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15 条记录 (耗时 0.021 秒)

    Process for the treatment of fibrous materials with modified organopolysiloxanes and the materials
    1.
    发明授权
    Process for the treatment of fibrous materials with modified organopolysiloxanes and the materials 失效
    用改性有机聚硅氧烷和材料处理纤维材料的方法

    公开(公告)号：US5196260A

    公开(公告)日：1993-03-23

    申请号：US892387

    申请日：1992-05-27

    申请人： Franz Dirschl ,  Jurgen Uhl ,  Michael Bernheim

    发明人： Franz Dirschl ,  Jurgen Uhl ,  Michael Bernheim

    IPC分类号： D06M15/356 ,  D06N3/12

    CPC分类号： D06N3/128 ,  D06M15/3568 ,  Y10T428/31663 ,  Y10T442/218 ,  Y10T442/223 ,  Y10T442/2352

    摘要： The present invention relates to a process for the treatment of fibrous materials with modified organopolysiloxanes, wherein, in an aqueous medium, an organopolysiloxane copolymer prepared in a first stage from customary cyclic siloxanes (A) and unsaturated silanes (B) in the presence of a crosslinking agent and emulsifier (1) is copolymerized in a second stage with at least one vinyl monomer in the presence of emulsifiers (2), and the resulting dispersion of the modified organopolysiloxane copolymer is applied to the material in the customary manner and the material is dried and subjected to condensation.The process has the advantage that the materials, in particular textiles, treated by the process, above all coated by the process, have very good waterproof properties and at the same time good to very good water repellency. However, the materials are simultaneously distinguished by a pleasant soft handle, without the degree of whiteness thereof being noticeably impaired.

    摘要翻译： 本发明涉及一种用改性有机聚硅氧烷处理纤维材料的方法，其中在水性介质中，在常规环状硅氧烷（A）和不饱和硅烷（B）的第一阶段中制备的有机聚硅氧烷共聚物在 交联剂和乳化剂（1）在乳化剂（2）的存在下在第二阶段与至少一种乙烯基单体共聚，并且将所得改性的有机聚硅氧烷共聚物的分散体以常规方式施加到材料上，并且材料是 干燥并冷凝。 该方法的优点是，通过该方法处理的材料，特别是纺织品，首先通过该方法涂覆，具有非常好的防水性能，同时具有非常好的防水性。 然而，这些材料同时通过舒适的柔软手柄来区分，而白度却明显受损。

    Water soluble, self-crosslinking, polymeric condensation product of amino (meth) acrylate and phosponic acid ester
    3.
    发明授权
    Water soluble, self-crosslinking, polymeric condensation product of amino (meth) acrylate and phosponic acid ester 失效
    氨基（甲基）丙烯酸酯和磷酸酯的水溶性，自交联，聚合缩合产物

    公开(公告)号：US4895927A

    公开(公告)日：1990-01-23

    申请号：US172878

    申请日：1988-03-25

    申请人： Simpert Ludemann ,  Michael Bernheim

    发明人： Simpert Ludemann ,  Michael Bernheim

    IPC分类号： C08F20/34 ,  C08G79/02 ,  C08L33/04 ,  C08L33/06 ,  D06M13/02 ,  D06M13/244 ,  D06M13/282 ,  D06M13/288 ,  D06M15/267

    CPC分类号： C08G79/02 ,  Y10T428/31504

    摘要： The present invention contains a process for manufacturing a water-soluble, self-crosslinking, polymeric condensation product by reacting 1 mole di-C.sub.1-4 -alkylamino-C.sub.24 alkyl(meth)acrylates with 0.3 to 1.5 mol di-C.sub.1-3 -alkyl-phosphonates in the presence of water under heating up to a remarkable increase of the viscosity.If aqueous solutions of these condensation products are used for the treatment of fibrous materials, a very high antistatic effect is imparted to them with only small changes of shade and a very good dry- and wet rubbing fastness as well as water-fastness. The effects show a good permanency.

