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公开(公告)号：US20130004886A1
公开(公告)日：2013-01-03
申请号：US13536612
申请日：2012-06-28
摘要： A process includes patterning a surface of a platinum group metal-based electrode by contacting the electrode with an adsorbate to form a patterned platinum group metal-based electrode including platinum group metal sites blocked with adsorbate molecules and platinum group metal sites which are not blocked.
摘要翻译： 一种方法包括通过使电极与被吸附物接触来形成铂族金属基电极的表面，以形成包含被吸附物分子封闭的铂族金属部位和未被阻断的铂族金属部位的图案化的铂族金属基电极。
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公开(公告)号：US09065142B2
公开(公告)日：2015-06-23
申请号：US13536612
申请日：2012-06-28
摘要： A process includes patterning a surface of a platinum group metal-based electrode by contacting the electrode with an adsorbate to form a patterned platinum group metal-based electrode including platinum group metal sites blocked with adsorbate molecules and platinum group metal sites which are not blocked.
摘要翻译： 一种方法包括通过使电极与被吸附物接触来形成铂族金属基电极的表面，以形成包含被吸附物分子封闭的铂族金属部位和未被阻断的铂族金属部位的图案化的铂族金属基电极。
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公开(公告)号：US20130004885A1
公开(公告)日：2013-01-03
申请号：US13245395
申请日：2011-09-26
摘要： A process includes patterning a surface of a platinum group metal-based electrode by contacting the electrode with an adsorbate to form a patterned platinum group metal-based electrode including platinum group metal sites blocked with adsorbate molecules and platinum group metal sites which are not blocked.
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4.发明申请MESOSTRUCTURED THIN-FILMS AS ELECTROCATALYSTS WITH TUNABLE COMPOSITIONS AND SURFACE MORPHOLOGY 审中-公开作为具有可组成组合物和表面形态的电解质的结构化薄膜公开(公告)号：US20130209898A1
公开(公告)日：2013-08-15
申请号：US13800707
申请日：2013-03-13
IPC分类号： H01M4/92
CPC分类号： H01M4/921 , B82Y30/00 , B82Y40/00 , H01M4/8803 , H01M4/8867 , H01M4/8871 , H01M4/8882 , H01M4/926
摘要： A composition of matter and method of manufacturing as thin film electrocatalyst. The method uses physical vapor deposition to deposit a thin film of PtM (Ma transition metal) to form a Pt based alloy and annealing the thin film to achieve a (111) hexagonal faceted grain structure having catalytic activity approaching Pt3Ni (111) skin.
摘要翻译： 物质的组成和制造方法作为薄膜电催化剂。 该方法使用物理气相沉积法沉积PtM（Ma过渡金属）薄膜以形成Pt基合金，并对薄膜进行退火以实现具有接近Pt3Ni（111）表面的催化活性的（111）六方晶面晶粒结构。
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5.发明申请NANOSEGREGATED BIMETALLIC OXIDE ANODE CATALYST FOR PROTON EXCHANGE MEMBRANE ELECTROLYZER 有权用于原子交换膜电解质的纳米二氧化钛阳极催化剂公开(公告)号：US20160089658A1
公开(公告)日：2016-03-31
申请号：US14502825
申请日：2014-09-30
申请人： Nemanja Danilovic , Yijin Kang , Nenad Markovic , Vojislav Stamenkovic , Deborah J. Myers , Ram Subbaraman
发明人： Nemanja Danilovic , Yijin Kang , Nenad Markovic , Vojislav Stamenkovic , Deborah J. Myers , Ram Subbaraman
IPC分类号： B01J23/46 , B01J37/12 , B01J37/08 , C25B13/04 , B01J37/14 , B01J37/03 , B01J35/02 , C25B9/08 , B01J37/16 , B01J37/18
CPC分类号： B01J23/468 , B01J35/0013 , B01J35/0033 , B01J35/008 , B01J35/023 , B01J37/031 , B01J37/08 , B01J37/12 , B01J37/14 , B01J37/16 , B01J37/18 , C25B9/08 , C25B11/04 , C25B13/04
摘要： A surface segregated bimetallic composition of the formula Ru1-xIrx wherein 0.1≦x≦0.75, wherein a surface of the material has an Ir concentration that is greater than an Ir concentration of the material as a whole is provided. The surface segregated material may be produced by a method including heating a bimetallic composition of the formula Ru1-xIrx, wherein 0.1≦x≦0.75, at a first temperature in a reducing environment, and heating the composition at a second temperature in an oxidizing environment. The surface segregated material may be utilized in electrochemical devices.
