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公开(公告)号:US20240124315A1
公开(公告)日:2024-04-18
申请号:US17768245
申请日:2020-10-14
Applicant: Drexel University
Inventor: Michel W. BARSOUM , Varun R. NATU
IPC: C01B32/921 , B01J4/00 , B01J8/02
CPC classification number: C01B32/921 , B01J4/001 , B01J8/0278 , C01P2002/72 , C01P2002/74 , C01P2002/85 , C01P2004/03 , C01P2004/04 , C01P2004/24 , H01M10/054
Abstract: Provided are methods for etching MAX-phase materials to produce MXenes, the etching being accomplished by a salt, one or both of a polar and a non-polar solvent, and optionally a crown ether, the etching also being optionally performed in a water-free or essentially water-free manner. Also provided are related systems and methods.
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公开(公告)号:US20220406486A1
公开(公告)日:2022-12-22
申请号:US17894609
申请日:2022-08-24
Applicant: Murata Manufacturing Co., Ltd. , DREXEL UNIVERSITY
Inventor: Akimaro YANAGIMACHI , Masashi KOYANAGI , Yuusuke OGAWA , Louisiane VERGER , Michel W. BARSOUM
Abstract: A paste that includes particles of a layered material in an ammonia aqueous solution. The particles include one or plural layers, the layers having a layer body represented by MmXn, wherein M is at least one metal of Group 3, 4, 5, 6, or 7, X is a carbon atom, a nitrogen atom, or a combination thereof, n is not less than 1 and not more than 4, and m is more than n but not more than 5, and a modifier or terminal T exists on a surface of the layer body, wherein T is at least one selected from the group consisting of a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, and a hydrogen atom, wherein the paste has a viscosity of 1 Pa·s or more at a shear velocity of 1/s when the paste has a solid content concentration of 1.0% by mass.
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">3.
公开(公告)号:US20180108910A1
公开(公告)日:2018-04-19
申请号:US15567777
申请日:2016-04-20
Applicant: Drexel University
Inventor: Michel W. BARSOUM , Babak ANASORI , Yury GOGOTSI
IPC: H01M4/58 , H01M10/0525 , C30B29/36 , C30B29/68 , C01B32/90 , C01B32/907
CPC classification number: H01M4/58 , C01B21/0602 , C01B32/90 , C01B32/907 , C01P2002/20 , C01P2002/70 , C01P2002/85 , C01P2006/40 , C30B7/02 , C30B29/36 , C30B29/38 , C30B29/60 , C30B29/68 , H01M10/0525
Abstract: The present disclosure is directed to compositions comprising at least one layer having first and second surfaces, each layer comprising: a substantially two-dimensional array of crystal cells, each crystal cell having an empirical formula of M′2M″nXn+1, such that each X is positioned within an octahedral array of M′ and M″; wherein M′ and M″ each comprise different Group IIIB, IVB, VB, or VIB metals; each X is C, N, or a combination thereof; n=1 or 2; and wherein the M′ atoms are substantially present as two-dimensional outer arrays of atoms within the two-dimensional array of crystal cells; the M″ atoms are substantially present as two-dimensional inner arrays of atoms within the two-dimensional array of crystal cells; and the two dimensional inner arrays of M″ atoms are sandwiched between the two-dimensional outer arrays of M′ atoms within the two-dimensional array of crystal cells.
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公开(公告)号:US20240286918A1
公开(公告)日:2024-08-29
申请号:US18572309
申请日:2022-06-23
Applicant: DREXEL UNIVERSITY
Inventor: Michel W. BARSOUM , Hussein Osama BADR , Tarek Aly ELMELIGY
CPC classification number: C01G23/00 , B82Y40/00 , C01P2002/01 , C01P2002/72 , C01P2004/64
Abstract: Processes of producing nanoparticles from solid phase precursor non-nanoparticles. Contacting a solid phase precursor non-nanoparticle selected from oxides of metals and metalloids, carbides of metals and metalloids, nitrides of metals and metalloids, borides of metals and metalloids, silicides of metals and metalloids, and phosphides of metals and metalloids, and mixtures thereof, with one or more onium ions in water in a vessel. Some processes can be one pot processes. The vessel is agitated and held at temperature for a time sufficient to form nanoparticles with the same crystalline structure as the solid phase precursor non-nanoparticle as determined by XRD and/or TEM. Nanoparticles made by the processes. Processes of use of the nanoparticles.
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5.
公开(公告)号:US20230034579A1
公开(公告)日:2023-02-02
申请号:US17781924
申请日:2020-12-03
Applicant: DREXEL UNIVERSITY
Inventor: Michel W. BARSOUM , Michael S. CAREY , Rahul Nagesh PAI , Vibha KALRA , Varun R. NATU
IPC: H01M4/58 , C01B32/907 , H01M4/36 , H01M4/62 , H01M4/04
Abstract: Provided are methods of effecting cation exchange in MXene materials so as to stabilize the materials. Also provided are compositions, comprising layered MXene materials that comprise an organic cation between layers. Also provided are MXene compositions comprising a chalcogen disposed thereon, the MXene composition further optionally comprising a quaternary ammonium halide disposed thereon.
