公开(公告)号：US4902849A

公开(公告)日：1990-02-20

申请号：US307122

申请日：1989-02-06

申请人： Dwight L. McKay ,  Michael E. Olbrich

发明人： Dwight L. McKay ,  Michael E. Olbrich

IPC分类号： B01J23/00 ,  B01J23/06 ,  B01J23/62 ,  B01J23/835 ,  C07C5/333

CPC分类号： B01J23/835 ,  B01J23/005 ,  B01J23/06 ,  B01J23/622 ,  C07C5/3337

摘要： In a process for dehydrogenating alkanes containing 2-5 carbon atoms per molecule in the presence of steam and a catalyst composition comprising IIA and/or IIB metal aluminate, a noble metal and a Group IVA metal oxide, the improvement comprises the step of contacting the catalyst composition, after it has been oxidatively regenerated, with a reducing gas comprising free hydrogen and steam.

公开(公告)号：US4926005A

公开(公告)日：1990-05-15

申请号：US353849

申请日：1989-05-17

申请人： Michael E. Olbrich ,  Dwight L. McKay ,  Dean P. Montgomery, deceased ,  by B. Jean, administratrix Montgomery

发明人： Michael E. Olbrich ,  Dwight L. McKay ,  Dean P. Montgomery, deceased ,  by B. Jean, administratrix Montgomery

IPC分类号： B01J23/62 ,  B01J23/825 ,  B01J23/835 ,  C07B61/00 ,  C07C5/333 ,  C07C11/02

CPC分类号： C07C5/3335 ,  C07C5/3337

摘要： In a process for dehydrogenating alkanes having 2-5 carbon atoms per molecule in the presence of steam and a catalyst composition comprising Group IIA and/or IIB metal aluminate, Group VIII metal(s) and Group IVA metal compound(s), the improvement comprises the step of pretreating the alkane containing feed with a material comprising a Group IIA and/or Group IIB metal aluminate under non-dehydrogenating conditions.

摘要翻译： 在蒸气存在下每分子具有2-5个碳原子的烷烃和包含IIA族和/或IIB族金属铝酸盐，Ⅷ族金属和IVA族金属化合物的催化剂组合物的脱氢方法中， 包括在非脱氢条件下用含有IIA族和/或IIB族金属铝酸盐的材料预处理含烷烃的进料的步骤。

公开(公告)号：US4411777A

公开(公告)日：1983-10-25

申请号：US345516

申请日：1982-02-04

申请人： Dwight L. McKay

发明人： Dwight L. McKay

IPC分类号： B01J29/90 ,  C10G11/02 ,  C10G11/05 ,  C10G11/18

CPC分类号： C10G11/02 ,  B01J29/90

摘要： A petroleum cracking catalyst having thereon metals usually found in petroleum, e.g., iron, nickel and vanadium, is modified by addition of potassium to increase significantly the rate of hydrogen production when employing the thus-modified catalyst for cracking of petroleum.

公开(公告)号：US4367136A

公开(公告)日：1983-01-04

申请号：US274981

申请日：1981-06-18

申请人： Dwight L. McKay

发明人： Dwight L. McKay

IPC分类号： B01J23/34 ,  B01J23/92 ,  B01J29/90 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18

CPC分类号： C10G11/04 ,  B01J23/34 ,  B01J23/92 ,  B01J29/90 ,  C10G11/05

摘要： The regeneration of cracking catalyst containing both manganese and antimony in a temperature range of 1260.degree.-1280.degree. F. has been found to result in unexpected sharp maximum of the CO.sub.2 /CO ratio in the regenerator off-gas.

公开(公告)号：US4283274A

公开(公告)日：1981-08-11

申请号：US145092

申请日：1980-04-30

申请人： Brent J. Bertus ,  Dwight L. McKay

发明人： Brent J. Bertus ,  Dwight L. McKay

IPC分类号： B01J23/08 ,  B01J29/06 ,  C10G11/04 ,  C10G11/05 ,  C10G9/16

CPC分类号： C10G11/04 ,  B01J23/08 ,  B01J29/061 ,  C10G11/05

摘要： A hydrocarbon cracking catalyst treated with thallium to passivate thereon contaminating metals, e.g., vanadium, iron and/or nickel is used in a process for cracking a hydrocarbon.

摘要翻译： 用铊处理以在其上钝化污染金属例如钒，铁和/或镍的烃裂解催化剂用于裂解烃的方法。

公开(公告)号：US4264434A

公开(公告)日：1981-04-28

申请号：US58405

申请日：1979-07-17

申请人： Brent J. Bertus ,  Dwight L. McKay ,  Harold W. Mark

发明人： Brent J. Bertus ,  Dwight L. McKay ,  Harold W. Mark

IPC分类号： B01J29/90 ,  C10G11/02 ,  C10G11/06 ,  C07F9/90 ,  C10G11/18

CPC分类号： C10G11/02 ,  B01J29/90

摘要： A hydrocarbon oil cracking process in which a cracking catalyst employed has been treated with a passivating amount of an antimony tris (hydrocarbyl sulfonate), e.g., antimony tris (p-toluene sulfonate). The catalyst can be a conventional cracking catalyst, e.g., silica/alumina, zeolite, etc. The application can be conducted before and/or after the catalyst has been used to crack a hydrocarbon.

