-
公开(公告)号：US5382635A
公开(公告)日：1995-01-17
申请号：US129227
申请日：1993-09-29
IPC分类号： C08C19/14 , C08F8/00 , C08L15/00 , C08L63/00 , C08L67/02 , C08L69/00 , C08L75/04 , C08L77/00 , C08L101/00 , C09J175/04 , C08F8/06
CPC分类号： C08L101/00 , C08C19/14 , C08L63/00 , C08L67/02 , C08L69/00 , C08L75/04 , C08L77/00 , C09J175/04 , C08L15/00
摘要： Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.
摘要翻译： 用作各种复合聚合物体系的填料或增量剂的橡胶颗粒通过与含氯气体的气 - 固相反应进行氯化。 含有氯化橡胶填料或增量剂的复合聚合物显示出比使用未氯化橡胶填料或增量剂制备的弯曲模量更高的挠曲模量。 通过使细碎的橡胶颗粒与包含至少约5体积％氯的含氯气体接触来进行橡胶颗粒的氯化。 有利地，氯可以用空气，氮气或其它基本上惰性气体稀释，并且可以含有少量的氟。 通过空气稀释的氯气氮稀释获得了改进的性能。 具有较高弯曲模量的改进的聚合物复合体系是由于使用氯化橡胶颗粒作为填料代替未氯化橡胶颗粒。
-
公开(公告)号：US5506283A
公开(公告)日：1996-04-09
申请号：US344097
申请日：1994-11-23
IPC分类号： C08C19/14 , C08F8/00 , C08L15/00 , C08L63/00 , C08L67/02 , C08L69/00 , C08L75/04 , C08L77/00 , C08L101/00 , C09J175/04 , C08F8/22
CPC分类号： C08L101/00 , C08C19/14 , C08L63/00 , C08L67/02 , C08L69/00 , C08L75/04 , C08L77/00 , C09J175/04 , C08L15/00
摘要： Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.
-
公开(公告)号：US5969053A
公开(公告)日：1999-10-19
申请号：US824704
申请日：1997-04-14
IPC分类号： C08C19/12 , C08C19/14 , C08F8/00 , C08F8/20 , C08J7/12 , C08L15/00 , C08L23/16 , C08L63/00 , C08L67/02 , C08L67/06 , C08L69/00 , C08L75/04 , C08L77/00 , C08L101/00 , C09D175/04 , C09J175/04 , C08F8/22 , C08F8/34
CPC分类号： C08C19/12 , C08C19/14 , C08J7/12 , C08J7/126 , C08L101/00 , C08L23/16 , C08L63/00 , C08L67/02 , C08L67/06 , C08L69/00 , C08L75/04 , C08L77/00 , C09D175/04 , C09J175/04 , C08L15/00 , Y10T428/31786 , Y10T428/31855
摘要： A plastic article having a number of surfaces with at least one surface being modified by contacting that surface with a reactive gas atmosphere containing F.sub.2, Cl.sub.2, O.sub.2, Ozone, SO.sub.3, oxidative acids, or mixtures thereof, at a temperature and gas partial pressure sufficient to increase the surface energy of the at least one surface being modified to at least 40 dynes/cm at a temperature of 20.degree. C., to enhance bonding of non-slip polymer coatings to the modified surface, to which coatings elastomeric or rigid particles may be admixed for imparting a surface profile and increasing the coefficient of friction between the coated surface and the counter-surface.
