公开(公告)号：US20140257005A1

公开(公告)日：2014-09-11

申请号：US14283529

申请日：2014-05-21

Applicant: FINA TECHNOLOGY, INC.

Inventor： Sivadinarayana Chinta ,  Joseph L. Thorman ,  James R. Butler ,  Joe Hunter ,  Taylor Rives

IPC: C07C2/84

CPC classification number: C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

Abstract: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

公开(公告)号：US08796497B2

公开(公告)日：2014-08-05

申请号：US14072971

申请日：2013-11-06

Applicant: Fina Technology, Inc.

Inventor： Sivadinarayana Chinta ,  Joseph L. Thorman ,  James R. Butler ,  Joe Hunter ,  Taylor Rives

IPC: C07C2/84 ,  C07C2/66

CPC classification number: C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

Abstract: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

Abstract translation: 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。

公开(公告)号：US09227887B2

公开(公告)日：2016-01-05

申请号：US14283529

申请日：2014-05-21

Applicant: FINA TECHNOLOGY, INC.

Inventor： Sivadinarayana Chinta ,  Joseph L. Thorman ,  James R. Butler ,  Joe Hunter ,  Taylor Rives

IPC: C07C2/84 ,  C07C2/66

CPC classification number: C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

Abstract: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

公开(公告)号：US08729328B2

公开(公告)日：2014-05-20

申请号：US13867295

申请日：2013-04-22

Applicant: Fina Technology, Inc.

Inventor： Sivadinarayana Chinta ,  Joseph L. Thorman ,  James R. Butler ,  Joe Hunter ,  Taylor Rives

IPC: C07C2/84 ,  C07C2/82

CPC classification number: C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

Abstract: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

公开(公告)号：US20140066677A1

公开(公告)日：2014-03-06

申请号：US14072971

申请日：2013-11-06

Applicant: FINA TECHNOLOGY, INC.

Inventor： Sivadinarayana Chinta ,  Joseph L. Thorman ,  James R. Butler ,  Joe Hunter ,  Taylor Rives

IPC: C07C2/84

CPC classification number: C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

Abstract: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

Abstract translation: 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。

公开(公告)号：US20130316899A1

公开(公告)日：2013-11-28

申请号：US13957106

申请日：2013-08-01

Applicant: FINA TECHNOLOGY, INC.

Inventor： Joseph E. Pelati ,  Taylor Rives

IPC: B01J23/75

CPC classification number: B01J23/75 ,  B01J29/06 ,  B01J29/061 ,  B01J29/072 ,  B01J29/7615 ,  B01J29/90 ,  B01J37/0009 ,  B01J37/0018 ,  B01J2229/20 ,  B01J2229/42 ,  C07C2/66 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/18 ,  C07C2523/22 ,  C07C2523/34 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/75 ,  Y02P20/584 ,  Y02P20/588 ,  C07C15/073

Abstract: A solid catalyst, such as a molecular sieve catalyst or solid acid catalyst, is supported by a binder, such as amorphous silica or alumina, wherein the binder is charged with metal ions to form an ion-modified binder. The ion-modified binder is capable of attachment to polar contaminants and inhibit their contact with the catalyst. The catalyst can be a zeolite and can be the catalyst for an alkylation reaction, such as the alkylation of benzene with ethylene.

Abstract translation: 诸如分子筛催化剂或固体酸催化剂的固体催化剂由诸如无定形二氧化硅或氧化铝的粘合剂负载，其中粘合剂装有金属离子以形成离子改性的粘合剂。 离子改性的粘合剂能够附着于极性污染物并且抑制它们与催化剂的接触。 催化剂可以是沸石，并且可以是用于烷基化反应的催化剂，例如苯与乙烯的烷基化。