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1.发明授权Chlorination process, alkylation of products of said process and some products thereof 失效氯化过程，所述方法的产物的烷基化及其一些产物
公开(公告)号：US5387725A
公开(公告)日：1995-02-07
申请号：US90597
申请日：1993-07-12
申请人： Marlin E. Walters , W. Frank Richey , Katherine S. Clement , Steven L. Brewster , Emmett L. Tasset , Paul M. Puckett , V. Rao Durvasula , Hong A. Nguyen
发明人： Marlin E. Walters , W. Frank Richey , Katherine S. Clement , Steven L. Brewster , Emmett L. Tasset , Paul M. Puckett , V. Rao Durvasula , Hong A. Nguyen
IPC分类号： C07D311/62 , B01J31/02 , C07B37/04 , C07B39/00 , C07B61/00 , C07C2/86 , C07C13/567 , C07C17/10 , C07C17/266 , C07C17/37 , C07C23/34 , C07C23/40 , C07C25/22 , C07C37/18 , C07C39/14 , C07C39/17 , C07C43/21 , C07C65/36 , C07C209/68 , C07C211/50 , C07C211/51 , C07C211/60 , C07C215/76 , C08G64/30 , C07C39/24 , C07B57/00 , C07C63/00
CPC分类号： C08G64/30 , C07B37/04 , C07B39/00 , C07C17/10 , C07C2/861 , C07C211/50 , C07C211/51 , C07C37/18 , C07C39/17 , C07C41/30 , C07C65/36 , C07C2103/18
摘要： Compounds having acidic protons and a molecular structure which can delocalize the electron density of the conjugate base (target compounds) are chlorinated by contacting such compounds with a perchloroalkane and aqueous base in the presence of a phase transfer catalyst which is an tetraalkylammonium hydroxide. Chlorinated products, preferably gem-dichloro compounds, are produced. The gem-dichloro compounds are useful for alkylation of aromatic compounds. For instance fluorene is chlorinated to form 9,9-dichlorofluorene which is reacted with such compounds as phenol or aniline to form such compounds as 9,9-bis(hydroxyphenyl)fluorene, 9,9-bis(aminophenyl)fluorene, or 9-aminophenyl-9-chlorofluorene.
摘要翻译： 通过在相转移催化剂（四烷基氢氧化铵）的存在下使这些化合物与全氯烷烃和碱水溶液接触，将具有酸性质子的化合物和可以使共轭碱（目标化合物）的电子密度离域的分子结构氯化。 产生氯化产物，优选偕二氯化合物。 偕二氯化合物可用于芳族化合物的烷基化。 例如芴被氯化以形成9,9-二氯芴，其与苯酚或苯胺等化合物反应形成9,9-双（羟基苯基）芴，9,9-双（氨基苯基）芴或9- 氨基苯基-9-氯芴。
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2.发明授权Stratified fibrous fluoropolymer compositions and process for forming such fluoropolymers 失效分层纤维状含氟聚合物组合物和形成这种含氟聚合物的方法
公开(公告)号：US4859745A
公开(公告)日：1989-08-22
申请号：US136690
申请日：1987-12-22
IPC分类号： C08F259/08
CPC分类号： C08F259/08 , Y10S525/902
摘要： The invention is a process for producing a modified polytetrafluoroethylene which comprises polymerizing tetrafluoroethylene in an aqueous medium containing a dispersing agent with a polymerization initiator source and then, copolymerizing tetrafluoroethylene one or more fluorinated modifiers having an acid functional group or a functional group which is convertible to the acid group as a copolymerizable modifier in the presence of the resulting polytetrafluoroethylene to a polymerization point past the Kraft point to produce highly porous, fibrous, stratified fluoropolymers having cores made of homopolymer of poly-tetrafluoroethylene coated with sheath layers which are made of a copolymer of polytetrafluoroethylene and one or more modifiers.The invention also includes a highly porous, fibrous, stratified fluoropolymer having a plurality of interconnected, fibrous-like projections wherein the stratified fluoropolymer has a core layer of polytetrafluoroethylene substantially completely covered by a copolymer of polytetrafluoroethylene and a fluorocarbon modifier.
