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公开(公告)号：US4752428A
公开(公告)日：1988-06-21
申请号：US7690
申请日：1987-01-28
IPC分类号： B29C45/00 , B29C37/00 , B29C45/17 , B29C45/18 , B29C49/06 , B29C49/42 , B29K23/00 , C08J5/00 , C08J5/12 , B29C33/10
CPC分类号： C08J5/124 , B29C37/0057 , B29C45/1701 , C08J5/00 , B29C2791/005 , C08J2323/12
摘要： The present invention is a process for making shaped articles by injecting a thermoplastic or thermoset polymer into a mold cavity in which is maintained at atmosphere containing between 0.1 mole % and 50 mole % F.sub.2 and at least 20 ppm O.sub.2 while said polymer is being injected into the mold. The process results in shaped articles having altered physical and chemical characteristics. A weld line formed where two interfaces of the polymer are joined in the mold cavity serves as a clean break point when pressure is applied to an article formed by the process. The atmosphere in the mold cavity may contain SO.sub.3.
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公开(公告)号：US4800053A
公开(公告)日：1989-01-24
申请号：US186322
申请日：1988-04-26
CPC分类号： C08J5/124 , B29C37/0057 , B29C45/1701 , B29C59/00 , C08J5/00 , B29C2791/005 , C08J2323/12
摘要： A process for making shaped articles by injecting a thermoplastic or thermoset polymer into a mold cavity in which is maintained a reactive atmosphere containing between 0.1 mole % and 50 mole % F.sub.2 and at least 20 ppm O.sub.2 while the polymer is being injected into the mold, such that any portion of the polymer contacts the reactive atmosphere for a time not greater than 0.5 sec.
摘要翻译： 一种通过将热塑性或热固性聚合物注射到模腔中来制造成形制品的方法，其中在将聚合物注入模具中时，其保持含有0.1摩尔％至50摩尔％F 2和至少20ppm O 2的反应气氛， 使得聚合物的任何部分与反应性气氛接触不超过0.5秒的时间。
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公开(公告)号：US5382635A
公开(公告)日：1995-01-17
申请号：US129227
申请日：1993-09-29
IPC分类号： C08C19/14 , C08F8/00 , C08L15/00 , C08L63/00 , C08L67/02 , C08L69/00 , C08L75/04 , C08L77/00 , C08L101/00 , C09J175/04 , C08F8/06
CPC分类号： C08L101/00 , C08C19/14 , C08L63/00 , C08L67/02 , C08L69/00 , C08L75/04 , C08L77/00 , C09J175/04 , C08L15/00
摘要： Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.
摘要翻译： 用作各种复合聚合物体系的填料或增量剂的橡胶颗粒通过与含氯气体的气 - 固相反应进行氯化。 含有氯化橡胶填料或增量剂的复合聚合物显示出比使用未氯化橡胶填料或增量剂制备的弯曲模量更高的挠曲模量。 通过使细碎的橡胶颗粒与包含至少约5体积％氯的含氯气体接触来进行橡胶颗粒的氯化。 有利地，氯可以用空气，氮气或其它基本上惰性气体稀释，并且可以含有少量的氟。 通过空气稀释的氯气氮稀释获得了改进的性能。 具有较高弯曲模量的改进的聚合物复合体系是由于使用氯化橡胶颗粒作为填料代替未氯化橡胶颗粒。
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公开(公告)号：US5969053A
公开(公告)日：1999-10-19
申请号：US824704
申请日：1997-04-14
IPC分类号： C08C19/12 , C08C19/14 , C08F8/00 , C08F8/20 , C08J7/12 , C08L15/00 , C08L23/16 , C08L63/00 , C08L67/02 , C08L67/06 , C08L69/00 , C08L75/04 , C08L77/00 , C08L101/00 , C09D175/04 , C09J175/04 , C08F8/22 , C08F8/34
CPC分类号： C08C19/12 , C08C19/14 , C08J7/12 , C08J7/126 , C08L101/00 , C08L23/16 , C08L63/00 , C08L67/02 , C08L67/06 , C08L69/00 , C08L75/04 , C08L77/00 , C09D175/04 , C09J175/04 , C08L15/00 , Y10T428/31786 , Y10T428/31855
摘要： A plastic article having a number of surfaces with at least one surface being modified by contacting that surface with a reactive gas atmosphere containing F.sub.2, Cl.sub.2, O.sub.2, Ozone, SO.sub.3, oxidative acids, or mixtures thereof, at a temperature and gas partial pressure sufficient to increase the surface energy of the at least one surface being modified to at least 40 dynes/cm at a temperature of 20.degree. C., to enhance bonding of non-slip polymer coatings to the modified surface, to which coatings elastomeric or rigid particles may be admixed for imparting a surface profile and increasing the coefficient of friction between the coated surface and the counter-surface.