摘要翻译： 提供式Ru1-xIrx的表面偏析的双金属组合物，其中0.1和nlE; x和nlE; 0.75，其中材料的表面的Ir浓度大于整个材料的Ir浓度。 表面偏析材料可以通过包括在还原环境中的第一温度下加热式Ru1-xIrx的双金属组合物，其中0.1＆lt; 1E＆gt; x＆nlE; 0.75的方法制备，并且在第二温度下在氧化 环境。 表面分离的材料可用于电化学装置中。
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公开(公告)号：US07871738B2
公开(公告)日：2011-01-18
申请号：US12338736
申请日：2008-12-18
摘要： A method of preparing a nanosegregated Pt alloy having enhanced catalytic properties. The method includes providing a sample of Pt and one or more of a transition metal in a substantially inert environment, and annealing the sample in such an environment for a period of time and at a temperature profile to form a nanosegregated Pt alloy having a Pt-skin on a surface. The resulting alloy is characterized by a plurality of compositionally oscillatory atomic layers resulting in an advantageous electronic structure with enhanced catalytic properties.
摘要翻译： 制备具有增强催化性能的纳米分离Pt合金的方法。 该方法包括在基本上惰性的环境中提供Pt和一种或多种过渡金属样品，并在这样的环境中将样品退火一段时间和温度分布，以形成具有Pt- 表面上的皮肤。 所得合金的特征在于多个组成振荡的原子层，从而形成具有增强催化性能的有利的电子结构。
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7.发明授权公开(公告)号：US08685878B2
公开(公告)日：2014-04-01
申请号：US13453782
申请日：2012-04-23
IPC分类号： H01M4/88 , B01J23/00 , B01J23/40 , B01J23/74 , B32B5/16 , B32B9/00 , B32B15/02 , B32B19/00 , B32B21/02 , B32B23/02 , B32B27/02 , H01M4/02 , H01M4/36 , H01M4/90 , H01M4/92 , C22C5/02 , C22C5/04
CPC分类号： H01M4/921 , H01M2004/028 , Y10S977/773 , Y10S977/81 , Y10S977/948 , Y10T428/12028 , Y10T428/12181 , Y10T428/12493 , Y10T428/2991
摘要： A multimetallic nanoscale catalyst having a core portion enveloped by a shell portion and exhibiting high catalytic activity and improved catalytic durability. In various embodiments, the core/shell nanoparticles comprise a gold particle coated with a catalytically active platinum bimetallic material. The shape of the nanoparticles is substantially defined by the particle shape of the core portion. The nanoparticles may be dispersed on a high surface area substrate for use as a catalyst and is characterized by no significant loss in surface area and specific activity following extended potential cycling.