摘要翻译： 本发明是一种改性聚四氟乙烯的制造方法，其特征在于，在含有聚合引发剂源的分散剂的水性介质中聚合四氟乙烯，然后使四氟乙烯与一种或多种具有酸官能团或官能团的氟化改性剂共聚， 该酸基团作为可共聚改性剂，在所得聚四氟乙烯存在下，聚合点经过牛皮纸点，以产生具有由涂覆有鞘层的聚四氟乙烯均聚物制成的芯的高度多孔，纤维状分层的含氟聚合物， 的聚四氟乙烯和一种或多种改性剂。 本发明还包括具有多个相互连接的纤维状突起的高度多孔，纤维状分层的氟聚合物，其中分层含氟聚合物具有基本上被聚四氟乙烯和氟碳改性剂的共聚物完全覆盖的聚四氟乙烯核心层。
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公开(公告)号：US4800186A
公开(公告)日：1989-01-24
申请号：US114323
申请日：1987-10-28
申请人： Emmett L. Tasset
发明人： Emmett L. Tasset
CPC分类号： B01J31/06 , B01J31/0215 , B01J31/0227 , B01J31/4007 , B01J38/52 , B01J2231/4205
摘要： A method of regenerating a deactivated fluorocarbonsulfonic acid polymer catalyst by contacting the deactivated catalyst with a solvent combination wherein a first solvent swells the structure of the polymer and the other acts as a diluent to modify the swelling action of the first. The combination dissolves the deactivating components.
摘要翻译： 通过使失活的催化剂与溶剂组合接触来再生失活的氟代烃磺酸聚合物催化剂的方法，其中第一溶剂使聚合物的结构膨胀，另一种作为稀释剂，以改变第一溶剂的溶胀作用。 该组合溶解去活化组分。
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4.发明授权Preparation of 4,4'-dihydroxy-'alkylstiblbene with reduced dimer formation 失效制备二聚体形成减少的4,4'-二羟基 - 烷基芪
公开(公告)号：US5723692A
公开(公告)日：1998-03-03
申请号：US713330
申请日：1996-09-13
IPC分类号： C07C37/72 , C07C37/00 , C07C37/20 , C07C39/215
CPC分类号： C07C37/001 , C07C37/20
摘要： Preparation of dihydroxy-.alpha.-alkylstilbenes with reduced undesirable by-products can be achieved by carrying out dehydrohalogenation of a substantially uniform dispersion of a halogenated intermediate of the desired product in the presence of water and a polar protic solvent.
摘要翻译： 通过在水和极性质子溶剂的存在下，通过进行所需产物的卤化中间体的基本上均匀分散体的脱卤化氢，可以制备具有减少的不希望的副产物的二羟基-α-烷基茋。
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5.发明授权Process for the surface treatment of polymer articles to provide for better adherence of paints 失效用于表面处理聚合物制品以提供更好的涂料粘附性的方法
公开(公告)号：US4808440A
公开(公告)日：1989-02-28
申请号：US114322
申请日：1987-10-28
申请人： Emmett L. Tasset
发明人： Emmett L. Tasset
CPC分类号： C08J7/14 , B05D3/101 , B05D2201/02
摘要： Polyurethane articles of manufacture are treated so as to make their surfaces more adherent to paint by contacting the surfaces of the articles with a solution of phosphoric acid in a low molecular weight organic solvent, e.g. a carboxylic acid ester such as ethyl acetate. The treated article is then dried at an elevated temperature.
摘要翻译： 处理聚氨酯制品以通过使制品的表面与磷酸在低分子量有机溶剂例如水溶液中的溶液接触来使其表面更粘附于涂料。 羧酸酯如乙酸乙酯。 然后将经处理的制品在升高的温度下干燥。
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6.发明授权
公开(公告)号：US4791081A
公开(公告)日：1988-12-13
申请号：US947788
申请日：1986-12-30
CPC分类号： B01J37/0203 , B01J31/10 , C08F2/18 , C08F214/262 , B01J2231/32 , B01J2231/323 , B01J2231/4205 , B01J2231/52
摘要： This invention discloses improved heterogeneous acid catalysts and a method for preparing these catalysts. A heterogeneous acid catalyst has been prepared by coating a carrier with an aqueous emulsion containing a fluorocarbonsulfonic acid polymer in the sulfonyl fluoride form, removing the excess water, heating to a temperature above the softening point of the polymer for a time, and then converting the polymer to the active sulfonic acid form. The substrate has pores of about 0.1 micrometers or greater and a surface area of about 20 m.sup.2 /g or less.
摘要翻译： 本发明公开了改进的异构酸催化剂及其制备方法。 已经通过用含有磺酰氟形式的氟代磺酸聚合物的水性乳液涂布载体来制备多相酸催化剂，除去多余的水，加热到高于聚合物软化点一段时间的温度，然后将 聚合物与活性磺酸形式。 基材具有约0.1微米或更大的孔隙和约20m 2 / g或更小的表面积。
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公开(公告)号：US4524011A
公开(公告)日：1985-06-18
申请号：US549364
申请日：1983-11-04
CPC分类号： C11D7/5018 , C23G5/02806 , C11D7/261 , C11D7/28
摘要： Superior solder flux, e.g., rosin flux, removal compositions are disclosed which have no flash point and are substantially non-corrosive toward aluminum. These compositions consist of about 0.5 to less than 2% methanol with about 3 to 10% of one or more alcohols containing 2-5 carbon atoms the balance being an inhibited 1,1,1-trichloroethane, wherein percentages are based on volume of the total composition.