摘要翻译： 通过使表面与含有F2，Cl2，O 2，臭氧，SO 3，氧化酸或其混合物的反应气体气氛接触，具有至少一个表面的多个表面的塑料制品在足够的温度和气体分压下 以在20℃的温度下将至少一个表面的表面能增加至至少40达因/厘米，以增强防滑聚合物涂层与改性表面的结合，涂层弹性体或刚性颗粒 可以混合以赋予表面轮廓并增加涂覆表面和对置表面之间的摩擦系数。
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公开(公告)号：US5506283A
公开(公告)日：1996-04-09
申请号：US344097
申请日：1994-11-23
IPC分类号： C08C19/14 , C08F8/00 , C08L15/00 , C08L63/00 , C08L67/02 , C08L69/00 , C08L75/04 , C08L77/00 , C08L101/00 , C09J175/04 , C08F8/22
CPC分类号： C08L101/00 , C08C19/14 , C08L63/00 , C08L67/02 , C08L69/00 , C08L75/04 , C08L77/00 , C09J175/04 , C08L15/00
摘要： Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.
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公开(公告)号：US5693714A
公开(公告)日：1997-12-02
申请号：US609520
申请日：1996-03-01
IPC分类号： C08C19/12 , C08F8/00 , C08F8/20 , C08L23/16 , C08L63/00 , C08L67/06 , C08L75/04 , C08L101/00 , C09D175/04 , C09J175/04
CPC分类号： C09D175/04 , C08C19/12 , C08L101/00 , C08L23/0853 , C08L23/16 , C08L63/00 , C08L67/06 , C08L75/04 , C09J175/04
摘要： Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.
摘要翻译： 用作各种复合聚合物体系的填料或增量剂的橡胶颗粒通过与含氯气体的气 - 固相反应进行氯化。 含有氯化橡胶填料或增量剂的复合聚合物显示出比使用未氯化橡胶填料或增量剂制备的弯曲模量更高的挠曲模量。 通过使细碎的橡胶颗粒与包含至少约5体积％氯的含氯气体接触来进行橡胶颗粒的氯化。 有利地，氯可以用空气，氮气或其它基本上惰性气体稀释，并且可以含有少量的氟。 通过空气稀释的氯气氮稀释获得了改进的性能。 具有较高弯曲模量的改进的聚合物复合体系是由于使用氯化橡胶颗粒作为填料代替未氯化橡胶颗粒。
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公开(公告)号：US4764405A
公开(公告)日：1988-08-16
申请号：US76457
申请日：1987-07-22
IPC分类号： B05D7/02 , B05D3/04 , B29C49/24 , B29C49/46 , B32B27/08 , B32B27/28 , B32B27/30 , B65D25/14 , C08J7/04 , C08J7/12 , B05D3/00 , B65D23/02
CPC分类号： B05D3/0446 , B29C49/46 , C08J7/047 , C08J7/12 , C08J7/126 , B29C2049/4617 , B29C2049/4623 , B29K2995/0067 , Y10T428/1379 , Y10T428/31507 , Y10T428/3154 , Y10T428/31573 , Y10T428/31797 , Y10T428/31913 , Y10T428/3192
摘要： The present invention is a method for improving the barrier properties of thermoplastic substrates. A surface of the thermoplastic substrate is contacted with a reactive gas stream having an F.sub.2 concentration greater than or equivalent to 0.0001 atm. partial pressure of F.sub.2 per atm. total pressure and sufficient oxygen such that the F.sub.2 /O.sub.2 ratio is less than or equal to about 100, with the remainder being additional reactive and/or non-reactive components. A barrier coating material is applied to the treated surface of the substrate and subsequently undergoes a curing step to form the final product.