摘要翻译： 通过使表面与含有F2，Cl2，O 2，臭氧，SO 3，氧化酸或其混合物的反应气体气氛接触，具有至少一个表面的多个表面的塑料制品在足够的温度和气体分压下 以在20℃的温度下将至少一个表面的表面能增加至至少40达因/厘米，以增强防滑聚合物涂层与改性表面的结合，涂层弹性体或刚性颗粒 可以混合以赋予表面轮廓并增加涂覆表面和对置表面之间的摩擦系数。
-
公开(公告)号：US4752428A
公开(公告)日：1988-06-21
申请号：US7690
申请日：1987-01-28
IPC分类号： B29C45/00 , B29C37/00 , B29C45/17 , B29C45/18 , B29C49/06 , B29C49/42 , B29K23/00 , C08J5/00 , C08J5/12 , B29C33/10
CPC分类号： C08J5/124 , B29C37/0057 , B29C45/1701 , C08J5/00 , B29C2791/005 , C08J2323/12
摘要： The present invention is a process for making shaped articles by injecting a thermoplastic or thermoset polymer into a mold cavity in which is maintained at atmosphere containing between 0.1 mole % and 50 mole % F.sub.2 and at least 20 ppm O.sub.2 while said polymer is being injected into the mold. The process results in shaped articles having altered physical and chemical characteristics. A weld line formed where two interfaces of the polymer are joined in the mold cavity serves as a clean break point when pressure is applied to an article formed by the process. The atmosphere in the mold cavity may contain SO.sub.3.
-
公开(公告)号：US5693714A
公开(公告)日：1997-12-02
申请号：US609520
申请日：1996-03-01
IPC分类号： C08C19/12 , C08F8/00 , C08F8/20 , C08L23/16 , C08L63/00 , C08L67/06 , C08L75/04 , C08L101/00 , C09D175/04 , C09J175/04
CPC分类号： C09D175/04 , C08C19/12 , C08L101/00 , C08L23/0853 , C08L23/16 , C08L63/00 , C08L67/06 , C08L75/04 , C09J175/04
摘要： Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.
摘要翻译： 用作各种复合聚合物体系的填料或增量剂的橡胶颗粒通过与含氯气体的气 - 固相反应进行氯化。 含有氯化橡胶填料或增量剂的复合聚合物显示出比使用未氯化橡胶填料或增量剂制备的弯曲模量更高的挠曲模量。 通过使细碎的橡胶颗粒与包含至少约5体积％氯的含氯气体接触来进行橡胶颗粒的氯化。 有利地，氯可以用空气，氮气或其它基本上惰性气体稀释，并且可以含有少量的氟。 通过空气稀释的氯气氮稀释获得了改进的性能。 具有较高弯曲模量的改进的聚合物复合体系是由于使用氯化橡胶颗粒作为填料代替未氯化橡胶颗粒。
-
公开(公告)号：US4800053A
公开(公告)日：1989-01-24
申请号：US186322
申请日：1988-04-26
CPC分类号： C08J5/124 , B29C37/0057 , B29C45/1701 , B29C59/00 , C08J5/00 , B29C2791/005 , C08J2323/12
摘要： A process for making shaped articles by injecting a thermoplastic or thermoset polymer into a mold cavity in which is maintained a reactive atmosphere containing between 0.1 mole % and 50 mole % F.sub.2 and at least 20 ppm O.sub.2 while the polymer is being injected into the mold, such that any portion of the polymer contacts the reactive atmosphere for a time not greater than 0.5 sec.
摘要翻译： 一种通过将热塑性或热固性聚合物注射到模腔中来制造成形制品的方法，其中在将聚合物注入模具中时，其保持含有0.1摩尔％至50摩尔％F 2和至少20ppm O 2的反应气氛， 使得聚合物的任何部分与反应性气氛接触不超过0.5秒的时间。
-
公开(公告)号：US4764405A
公开(公告)日：1988-08-16
申请号：US76457
申请日：1987-07-22
IPC分类号： B05D7/02 , B05D3/04 , B29C49/24 , B29C49/46 , B32B27/08 , B32B27/28 , B32B27/30 , B65D25/14 , C08J7/04 , C08J7/12 , B05D3/00 , B65D23/02
CPC分类号： B05D3/0446 , B29C49/46 , C08J7/047 , C08J7/12 , C08J7/126 , B29C2049/4617 , B29C2049/4623 , B29K2995/0067 , Y10T428/1379 , Y10T428/31507 , Y10T428/3154 , Y10T428/31573 , Y10T428/31797 , Y10T428/31913 , Y10T428/3192
摘要： The present invention is a method for improving the barrier properties of thermoplastic substrates. A surface of the thermoplastic substrate is contacted with a reactive gas stream having an F.sub.2 concentration greater than or equivalent to 0.0001 atm. partial pressure of F.sub.2 per atm. total pressure and sufficient oxygen such that the F.sub.2 /O.sub.2 ratio is less than or equal to about 100, with the remainder being additional reactive and/or non-reactive components. A barrier coating material is applied to the treated surface of the substrate and subsequently undergoes a curing step to form the final product.