摘要翻译： 公开了优异的助焊剂，例如松香助焊剂，去除组合物，其不具有闪点并对铝基本上不具有腐蚀性。 这些组合物由约0.5至小于2％的甲醇组成，约3至10％的一种或多种含有2-5个碳原子的醇，余量为受抑制的1,1,1-三氯乙烷，其中百分比基于 总成分
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公开(公告)号：US5136110A
公开(公告)日：1992-08-04
申请号：US626597
申请日：1990-12-12
CPC分类号： C07C37/18
摘要： The invention is a process for the preparation of triaromatic bisphenols reacting a phenolic compound, e.g. phenol, with a suitable halo-compound, for instance 1,1-dichloroethylbenzene, 1-chlorostyrene, or mixtures thereof. The reaction may be conducted in the presence or absence of a solvent; an excess of the phenolic compound can serve as the solvent. The product is conveniently recovered by removing the by-product HCl, excess phenolic compound, excess solvent and cooling. Yields of bis-1,1-(4-hydroxyphenyl)-1-phenylethane which are greater than 90% of theoretical have been obtained by the reaction of phenol and 1,1-dichloroethylbenzene and a large portion of the yield is para isomer. Suitable halo-compounds include aromatic dihalo-compounds having at least one aliphatic substituent having two alpha-halogen atoms and at least one beta halogen atom, halo-styrenes having structures corresponding to such aromatic dihalo-compounds except that an alpha-halogen atom and a beta hydrogen atom are removed and there is a double bond between the alpha and beta carbon atoms, trihalotoluenes, and dihalocyanotoluenes.
摘要翻译： 本发明是制备与酚类化合物反应的三芳族双酚的方法， 苯酚，具有合适的卤代化合物，例如1,1-二氯乙苯，1-氯苯乙烯或其混合物。 反应可以在存在或不存在溶剂的情况下进行; 过量的酚类化合物可用作溶剂。 通过除去副产物HCl，过量酚类化合物，过量溶剂和冷却，方便地回收产物。 通过苯酚和1,1-二氯乙苯的反应得到大于理论值的90％的双-1,1-（4-羟基苯基）-1-苯基乙烷的产率，大部分产率是对位异构体。 合适的卤代化合物包括具有至少一个具有两个α-卤素原子和至少一个β卤素原子的脂族取代基的芳族二卤代化合物，具有对应于这种芳族二卤化合物的结构的卤代苯乙烯，除了α-卤素原子和 β氢原子被去除，并且在α和β碳原子之间存在双键，三卤代甲苯和二卤甲氧基甲苯。
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9.发明授权
公开(公告)号：US4602110A
公开(公告)日：1986-07-22
申请号：US734311
申请日：1985-05-15
申请人： Emmett L. Tasset
发明人： Emmett L. Tasset
IPC分类号： C07C213/10 , C07C20060101 , C07C215/40 , C07C89/04
CPC分类号： C07C213/10
摘要： A method of purifying 3-chloro-2-hydroxypropyl trialkylammonium chloride. An aqueous slurry is prepared containing about 70-98 wt. % total solids including the chloride and impurities associated with the preparation thereof. To this slurry is then added a miscible alcohol having about 3-4 carbon atoms. A solid filtrate is collected and optionally washed with additional alcohol and dried. The solid filtrate is substantially more pure in the chloride than the starting material.
摘要翻译： 一种纯化3-氯-2-羟丙基三烷基氯化铵的方法。 制备含有约70-98wt。 包括氯化物的总固体％和与其制备相关的杂质。 然后向该浆料中加入具有约3-4个碳原子的可混溶的醇。 收集固体滤液，任选地用另外的醇洗涤并干燥。 固体滤液在氯化物中比起始原料基本上更纯净。
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10.发明授权
公开(公告)号：US4533653A
公开(公告)日：1985-08-06
申请号：US451123
申请日：1982-12-20
摘要： An improved process of making an oxidation catalyst containing vanadium, tin, potassium and a silicate binder which comprises employing a porosity control agent and calcination conditions to produce a catalyst having a mean pore diameter in the range of 5-15.mu. and at least 90% of the pores having diameters
摘要翻译： 制备含有钒，锡，钾和硅酸盐粘合剂的氧化催化剂的改进方法，其包括使用孔隙率控制剂和煅烧条件来制备平均孔径在5-15μm和至少90％范围内的催化剂， 的直径<10微米的孔。
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