2022-01-25

申请号：US16340978

申请日：2017-11-17

Applicant: Dow Global Technologies LLC

Inventor： Carmelo Declet Perez ,  Brian W. Walther ,  James L. Cooper ,  Hayley A. Brown

IPC: C08L23/08 ,  B32B15/08 ,  B32B27/32 ,  C09J123/08 ,  B32B5/02 ,  B32B15/082 ,  B32B15/20 ,  B65D65/40 ,  C08J5/12 ,  C09J133/02

Abstract: The present invention provides polymer blends that can be used in a multilayer structure and to multilayer structures comprising one or more layers formed from such blends. In one aspect, a polymer blend comprises an ionomer of a copolymer comprising ethylene and at least one of acrylic acid and methacrylic acid having a melt index (I2) of 1 to 60 g/10 minutes, wherein the total amount of ionomer comprises 50 to 99 weight percent of the blend based on the total weight of the blend, and a polyolefin having a density of 0.870 g/cm3 or more and having a melt index (I2) of 20 g/10 minutes or less, wherein the polyolefin comprises 1 to 50 weight percent of the blend based on the total weight of the blend, wherein the polymer blend meets the following equation: 3.5

公开(公告)号：US20200109271A1

公开(公告)日：2020-04-09

申请号：US16080621

申请日：2017-05-17

Applicant: Dow Global Technologies LLC

Inventor： Hayley A. Brown ,  Teresa P. Karjala ,  Lori L. Kardos ,  David T. Gillespie ,  Zachary L. Polk ,  Jose Ortega

IPC: C08L23/06 ,  C08L23/12 ,  B01J19/18

Abstract: A composition comprising an ethylene-based polymer, which comprises the following properties: a) (Mw(abs)/Mw(conv)−2.00)*(100,000 g/mol/Mw(abs))*CDF?IR #191 (MW≤10,000 g/mol)≥0.030; and b) a melt index (I2) from 0.30 to 2.50 g/10 min.

公开(公告)号：US20200087492A1

公开(公告)日：2020-03-19

申请号：US16470853

申请日：2017-11-29

Applicant: Dow Global Technologies LLC

Inventor： Cornelis F.J. Den Doelder ,  Carmelo Declet Perez ,  Otto J. Berbee ,  Hayley A. Brown

IPC: C08L23/06 ,  C08J3/12 ,  B29B9/06

Abstract: A process for producing a composition comprising A) an ethylene-based polymer that has a density greater than, or equal to, 0.940 g/cc, and B) an ethylene homopolymer formed by polymerizing a reaction mixture comprising ethylene, using a free-radical, high pressure polymerization process includes adding component (A) to a molten stream of component (B) after component (B) exits the separator and before component (B) is solidified in the pelletizer. A polymerization configuration for producing the composition includes at least one reactor, at least one separator, at least one pelletizer, and a device used to feed component (A), in the molten state, to a molten stream of component (B) before the pelletizer. The composition has a ratio of the melt strength of the composition to the melt strength of component (B) is greater than or equal to 1.04 and a density of greater than 0.920 g/cc.

公开(公告)号：US11607864B2

公开(公告)日：2023-03-21

申请号：US16643246

申请日：2018-07-17

Applicant: Dow Global Technologies LLC

Inventor： Viraj K. Shah ,  Kalyan Sehanobish ,  Amira A. Marine ,  Brian Dorvel ,  Harpreet Singh ,  Hayley A. Brown

IPC: B32B7/12 ,  C09J7/29 ,  C09J7/38 ,  B32B27/08 ,  B32B27/30 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B37/12

Abstract: Laminate film structures including an adhesive layer having gas and moisture barrier properties are disclosed. The disclosed laminate film structures comprise films bonded together with an adhesive composition, the adhesive composition having barrier properties, e.g., controlling oxygen and/or water vapor transmission rates. The disclosed laminate film structures comprise films made from polymers and/or metallized polymers whereby the weight, thickness, and/or number of film layers has been reduced by using a barrier adhesive in place of a standard adhesive while still achieving similar barrier properties. Methods for forming laminate structures having a desired barrier performance are also disclosed, the methods comprising determining the desired barrier performance of the laminate structure, selecting a barrier adhesive, selecting two or more film layers, including at least a first film layer and a second film layer, applying the barrier adhesive on a surface of the first film layer, and bringing a surface of the second film layer into contact with the barrier adhesive applied on the surface of the first film layer, thereby forming the laminate structure having a desired barrier performance.

公开(公告)号：US11312844B2

公开(公告)日：2022-04-26

申请号：US16304893

申请日：2016-07-28

Applicant: Dow Global Technologies LLC

Inventor： Jian Wang ,  Jichang Feng ,  Xiao Bing Yun ,  Mehmet Demirors ,  Edward L. Lee ,  Hayley A. Brown ,  Bin Li

IPC: C08J9/06 ,  C08L23/06 ,  C08J9/00 ,  C08L23/08

Abstract: A composition suitable for making uncrosslinked polyethylene foam and an uncrosslinked polyethylene foam comprising: 50-95 wt. % of a low density polyethylene having a density ranging from 0.915 to 0.930 g/cc and melt index of 1-4 g/10 min; and 5-50 wt. % of an ethylene/alpha-olefin interpolymer having: a density ranging from 0.910-0.930 g/cc; a melt index ranging from 0.5 to 6.0 g/10 min; a Mw/Mn of from 2.8 to 4.5; and a ZSVR of 1.8 to 10.0.

