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    Liquid Stable Thiol-Acrylate/Vinyl Ether Compositions
    1.
    发明申请
    Liquid Stable Thiol-Acrylate/Vinyl Ether Compositions 审中-公开
    液体稳定的硫醇 - 丙烯酸酯/乙烯基醚组合物

    公开(公告)号：US20100105795A1

    公开(公告)日：2010-04-29

    申请号：US11814536

    申请日：2005-11-11

    申请人： Eerik Maandi ,  Edwin Perez ,  John G. Woods ,  Joel D. Schall ,  Seamus Grant

    发明人： Eerik Maandi ,  Edwin Perez ,  John G. Woods ,  Joel D. Schall ,  Seamus Grant

    IPC分类号： C08L75/00 ,  C08G75/00 ,  C08F2/46 ,  C08G18/00 ,  C08G18/63

    CPC分类号： C08F222/1006

    摘要： The present invention relates to liquid stable thiol-acrylate and thiol-vinyl ether compositions. More particularly, in accordance with some embodiments, the compositions may include a (meth)acrylate, a thiol component, an organic acid stabilizer, and a curing initiator. In other embodiments, the compositions may include a curable component selected from a (meth)acrylate, vinyl ether and/or alkenyl ether, a reactive diluent having vinyl ether and acrylate functionality, a thiol component and a stabilizer selected from an organic acid, a hemiacetal ester derivative of an organic acid and/or a phenol acetal.

    摘要翻译： 本发明涉及液体稳定的硫醇 - 丙烯酸酯和硫醇 - 乙烯基醚组合物。 更具体地，根据一些实施方案，组合物可以包括（甲基）丙烯酸酯，硫醇组分，有机酸稳定剂和固化引发剂。 在其它实施方案中，组合物可以包括选自（甲基）丙烯酸酯，乙烯基醚和/或烯基醚的可固化组分，具有乙烯基醚和丙烯酸酯官能团的反应性稀释剂，硫醇组分和选自有机酸， 有机酸的半缩醛酯衍生物和/或酚缩醛。

    Anaerobic compositions which expand when post-cured
    4.
    发明授权
    Anaerobic compositions which expand when post-cured 失效
    厌氧组合物在治愈后膨胀

    公开(公告)号：US5373075A

    公开(公告)日：1994-12-13

    申请号：US189686

    申请日：1994-02-01

    申请人： Eerik Maandi ,  Richard D. Rich

    发明人： Eerik Maandi ,  Richard D. Rich

    IPC分类号： C08F220/28 ,  C08F2/02 ,  C08F20/10 ,  C08F22/36 ,  C08F222/40 ,  C08F290/00 ,  C08F299/02 ,  C09J4/00 ,  C09J4/02 ,  C08F22/40

    CPC分类号： C09J4/00

    摘要： An adhesive composition capable of post-cure expansion comprising a multifunctional (meth)acrylate and a maleimide capable of effectuating expansion upon post-cure. A homogeneous mixture of a monomer and maleimide are subjected to a first cure heat stage wherein a rigid partially-cured plastic is formed and a post-cure heart stage to effectuate permanent expansion of the cured adhesive composition.

    摘要翻译： 一种能够后固化膨胀的粘合剂组合物，其包含多官能（甲基）丙烯酸酯和能够在后固化后实现膨胀的马来酰亚胺。 将单体和马来酰亚胺的均匀混合物进行第一固化加热阶段，其中形成刚性部分固化的塑料和后固化心脏阶段以实现固化的粘合剂组合物的永久膨胀。

    Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces
    6.
    发明授权
    Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces 失效
    具有粘附于低能量表面的不可燃和不可燃的粘合剂粘合系统

    公开(公告)号：US06867271B1

    公开(公告)日：2005-03-15

    申请号：US10437031

    申请日：2003-05-14

    申请人： Eerik Maandi ,  Brendan J. Kneafsey

    发明人： Eerik Maandi ,  Brendan J. Kneafsey

    IPC分类号： C08F4/12

    CPC分类号： C08F4/52 ,  C09D4/00 ,  C09D133/08

    摘要： This invention relates to (meth)acrylate based polymerizable compositions and multipart adhesive systems prepared therefrom, which include an aziridine-containing compound in a carrier material with which the aziridine-containing compound is unreactive. The inventive composition demonstrates a flash point above 140° F., desirably above 200° F., for each of the parts of the adhesive system. To achieve the physical properties of the inventive compositions and adhesive systems, it is desirable for the carrier material to have such flash points; however, provided that in their entirety the inventive compositions and adhesive systems have such flash points, it is not necessary for the carrier material itself to have such flash points. The inventive compositions and adhesive systems also include a package for controlling the rate of cure and indicating the extent of cure. The inventive compositions and adhesive systems are particularly well suited to bonding applications which involve at least one low energy bonding surface, for example, polyolefin, polyethylene, and polypropylene surfaces.