    摘要翻译： 本发明包含一种通过使1摩尔二-C1-4烷基氨基-C24烷基（甲基）丙烯酸酯与0.3-1.5摩尔二-C1-3烷基 - 丙烯酸酯反应制备水溶性自交联聚合缩合产物的方法， 在加热的情况下在水存在下使膦酸盐显着增加粘度。 如果将这些缩合产物的水溶液用于纤维材料的处理，则仅具有小的变化和非常好的干湿摩擦牢度以及耐水性，赋予它们非常高的抗静电效果。 效果显示出良好的永久性。

    Process for sizing paper or cardboard with anionic hydrophobic sizing agents and cationic retention aids
    4.
    发明授权
    Process for sizing paper or cardboard with anionic hydrophobic sizing agents and cationic retention aids 失效
    使用阴离子疏水施胶剂和阳离子助留剂调整纸张或纸板的方法

    公开(公告)号：US4735685A

    公开(公告)日：1988-04-05

    申请号：US773705

    申请日：1985-09-09

    申请人： Michael Bernheim ,  Hubert Meindl ,  Peter Rohringer

    发明人： Michael Bernheim ,  Hubert Meindl ,  Peter Rohringer

    IPC分类号： C07D307/89 ,  D21H17/07 ,  D21H17/16 ,  D21H17/56 ,  D21H3/08

    CPC分类号： C07D307/89 ,  D21H17/07 ,  D21H17/16

    摘要： Anionic sizing agents containing anhydride groups, which are novel compounds and which contain a single N,N-C.sub.6 -C.sub.22 di(alkyl- or alkenyl)amido group, a N-C.sub.6 -C.sub.22 (alkyl- or alkenyl)amido group or a C.sub.6 -C.sub.22 -(alkyl or alkenyl) ester group as hydrophobic substituent, and at least one anionic group in acid or salt form, in particular the anhydride of a N,N-C.sub.6 -C.sub.22 dialkylamido- or N,N-C.sub.6 -C.sub.22 dialkenylamidocarboxylic acid, the anhydride of a N-C.sub.6 -C.sub.22 alkylamido- or N,N-C.sub.6 -C.sub.22 alkenylamidocarboxylic acid, or the C.sub.6 -C.sub.22 alkyl ester or C.sub.6 -C.sub.22 alkenyl ester of an aromatic tetracarboxylic acid anhydride or a salt thereof, are particularly suitable, together with commerically available retention aids, for use in a process for pulp-sizing or surface-sizing paper or cardboard.

    摘要翻译： 含有酸酐基团的阴离子施胶剂是新型化合物，其含有单个N，N-C 6 -C 22二（烷基 - 或烯基）酰氨基，N-C 6 -C 22（烷基 - 或烯基）酰氨基或C 6 -C 22二 C 22 - （烷基或烯基）酯基作为疏水性取代基，以及至少一种酸或盐形式的阴离子基团，特别是N，N-C6-C22二烷基酰氨基或N，N-C6-C22二烯酰基氨基羧酸的酸酐， N-C6-C22烷基酰氨基或N，N-C6-C22链烯基酰胺羧酸或芳香族四羧酸酐或其盐的C 6 -C 22烷基酯或C 6 -C 22烯基酯的酸酐特别合适，以及商业上可获得的保留 辅助材料，用于纸浆尺寸或表面尺寸纸张或纸板的过程中。

    Organopolysiloxanes containing substituted 1,3,5-triazine units
    5.
    发明授权
    Organopolysiloxanes containing substituted 1,3,5-triazine units 失效
    含有取代的1,3,5-三嗪单元的有机聚硅氧烷

    公开(公告)号：US5393859A

    公开(公告)日：1995-02-28

    申请号：US252728

    申请日：1994-06-02

    申请人： Michael Bernheim ,  Harald Chrobaczek ,  Michael Messner

    发明人： Michael Bernheim ,  Harald Chrobaczek ,  Michael Messner

    IPC分类号： C08G77/38 ,  C08G77/54 ,  D06M15/643 ,  D06M15/647 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  D06M101/16 ,  D06M101/30 ,  D06M101/34 ,  C08G77/40

    CPC分类号： D06M15/6436 ,  C08G77/54

    摘要： Organopolysiloxanes in which two polysiloxane chains are bonded via a divalent radical can be obtained by reaction of cyanuric halides with organopolysiloxanes which contain primary amino groups in substituents. The divalent radical contains 1,3,5-triazine rings, to which a halogen atom is still bonded. The organopolysiloxanes thus obtained are suitable for soft handle treatment of fiber materials. In particular, textile sheet-like structures which comprise cellulose fibers can thereby be given a soft handle and improved permanence of the treatment effects with respect to washing processes.

