Addition of a Base to Enhance Product Yield in Alkylation Reactions
    2.
    发明申请
    Addition of a Base to Enhance Product Yield in Alkylation Reactions 审中-公开
    添加碱以提高烷基化反应中的产物产率

    公开(公告)号:US20140256537A1

    公开(公告)日:2014-09-11

    申请号:US14282624

    申请日:2014-05-20

    IPC分类号: B01J31/26

    摘要: A process for making styrene including providing toluene, a co-feed, and a C1 source to a reactor containing a catalyst having acid sites and reacting toluene with the C1 source in the presence of the catalyst and the co-feed to form a product stream containing ethylbenzene and styrene, wherein the C1 source is selected from methanol, formaldehyde, formalin, trioxane, methylformcel, paraformaldehyde, methylal, dimethyl ether, and wherein the co-feed removes at least a portion of the acid sites on the catalyst. The co-feed can be selected from the group of aniline, amines, cresol, anisol, and combinations thereof.

    摘要翻译: 一种制备苯乙烯的方法,包括在含有具有酸性位点的催化剂的反应器中提供甲苯,共进料和C1源,并在催化剂和共进料存在下使甲苯与C1源反应形成产物流 含有乙苯和苯乙烯,其中C1源选自甲醇,甲醛,福尔马林,三恶烷,甲基甲缩醛,多聚甲醛,甲缩醛,二甲醚,并且其中所述共进料除去催化剂上至少一部分酸性位点。 共进料可以选自苯胺,胺,甲酚,茴香醚及其组合。

    Process for the Oxidative Coupling of Hydrocarbons
    3.
    发明申请
    Process for the Oxidative Coupling of Hydrocarbons 有权
    碳氢化合物的氧化偶合过程

    公开(公告)号:US20140066677A1

    公开(公告)日:2014-03-06

    申请号:US14072971

    申请日:2013-11-06

    IPC分类号: C07C2/84

    摘要: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译: 烃的氧化偶合的方法,例如甲烷氧化偶联甲苯,包括在反应器内提供氧化催化剂,并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括(A)选自镧系元素,Mg,Ca和元素周期表第4族元素(Ti,Zr和Hf)中的至少一种元素; (B)选自Li,Na,K,Rb,Cs的第1族元素和第3族元素(包括La和Ac)和元素周期表第5-15族中的至少一种元素; (C)选自Li,Na,K,Rb,Cs族元素和元素Ca,Sr和Ba中的至少一种元素; 和(D)氧气。

    Process for the oxidative coupling of hydrocarbons
    6.
    发明授权
    Process for the oxidative coupling of hydrocarbons 有权
    碳氢化合物的氧化偶合方法

    公开(公告)号:US08796497B2

    公开(公告)日:2014-08-05

    申请号:US14072971

    申请日:2013-11-06

    IPC分类号: C07C2/84 C07C2/66

    摘要: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译: 烃的氧化偶合的方法,例如甲烷氧化偶联甲苯,包括在反应器内提供氧化催化剂,并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括(A)选自镧系元素,Mg,Ca和元素周期表第4族元素(Ti,Zr和Hf)中的至少一种元素; (B)选自Li,Na,K,Rb,Cs的第1族元素和第3族元素(包括La和Ac)和元素周期表第5-15族中的至少一种元素; (C)选自Li,Na,K,Rb,Cs族元素和元素Ca,Sr和Ba中的至少一种元素; 和(D)氧气。

    USE OF A CO-FEED IN THE COUPLING OF TOLUENE WITH A CARBON SOURCE
    10.
    发明申请
    USE OF A CO-FEED IN THE COUPLING OF TOLUENE WITH A CARBON SOURCE 审中-公开
    在碳氢化合物与碳源的联合中使用CO

    公开(公告)号:US20140257004A1

    公开(公告)日:2014-09-11

    申请号:US14282165

    申请日:2014-05-20

    IPC分类号: C07C2/86

    摘要: A process for making styrene is disclosed that includes providing toluene, a co-feed, and a C1 source to a reactor containing a catalyst, reacting toluene with the C1 source in the presence of the catalyst and the co-feed to form a product stream containing ethylbenzene and styrene. The co-feed can be selected from the group of water, carbon monoxide, hydrogen, and combinations thereof.

    摘要翻译: 公开了一种制备苯乙烯的方法,其包括向含有催化剂的反应器提供甲苯,共进料和C1源,在催化剂和共进料存在下使甲苯与C1源反应以形成产物流 含乙苯和苯乙烯。 共进料可以选自水,一氧化碳,氢气及其组合。