公开(公告)号：US11110690B2

公开(公告)日：2021-09-07

申请号：US16461534

申请日：2017-11-10

Applicant: Dow Global Technologies LLC

Inventor： Sydney E. Hansen ,  Brian W. Walther ,  Hayley A. Brown ,  Santosh S. Bawiskar

IPC: B32B27/08 ,  B32B7/12 ,  B32B27/18 ,  B32B27/30 ,  B32B27/32 ,  C08F255/02 ,  C08K5/00 ,  C08K5/134 ,  C08K5/5333 ,  C08L23/06 ,  C08L23/08 ,  C08L51/06 ,  C08L53/02

Abstract: Embodiments are directed to a tie layer composition comprising functionalized polyethylene, styrene block copolymer, base polyethylene, and antioxidant co-stabilizers, wherein the antioxidant co-stabilizers comprise at least one oxygen scavenger, at least one peroxy free radical scavenger, and at least one alkyl free radical scavenger. Further embodiments are directed to multilayer films or sheets which include the tie layer composition.

公开(公告)号：US10759928B2

公开(公告)日：2020-09-01

申请号：US16080621

申请日：2017-05-17

Applicant: Dow Global Technologies LLC

Inventor： Hayley A. Brown ,  Teresa P. Karjala ,  Lori L. Kardos ,  David T. Gillespie ,  Zachary L. Polk ,  Jose Ortega

IPC: C08F10/02 ,  C08L23/04 ,  C08L23/06 ,  B01J19/18 ,  C08L23/12 ,  C08F210/02 ,  C08F110/02

Abstract: A composition comprising an ethylene-based polymer, which comprises the following properties: a) (Mw(abs)/Mw(conv)−2.00)*(100,000 g/mol/Mw(abs))*CDF?IR #191 (MW≤10,000 g/mol)≥0.030; and b) a melt index (I2) from 0.30 to 2.50 g/10 min.

公开(公告)号：US12215232B2

公开(公告)日：2025-02-04

申请号：US17424351

申请日：2020-01-31

Applicant: Dow Global Technologies LLC

Inventor： Cristina Serrat ,  Charles J. DuBois, Jr. ,  Hayley A. Brown ,  Jorge C. Gomes ,  Renata de Oliveria Pimentel

IPC: C08L95/00 ,  E01C7/26

Abstract: The present disclosure provides embodiments of an asphalt composition and methods of making that may include asphalt binder; a recycled polymer component; an epoxy-functionalized ethylene copolymer, the epoxy-functionalized ethylene copolymer having the formula E/X/Y/Z. E may be a copolymer unit —(CH2CH2)— derived from ethylene; X may be a copolymer unit —(CH2CR1R2)—, where R1 is hydrogen, methyl, or ethyl, and R2 is carboalkoxy, acyloxy, or alkoxy of 1 to 10 carbon atoms, present in from 0 to about 40 weight % of the copolymer; Y may be a copolymer unit —(CH2CR3R4)—, where R3 is hydrogen or methyl and R4 is carboglycidoxy or glycidoxy present in from 0 to about 25 weight % of the copolymer; Z may be a copolymer derived from comonomers including carbon monoxide, sulfur dioxide, acrylonitrile, or other monomers, present from 0 to about 10 weight % of the copolymer.

公开(公告)号：US11891463B2

公开(公告)日：2024-02-06

申请号：US17254987

申请日：2019-06-26

Applicant: Dow Global Technologies LLC

Inventor： John O. Osby ,  Hayley A. Brown ,  Mehmet Demirors ,  Carmelo Declet Perez

IPC: C08F210/02 ,  C08F236/20 ,  C08L23/08 ,  C08F220/40 ,  C08F2/38 ,  C08F210/06

CPC classification number: C08F210/02 ,  C08F2/38 ,  C08F210/06 ,  C08F236/20 ,  C08L23/0869 ,  C08F220/40 ,  C08L2201/08 ,  C08L2203/16 ,  C08L2203/30 ,  C08L2207/066

Abstract: An ethylene-based polymer formed from reacting at least the following: ethylene and at least one asymmetrical polyene, of Structure 1, as described herein.

公开(公告)号：US20230383058A1

公开(公告)日：2023-11-30

申请号：US18250867

申请日：2021-10-27

Applicant: Dow Global Technologies LLC

Inventor： Xian Jiang ,  Yushan Hu ,  Wayne C. Whelchel ,  Bruce M. Hasch ,  Hayley A. Brown ,  Seema V. Karande

IPC: C08G67/02 ,  C08L27/06

CPC classification number: C08G67/02 ,  C08L27/06 ,  C08L2205/06

Abstract: The present disclosure provides embodiments of a tetrapolymer composition. In embodiments, the tetrapolymer composition may have the formula E/P/X/CO, which may include from 25 wt. % to 90 wt. % of ethylene (E), from 0.1 wt. % to 5.0 wt. % of propylene (P), from 5 wt. % to 40 wt. % of alkyl acrylate (X), and from 3 wt. % to 30 wt. % of carbon monoxide (CO). X may be selected from the group consisting of vinyl acetate or n-butyl acrylate. The tetrapolymer composition may have a melt index, 12, from 10 to 1,000 g/10 min when measured according to ASTM 1238 at 2.16 kg and 190 C. Additionally, the present disclosure provides embodiments of a polymer formulation comprising the tetrapolymer composition and polyvinyl chloride.