-
公开(公告)号：US4420591A
公开(公告)日：1983-12-13
申请号：US365117
申请日：1982-04-05
CPC分类号： C08F2/004
摘要： This invention relates to an improvement for reducing the amount of wall fouling in the suspension polymerization of vinyl chloride. The improvement resides in wetting the reactor surface with a solution containing selenous acid prior to charging the vinyl chloride recipe to the reactor. Preferably, the surface of the resulting reactor is heated at a temperature of from 40.degree.-100.degree. C. prior to charging the recipe.
摘要翻译： 本发明涉及减少氯乙烯悬浮聚合中壁污染量的改进。 改进在于在将氯乙烯配方装入反应器之前用含有硒酸的溶液润湿反应器表面。 优选地，在充填配方之前，将所得反应器的表面在40℃-100℃的温度下加热。
-
9.发明申请System for adhesion treatment, coating and curing of wood polymer composites 审中-公开木材聚合物复合材料的粘合处理，涂层和固化系统公开(公告)号：US20090130314A1
公开(公告)日：2009-05-21
申请号：US12313416
申请日：2008-11-19
IPC分类号： B05D3/10
摘要： The present invention describes a system for modifying polymer composite surfaces to achieve 100% adhesion to paints, coatings, adhesives, or inks. The adhesion modification technology overcomes the deficiencies of energy-based treatment technologies common with wood-like polymer composites produced using various types of fillers and reinforcements, and specifically those containing cellulose and lignin.
摘要翻译： 本发明描述了一种用于改进聚合物复合材料表面以实现与油漆，涂料，粘合剂或油墨100％粘附的系统。 粘合改性技术克服了使用各种类型的填料和增强材料生产的木质聚合物复合材料，特别是含有纤维素和木质素的能量基处理技术的缺点。
-
10.发明授权Polymeric materials having controlled physical properties and processes for obtaining these 失效具有受控物理性质的聚合材料和获得这些物质的方法
公开(公告)号：US4771110A
公开(公告)日：1988-09-13
申请号：US825839
申请日：1986-02-04
IPC分类号： C08J3/00 , C08C19/14 , C08F8/00 , C08F8/22 , C08G18/06 , C08G18/08 , C08G18/69 , C08G85/00 , C08J3/20 , C08J9/00 , C08J11/04 , C08L7/00 , C08L21/00 , C08L23/00 , C08L67/00 , C08L75/00 , C08L101/00 , C08L75/04
CPC分类号： C08J9/0061 , C08C19/14 , C08F8/22 , C08G18/06 , C08G18/69 , C08G85/00 , C08J11/04 , C08J2375/04 , Y02P20/143 , Y02W30/70
摘要： Ground polymer elastomer or other polymeric plastic, particularly from recovered scrap, is surface modified by treatment with a gaseous mixture containing a minor amount of fluorine and a larger amount of at least one reactive gas in an inert gaseous carrier. By the treatment the ground material is made more compatible for admixture with polyfunctional polymer-forming liquids, thereby obtaining novel composites of controlled physical properties. The other reactive gas is preferably oxygen or one of the gases from the group consisting of: chlorine and SO.sub.2 with or without added oxygen.
摘要翻译： 研磨聚合物弹性体或其他聚合物塑料，特别是回收的废料，通过在惰性气态载体中用含少量氟和更多量的至少一种反应性气体的气态混合物进行处理来进行表面改性。 通过处理使研磨材料与多官能聚合物形成液体的混合更加相容，从而获得具有受控物理性质的新型复合材料。 其它反应性气体优选为氧气或来自由具有或不具有添加氧气的氯和SO 2组成的组中的一种气体。
-
-
-
-
-
-
-
-
-
搜索结果
20 条记录 (耗时 0.029 秒)