    摘要翻译： 本发明涉及由（甲基）丙烯酸酯系聚合的组合物和由其制备的多部分粘合剂体系，其包括在含氮丙啶的化合物不反应的载体材料中的含氮丙啶的化合物。 本发明的组合物对于粘合剂体系的每个部分显示高于140°F的闪点，优选高于200°F。 为了达到本发明组合物和粘合剂体系的物理性能，载体材料最好具有这样的闪点; 然而，只要本发明的组合物和粘合剂体系全部具有这样的闪点，载体材料本身就不必具有这样的闪点。 本发明的组合物和粘合剂体系还包括用于控制固化速率并指示固化程度的包装。 本发明的组合物和粘合剂体系特别适用于涉及至少一个低能量结合表面的粘合应用，例如聚烯烃，聚乙烯和聚丙烯表面。

    Bonding system having adherence to low energy surfaces
    7.
    发明授权
    Bonding system having adherence to low energy surfaces 失效
    粘合系统具有坚固的低能量表面

    公开(公告)号：US06632908B1

    公开(公告)日：2003-10-14

    申请号：US10094817

    申请日：2002-03-12

    申请人： Eerik Maandi

    发明人： Eerik Maandi

    IPC分类号： C08F11802

    CPC分类号： C08F290/062

    摘要： The present invention is directed to (meth)acrylate compositions useful for bonding substrates including metals, plastics, and glass to similar or different substrates, in particular, low energy surfaces. The invention also provides an initiator system for (meth)acrylate based adhesives; a kit for bonding substrates, at least one of which includes a low energy surface; a resultant bonded assembly; and a method of bonding low energy substrates. A (meth)acrylate composition within the present invention includes a (meth)acrylate component and an initiator system including an organometallic compound, a peroxy compound, an aziridine functionalized compound, and a compound having an acid functional group.

    摘要翻译： 本发明涉及用于将包括金属，塑料和玻璃的基材粘合到相似或不同的基材，特别是低能量表面的（甲基）丙烯酸酯组合物。 本发明还提供了一种（甲基）丙烯酸酯基粘合剂的引发剂体系; 用于接合基板的套件，其中至少一个包括低能量表面; 合成的粘合组件; 以及键合低能量基板的方法。 本发明中的（甲基）丙烯酸酯组合物包括（甲基）丙烯酸酯组分和包含有机金属化合物，过氧化合物，氮丙啶官能化化合物和具有酸官能团的化合物的引发剂体系。

    Preapplied silicone threadlocker and sealant
    8.
    发明授权
    Preapplied silicone threadlocker and sealant 失效
    预涂硅胶螺纹锁和密封剂

    公开(公告)号：US5853520A

    公开(公告)日：1998-12-29

    申请号：US788724

    申请日：1997-01-23

    申请人： Richard D. Rich ,  Eerik Maandi ,  Paula M. Gontarz ,  Hsien-Kun Chu

    发明人： Richard D. Rich ,  Eerik Maandi ,  Paula M. Gontarz ,  Hsien-Kun Chu

    IPC分类号： C08K9/10 ,  C09J4/00 ,  C09J4/02 ,  C09J5/00 ,  C09J183/06 ,  C09J183/07 ,  F16B39/00

    CPC分类号： C09J4/00 ,  C08K9/10 ,  C09J183/06

    摘要： A curable composition, having utility for threadlocking engageable members of a threaded mechanical fastener, comprising: a reactive silicone (meth)acrylate emulsified in an aqueous medium, optionally further comprising a polymerizable non-silicone (meth)acrylate monomer or oligomer; and a microencapsulated peroxy initiator which is initiatingly effective for cure of the reactive silicone (meth)acrylate. The curable composition may be usefully employed for adhesively bonding engageable structural parts, by applying the aqueous emulsion of the reactive silicone (meth)acrylate, containing a microencapsulated peroxy initiator, to at least a portion of an engagement surface of a matable part which is matably engageable with a complimentary engagement structure, to yield an emulsion-coated engagement surface, drying the emulsion-coated engagement surface to form a dried coating thereon; and thereafter engaging the surface having the dried coating thereon, with the complimentary engagement structure, to release the microencapsulated peroxy initiator and bond the matable part and complimentary engagement structure.