摘要翻译： 其中使用的裂化催化剂已经用钝化量的三（烃基磺酸盐）锑三（对甲苯磺酸）锑处理的烃油裂解方法。 催化剂可以是常规的裂化催化剂，例如二氧化硅/氧化铝，沸石等。应用可以在催化剂用于裂化烃之前和/或之后进行。

公开(公告)号：US4263172A

公开(公告)日：1981-04-21

申请号：US065826

申请日：1979-08-13

申请人： Dwight L. McKay

发明人： Dwight L. McKay

IPC分类号： B01J27/057 ,  C10G11/04 ,  B01J21/16 ,  B01J27/02 ,  B01J29/06

CPC分类号： C10G11/04 ,  B01J27/0573

摘要： Prevention of detrimental effects of metals such as nickel, vanadium and iron on the activity of cracking catalysts is achieved by contacting the cracking catalyst with manganese selenide. The modifying treatment of the catalyst with manganese selenide increases octane rating of the gasoline produced.

摘要翻译： 通过使裂化催化剂与硒化锰接触，可以防止镍，钒，铁等金属对裂化催化剂的有害影响。 用硒化锰改性催化剂可提高所产生汽油的辛烷值。

公开(公告)号：US4256564A

公开(公告)日：1981-03-17

申请号：US26504

申请日：1979-04-03

申请人： John S. Roberts ,  Brent J. Bertus ,  Dwight L. McKay

发明人： John S. Roberts ,  Brent J. Bertus ,  Dwight L. McKay

IPC分类号： B01J21/20 ,  B01J23/08 ,  C10G11/05 ,  C10G9/16

CPC分类号： C10G11/05 ,  B01J21/20 ,  B01J23/08 ,  Y10S502/517

摘要： A novel cracking catalyst, a method of preparing same, and an improved hydrocarbon cracking process are provided wherein the adverse effects of metals such as nickel, vanadium, iron, copper, and cobalt on the cracking catalyst are reduced by contacting the cracking catalyst with a sufficient amount of at least one indium modifier selected from the group consisting of elemental indium and indium compounds free of the element antimony.

摘要翻译： 提供了一种新的裂化催化剂，其制备方法和改进的烃裂解方法，其中通过使裂化催化剂与裂化催化剂接触，减少了镍，钒，铁，铜和钴等金属对裂化催化剂的不利影响 足够量的至少一种选自元素锑的元素铟和铟化合物的铟改性剂。

公开(公告)号：US4218337A

公开(公告)日：1980-08-19

申请号：US18690

申请日：1979-03-08

申请人： Dwight L. McKay

发明人： Dwight L. McKay

IPC分类号： B01J27/057 ,  C10G11/04 ,  B01J27/30 ,  B01J27/02 ,  B01J29/38 ,  C10G11/02

CPC分类号： B01J27/0576 ,  C10G11/04 ,  Y10S502/521

摘要： A novel cracking catalyst, a method of preparing same and an improved hydrocarbon cracking process are provided wherein adverse effects of metals such as nickel, vanadium and iron in the cracking catalyst are precluded or mitigated by contacting the cracking catalyst with at least one treating agent selected from the group consisting of elemental tellurium, oxides of tellurium and compounds convertible to elemental tellurium or oxide thereof during cracking or catalyst regeneration, whereby to said cracking catalyst is added a modifying amount of said treating agent.

摘要翻译： 提供了一种新颖的裂化催化剂，其制备方法和改进的烃裂解方法，其中通过使裂化催化剂与选择的至少一种处理剂接触来排除或减轻裂化催化剂中的镍，钒和铁等金属的不利影响 由元素碲，碲的氧化物和在裂化或催化剂再生期间可转化为元素碲或其氧化物的化合物组成的组，由此向所述裂化催化剂中加入改性量的所述处理剂。

公开(公告)号：US4209453A

公开(公告)日：1980-06-24

申请号：US926695

申请日：1978-07-25

申请人： Brent J. Bertus ,  Dwight L. McKay ,  Harold W. Mark

发明人： Brent J. Bertus ,  Dwight L. McKay ,  Harold W. Mark

IPC分类号： B01J31/18 ,  C07F9/141 ,  C10G11/02 ,  C07F9/92

CPC分类号： C10G11/02 ,  B01J31/185 ,  C07F9/141 ,  B01J2531/52 ,  Y10S502/521

摘要： A cracking catalyst is treated with an antimony tris(dihydrocarbyl phosphite) to passivate contaminating metals whenever these metals have been deposited on the catalyst. Unused or used catalyst can be treated.

摘要翻译： 每当这些金属沉积在催化剂上时，用三（二烃基亚磷酸酯）锑处理裂化催化剂以钝化污染的金属。 未使用或使用的催化剂可以处理。