摘要翻译： 一种多金属纳米级催化剂，其核心部分被外壳部分包围并显示出高催化活性和改进的催化耐久性。 在各种实施方案中，核/壳纳米颗粒包含用催化活性的铂双金属材料涂覆的金颗粒。 纳米颗粒的形状基本上由芯部分的颗粒形状限定。 纳米颗粒可以分散在高表面积底物上用作催化剂，其特征在于延长的电位循环后表面积和比活性没有明显的损失。
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8.发明授权公开(公告)号：US08178463B2
公开(公告)日：2012-05-15
申请号：US12754323
申请日：2010-04-05
IPC分类号： H01M4/88 , H01M4/02 , H01M4/36 , H01M4/92 , H01M4/90 , B01J21/18 , B01J23/00 , B01J23/40 , C22C5/04 , C22C5/02 , B32B5/16 , B32B9/00 , B32B15/02 , B32B17/02 , B32B19/00 , B32B21/02 , B32B23/02 , B32B27/02 , B32B15/00 , B22F7/00 , B22F7/02 , B22F1/02 , B23K35/36 , C25D5/10
CPC分类号： H01M4/921 , H01M2004/028 , Y10S977/773 , Y10S977/81 , Y10S977/948 , Y10T428/12028 , Y10T428/12181 , Y10T428/12493 , Y10T428/2991
摘要： A multimetallic nanoscale catalyst having a sore portion enveloped by a shell portion and exhibiting high catalytic activity and improved catalytic durability. In various embodiments, the core/shell nanoparticles comprise a gold particle coated with a catalytically active platinum bimetallic material. The shape of the nanoparticles is substantially defined by the particle shape of the core portion. The nanoparticles may be dispersed on a high surface area substrate for use as a catalyst and is characterized by no significant loss in surface area and specific activity following extended potential cycling.
摘要翻译： 一种多金属纳米尺寸催化剂，其具有由壳部分包围并具有高催化活性和改善的催化耐久性的酸洗部分。 在各种实施方案中，核/壳纳米颗粒包含用催化活性的铂双金属材料涂覆的金颗粒。 纳米颗粒的形状基本上由芯部分的颗粒形状限定。 纳米颗粒可以分散在高表面积底物上用作催化剂，其特征在于延长的电位循环后表面积和比活性没有明显的损失。
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公开(公告)号：US20110077147A1
公开(公告)日：2011-03-31
申请号：US12961870
申请日：2010-12-07
CPC分类号： H01M4/921 , B82Y30/00 , G06F19/3418 , G16H50/20 , H01M4/926
摘要： A method of preparing a nanosegregated Pt alloy having enhanced catalytic properties. The method includes providing a sample of Pt and one or more of a transition metal in a substantially inert environment, and annealing the sample in such an environment for a period of time and at a temperature profile to form a nanosegregated Pt alloy having a Pt-skin on a surface. The resulting alloy is characterized by a plurality of compositionally oscillatory atomic layers resulting in an advantageous electronic structure with enhanced catalytic properties.
摘要翻译： 制备具有增强催化性能的纳米分离Pt合金的方法。 该方法包括在基本上惰性的环境中提供Pt和一种或多种过渡金属样品，并在这样的环境中将样品退火一段时间和温度分布，以形成具有Pt- 表面上的皮肤。 所得合金的特征在于多个组成振荡的原子层，从而形成具有增强催化性能的有利的电子结构。
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公开(公告)号：US20110245068A1
公开(公告)日：2011-10-06
申请号：US12754323
申请日：2010-04-05
IPC分类号： H01M4/92 , B01J23/42 , B01J23/745 , B01J23/52
CPC分类号： H01M4/921 , H01M2004/028 , Y10S977/773 , Y10S977/81 , Y10S977/948 , Y10T428/12028 , Y10T428/12181 , Y10T428/12493 , Y10T428/2991
摘要： A multimetallic nanoscale catalyst having a sore portion enveloped by a shell portion and exhibiting high catalytic activity and improved catalytic durability. In various embodiments, the core/shell nanoparticles comprise a gold particle coated with a catalytically active platinum bimetallic material. The shape of the nanoparticles is substantially defined by the particle shape of the core portion. The nanoparticles may be dispersed on a high surface area substrate for use as a catalyst and is characterized by no significant loss in surface area and specific activity following extended potential cycling.
摘要翻译： 一种多金属纳米尺寸催化剂，其具有由壳部分包围并具有高催化活性和改善的催化耐久性的酸洗部分。 在各种实施方案中，核/壳纳米颗粒包含用催化活性的铂双金属材料涂覆的金颗粒。 纳米颗粒的形状基本上由芯部分的颗粒形状限定。 纳米颗粒可以分散在高表面积底物上用作催化剂，其特征在于延长的电位循环后表面积和比活性没有明显的损失。
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