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公开(公告)号:US20240274831A1
公开(公告)日:2024-08-15
申请号:US18568358
申请日:2022-06-10
Applicant: DREXEL UNIVERSITY
Inventor: Rahul Nagesh PAI , Vibha KALRA , Michel W. BARSOUM , Hussein O. BADR
IPC: H01M4/62 , H01M4/02 , H01M4/13 , H01M10/052
CPC classification number: H01M4/628 , H01M4/13 , H01M4/623 , H01M10/052 , H01M2004/028
Abstract: By combining two-dimensional (2D) transition metal oxide and/or carbo-oxides with sulfur, one can form cathodes for use in Li—S batteries, which batteries in turn exhibit high capacity and other attractive characteristics. Accordingly, provided herein are methods, comprising: forming an admixture that comprises sulfur, a 2D transition metal carbo-oxide, and optionally a conductive material. Also provided are electrodes, comprising sulfur, a 2D transition metal carbo-oxide, and optionally a conductive material. Further provided are energy cells, the energy cell comprising a first electrode according to the present disclosure. Additionally provided are methods, the methods comprising discharging an energy cell according to the present disclosure or charging an energy cell according to the present disclosure. Also provided are electrical devices, comprising an energy cell according to the present disclosure.
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公开(公告)号:US20180044182A1
公开(公告)日:2018-02-15
申请号:US15554904
申请日:2016-03-01
Applicant: Drexel University
Inventor: Michel W. BARSOUM , Chunfeng HU
IPC: C01B21/06 , C01B21/072 , C01B32/90 , C01B21/076
Abstract: The present invention is directed to crystalline solids having an empirical formula of M2A2X, wherein M is at least one Group IIIB, IVB, VB, or VIB metal, preferably Cr, Hf, Sc, Ti, Mo, Nb, Ta, V, Zr, or a combination thereof; wherein A is Al, Ga, Ge, In, Pb, or Sn, or a combination thereof; and each X is CxNy, where x+y=1. In some particular embodiments, the crystalline composition has a unit cell stoichiometry of Mo2Ga2C.
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公开(公告)号:US20250091029A1
公开(公告)日:2025-03-20
申请号:US18832624
申请日:2023-02-10
Applicant: DREXEL UNIVERSITY
Inventor: Michel W. BARSOUM , Hussein O. BADR , Joshua SNYDER
Abstract: A method, comprising: to an initial sample that has an initial concentration of urea in solution, contacting a composition comprising metal oxide nanofilaments under such conditions that at least some of the urea adsorbs to the metal oxide nanofilaments so as to give rise to a final concentration of urea in the solution A device for removing urea from an initial aqueous solution of urea, the device comprising an exchangeable cartridge of metal oxide nanofilaments composition through which the initial aqueous solution is directed to pass, the passage adapted to allow the initial aqueous urea solution to contact the metal oxide nanofilaments contained in the cartridge. Contacting a composition comprising metal oxide-based nanofilaments to an initial sample that comprises a metal ion and/or a metal under such conditions that at least some of the metal ion and/or the metal associates with the metal oxide nanofilaments.
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公开(公告)号:US20210094831A1
公开(公告)日:2021-04-01
申请号:US16954786
申请日:2018-12-17
Applicant: Drexel University
Inventor: Michel W. BARSOUM , Di ZHAO , Varun NATU
IPC: C01B32/921 , B03D3/06
Abstract: The present disclosure describes a crumpled form of MXene materials, and methods of making and using these novel compositions.
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10.
公开(公告)号:US20170294546A1
公开(公告)日:2017-10-12
申请号:US15513740
申请日:2015-09-23
Applicant: Drexel University
Inventor: Michael J. GHIDIU , Michel W. BARSOUM , Yury GOGOTSI , Aaron Thomas FAFARMAN , Andrew DeVries Dillon
IPC: H01L31/0224 , H01L33/42 , H01L51/52 , C04B35/58
CPC classification number: H01L31/022466 , C01B32/914 , C01B32/921 , C01B32/949 , C04B35/56 , C04B35/5607 , C04B35/5618 , C04B35/58 , C04B35/58007 , C04B2235/3201 , C04B2235/3203 , C04B2235/3205 , C04B2235/445 , H01L33/42 , H01L51/5203
Abstract: The present invention(s) is directed to novel conductive Mn+1Xn(Ts) compositions exhibiting high volumetric capacitances, and methods of making the same. The present invention(s) is also directed to novel conductive Mn+1Xn(Ts) compositions, methods of preparing transparent conductors using these materials, and products derived from these methods.
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