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    CATALYTIC HYDRODEOXYGENATION OF AN OXYGENATE FEEDSTOCK
    1.
    发明申请
    CATALYTIC HYDRODEOXYGENATION OF AN OXYGENATE FEEDSTOCK 有权
    催化氢氧化反应的氧化反应

    公开(公告)号：US20100043278A1

    公开(公告)日：2010-02-25

    申请号：US11911168

    申请日：2007-06-09

    申请人： Eelko Brevoord ,  Robertus Gerardus Leliveld ,  Stephan Janbroers

    发明人： Eelko Brevoord ,  Robertus Gerardus Leliveld ,  Stephan Janbroers

    IPC分类号： C10L1/188

    CPC分类号： B01J23/85 ,  B01J23/883 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/1011 ,  C10G2300/207 ,  C10G2300/4018 ,  C11C3/123 ,  Y02P30/20

    摘要： A method for the hydrodeoxygenation of an oxygenate feedstock comprising contacting the feedstock with a sulphided catalyst composition under hydrodeoxygenation conditions, wherein the catalyst composition comprises: i) a porous carrier substantially comprised of alumina, the carrier comprising between about 0.001 and about 1 wt. % phosphorous and between about 0.001 and about 1 wt. % silicon (both calculated as oxides) and having a mean pore diameter in the range from about 5 nm to about 40 nm; and, ii) from about 1 to about 20 wt. % of an active metal component (calculated as oxides based on the weight of the composition) borne on said porous carrier and which comprises at least one Group VIB metal and at least one Group VIII metal.

    摘要翻译： 一种用于含氧化合物原料的加氢脱氧的方法，包括在加氢脱氧条件下使原料与硫化催化剂组合物接触，其中催化剂组合物包含：i）基本上由氧化铝组成的多孔载体，载体包含约0.001至约1wt。 ％磷，约0.001至约1wt。 ％硅（均计算为氧化物），平均孔径在约5nm至约40nm的范围内; 和，ii）约1至约20wt。 ％的活性金属组分（以基于组合物重量的氧化物计算）承载在所述多孔载体上，并且包含至少一种VIB族金属和至少一种第Ⅷ族金属。

    Bulk catalyst comprising metal oxidic particles and a process for the manufacture thereof
    8.
    发明授权
    Bulk catalyst comprising metal oxidic particles and a process for the manufacture thereof 有权
    包含金属氧化物颗粒的散装催化剂及其制造方法

    公开(公告)号：US08394263B2

    公开(公告)日：2013-03-12

    申请号：US12091327

    申请日：2006-10-25

    申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

    发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

    IPC分类号： B01J23/755

    CPC分类号： B01J37/20 ,  B01J23/85 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/10 ,  C10G45/08 ,  C10G2300/202

    摘要： The invention relates to a bulk catalyst having improved activity in hydrodesulphurization, in particular in relatively low Group VIII over Group VIB metal molar ratios. The bulk catalyst comprises metal oxidic particles comprising one or more Group VIB metals and one or more-Group VIII metals which metal oxidic particles are obtainable by a process comprising the steps of reacting the compounds comprising one or more Group VIB metals and compounds comprising one or more Group VIII metals in hydrothermal conditions at a reaction temperature above the boiling temperature of the protic liquid, preferably in an autoclave at a reaction pressure above atmospheric pressure and. The invention also relates to the corresponding sulphided catalyst, to a process for the manufacture of said bulk catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurization and hydrodenitrogenation of hydrocarbon feedstock.

    摘要翻译： 本发明涉及具有改进的加氢脱硫活性的本体催化剂，特别是在VIB族金属摩尔比相对较低的第VIII族。 本体催化剂包含包含一种或多种VIB族金属和一种或多种VIII族金属的金属氧化物颗粒，该金属氧化物颗粒可通过包括以下步骤的方法获得，所述方法包括使包含一种或多种VIB族金属的化合物与包含一种或多种 反应温度高于质子液体沸点温度的水热条件下，优选在反应压力高于大气压的高压釜中。 本发明还涉及相应的硫化催化剂，制备所述本体催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。