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公开(公告)号：US20120246798A1
公开(公告)日：2012-10-04
申请号：US13469545
申请日：2012-05-11
申请人： Mark A. Williams , Jeffrey A. Klein
发明人： Mark A. Williams , Jeffrey A. Klein
IPC分类号： A41D19/00
CPC分类号： A41D19/0006 , A41D19/001 , A41D27/245 , A41D2400/22 , A43B7/125 , B32B7/12 , B32B27/08 , B32B27/12 , B32B27/322 , B32B27/40
摘要： The present invention provides waterproof, breathable non-textile seamed articles which exhibit high levels of durability and allow wearers a high level of flexibility and article strength. This invention is of particular interest for use in dexterous hand coverings and conformable foot coverings.
摘要翻译： 本发明提供了具有高水平的耐久性的耐水透气非纺织品缝合制品，并且使得穿着者具有高水平的柔韧性和制品强度。 本发明特别令人感兴趣的是用于灵巧的手部护理和适形的脚部覆盖物。
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公开(公告)号：US08112820B2
公开(公告)日：2012-02-14
申请号：US11522489
申请日：2006-09-14
IPC分类号： A41D19/00
CPC分类号： A41D19/0089 , A41D13/0005
摘要： A protective sealing system with a barrier seal between two articles of apparel is provided. The system has at least two elastomeric cuffs securable to a sealing support oriented between wearer of garment and both the first cuff and the second elastomeric cuff to expand said cuffs providing a double barrier seal.
摘要翻译： 提供了一种在两件服装之间具有屏障密封的保护性密封系统。 该系统具有至少两个可固定到衣服穿戴者与第一箍和第二弹性箍之间的密封支撑的弹性箍，以扩展所述袖口以提供双重屏障密封。
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公开(公告)号：US5802667A
公开(公告)日：1998-09-08
申请号：US711220
申请日：1996-09-09
申请人： Mark A. Williams
发明人： Mark A. Williams
CPC分类号： F28G3/04 , A46B13/02 , B08B9/0436 , B08B9/045 , F23J3/026
摘要： A duct cleaning device, including a flexible conduit with a first, inlet end and a second, outlet end. An end cap with a central hole is attached to the first end; a connector adapted for coupling the device to a vacuum hose (or the inlet of a vacuum cleaner) is attached to the second end. A flexible, radially-projecting brush is attached to the exterior of the conduit, extending helically about the conduit; a plurality of throughholes (some of which carry flexible, radially-projecting tubes) are positioned near the brush. In operation, the device is connected to a source of vacuum. The first end is rotated while being moved into (or removed from) a duct, while the brush sweeps the interior surface of the duct to dislodge particulates of house dust and other contaminants from the surface. The particulates are swept into the conduit through the hole in the end cap and the throughholes in the conduit. The conduit and the brush are flexible, so the device can readily traverse offsets and bends in duct systems without damaging flexible plastic or fiberglass ducts.
摘要翻译： 管道清洁装置，包括具有第一入口端和第二出口端的柔性管道。 具有中心孔的端盖连接到第一端; 适于将设备耦合到真空软管（或真空吸尘器的入口）的连接器附接到第二端。 柔性的径向伸出的刷子附接到导管的外部，螺旋地围绕导管延伸; 多个通孔（其中一些带有柔性的径向突出的管）位于刷子附近。 在操作中，该装置连接到真空源。 第一端在被移动（或从管道中移除）的同时旋转，同时刷子扫过管道的内表面以从表面移除房屋灰尘和其它污染物的微粒。 颗粒通过端盖中的孔和管道中的通孔扫入导管。 导管和刷子是柔性的，因此该装置可以容易地在管道系统中横穿偏移和弯曲而不损坏柔性塑料或玻璃纤维导管。
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