    摘要翻译： 一种可固化组合物，其用于螺纹机械紧固件的可接合构件的螺纹锁定，包括：在水性介质中乳化的反应性硅氧烷（甲基）丙烯酸酯，任选地还包含可聚合的非硅氧烷（甲基）丙烯酸酯单体或低聚物; 和对于反应性硅氧烷（甲基）丙烯酸酯的固化起始有效的微胶囊化过氧化引发剂。 可固化组合物可用于粘合可接合的结构部件，通过将含有微胶囊化过氧化物引发剂的反应性硅氧烷（甲基）丙烯酸酯的水性乳液施用于可配合的可配配部分的接合表面的至少一部分 可接合互补的接合结构，以产生乳液涂覆的接合表面，干燥乳液涂覆的接合表面以在其上形成干燥的涂层; 然后将其上具有干燥涂层的表面与互补的接合结构接合，以释放微胶囊化的过氧化物引发剂并结合可配合部分和互补的接合结构。

    Anaerobic compositions which expand when post-cured
    9.
    发明授权
    Anaerobic compositions which expand when post-cured 失效
    厌氧组合物在治愈后膨胀

    公开(公告)号：US5302679A

    公开(公告)日：1994-04-12

    申请号：US926344

    申请日：1992-08-06

    申请人： Eerik Maandi ,  Richard D. Rich

    发明人： Eerik Maandi ,  Richard D. Rich

    IPC分类号： C08F220/28 ,  C08F2/02 ,  C08F20/10 ,  C08F22/36 ,  C08F222/40 ,  C08F290/00 ,  C08F299/02 ,  C09J4/00 ,  C09J4/02 ,  C08F22/40

    CPC分类号： C09J4/00

    摘要： An adhesive composition capable of post-cure expansion comprising a multifunctional methacrylate and a maleimide capable of effectuating expansion upon post-cure. A homogeneous mixture of a monomer and maleimide are subjected to a first cure heat stage wherein a rigid partially-cured plastic is formed and a post-cure heat stage to effectuate permanent expansion of the cured adhesive composition.

    摘要翻译： 一种能够后固化膨胀的粘合剂组合物，其包括多官能甲基丙烯酸酯和能够在后固化时实现膨胀的马来酰亚胺。 将单体和马来酰亚胺的均匀混合物进行第一固化加热阶段，其中形成刚性部分固化的塑料和后固化热级以实现固化的粘合剂组合物的永久膨胀。

    Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces
    10.
    发明授权
    Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces 有权
    具有粘附于低能量表面的不可燃和不可燃的粘合剂粘合系统

    公开(公告)号：US07098279B2

    公开(公告)日：2006-08-29

    申请号：US10419250

    申请日：2003-04-21

    申请人： Eerik Maandi ,  Brendan J. Kneafsey

    发明人： Eerik Maandi ,  Brendan J. Kneafsey

    IPC分类号： C08F4/12 ,  C08F2/00 ,  B32B27/30

    CPC分类号： C09J4/00 ,  C08K5/29 ,  C08L2666/04 ,  C09J133/02 ,  Y10T428/31935 ,  C08F220/10

    摘要： This invention relates to (meth)acrylate based polymerizable compositions and adhesive systems prepared therefrom, which include an initiator system comprising a complex of an organoborane with a complexing agent, an aziridine-containing compound, and a carrier material with which the initiator system is unreactive and which renders the composition having a flash point above 140° F. The inventive compositions desirably have a flash point above 200° F., for each of the parts of the adhesive system. To achieve the physical properties of the inventive compositions and adhesive systems, it is desirable for the carrier material to have such flash points; however, provided that in their entirety the inventive compositions and adhesive systems have such flash points, it is not necessary for the carrier material itself to have such flash points. The inventive compositions and adhesive systems also include a package for controlling the rate of cure and indicating the extent of cure. The inventive compositions and adhesive systems are particularly well suited to bonding applications which involve at least one low energy bonding surface, for example, polyolefin, polyethylene, and polypropylene surfaces.

    摘要翻译： 本发明涉及基于（甲基）丙烯酸酯的可聚合组合物及其制备的粘合剂体系，其包括引发剂体系，其包括有机硼烷与络合剂的络合物，含氮丙啶的化合物和引发剂体系不反应的载体材料 并且使组合物的闪点高于140°F。本发明的组合物理想地具有高于200°F的闪点，用于粘合剂体系的每个部分。 为了达到本发明组合物和粘合剂体系的物理性能，载体材料最好具有这样的闪点; 然而，只要本发明的组合物和粘合剂体系全部具有这样的闪点，载体材料本身就不必具有这样的闪点。 本发明的组合物和粘合剂体系还包括用于控制固化速率并指示固化程度的包装。 本发明的组合物和粘合剂体系特别适用于涉及至少一个低能量结合表面的粘合应用，例如聚烯烃，聚乙烯和聚丙烯表面。