    摘要翻译： 其中两个聚硅氧烷链通过二价基团键合的有机聚硅氧烷可以通过将氰尿酰卤与在取代基中含有伯氨基的有机聚硅氧烷反应获得。 二价基团含有1,3,5-三嗪环，其中卤素原子仍然键合。 这样获得的有机聚硅氧烷适用于纤维材料的软处理。 特别地，包含纤维素纤维的织物片状结构因此可以被赋予柔软的手感并且改善了洗涤过程中处理效果的持久性。

    Process for sizing paper with anionic hydrophobic sizing agents and cationic retention aids
    7.
    发明授权
    Process for sizing paper with anionic hydrophobic sizing agents and cationic retention aids 失效
    用阴离子疏水施胶剂和阳离子助留剂调整纸张的方法

    公开(公告)号：US4956049A

    公开(公告)日：1990-09-11

    申请号：US372217

    申请日：1989-06-23

    申请人： Michael Bernheim ,  Dieter Strasilla ,  Bernardo De Sousa ,  Peter Rohringer

    发明人： Michael Bernheim ,  Dieter Strasilla ,  Bernardo De Sousa ,  Peter Rohringer

    IPC分类号： C08L3/00 ,  C07C275/34 ,  C07C275/42 ,  C07C309/51 ,  C08G73/00 ,  C08G73/02 ,  C08L3/04 ,  C08L77/00 ,  D21H17/03 ,  D21H17/46

    CPC分类号： D21H17/03 ,  C07C275/34 ,  C07C275/42 ,  C07C309/51

    摘要： Sizing agents, some of which are known compounds and some of which are novel aromatic compounds which contain in the aromatic nucleus a single hydrophobic substituent containing at least 5 carbon atoms and at least one anionic group, said hydrophobic substituent being linked to the aromatic nucleus through an ester, amide, urethane or urea bridge, with the CO group of ester and amide bridges being attached to the hydrophobic radical and a methylene group being optionally present between said bridges and the aromatic nucleus, are particularly suitable, together with commercially available retention aids, for use in a process for the mass sizing of paper or cardboard or for the surface sizing of paper.

    摘要翻译： 上浆剂，其中一些是已知的化合物，其中一些是新颖的芳族化合物，其在芳香核中含有单个含有至少5个碳原子的疏水性取代基和至少一个阴离子基团，所述疏水性取代基通过芳香族核连接 酯，酰胺，氨基甲酸酯或尿素桥，酯基和酰胺桥的CO基团连接到疏水基团上，并且任选地存在于所述桥和芳香核之间的亚甲基基团，特别适用于市售的助留剂 ，用于纸张或纸板的大规模尺寸或纸张表面尺寸的过程。

    Process for sizing paper with anionic hydrophobic sizing agents and cationic retention aids
    10.
    发明授权
    Process for sizing paper with anionic hydrophobic sizing agents and cationic retention aids 失效
    用阴离子疏水施胶剂和阳离子助留剂调整纸张的方法

    公开(公告)号：US4627889A

    公开(公告)日：1986-12-09

    申请号：US497307

    申请日：1983-05-23

    申请人： Michael Bernheim ,  Hubert Meindl ,  Peter Rohringer ,  Hans Wegmuller ,  Dieter Werthemann

    发明人： Michael Bernheim ,  Hubert Meindl ,  Peter Rohringer ,  Hans Wegmuller ,  Dieter Werthemann

    IPC分类号： D21H17/03 ,  C07C311/54 ,  D21H17/09 ,  D21H3/12

    CPC分类号： D21H17/09 ,  C07C311/54

    摘要： Sizing agents which are novel compounds and have at least one anionic or acidic group which is optionally in salt form and at least two hydrophobic substituents of which at least two of the most adjacent ones are bonded to each other with a bridging member which has at least 1 carbon atom and 2 hetero atoms, at least one sulfur atom being present as hetero atom, in particular sulfimides or bisulfimides of fatty acid derivatives, are highly suitable for use, together with commercially available retention aids, in a process for sizing paper or cardboard.

    摘要翻译： 作为新化合物并且具有至少一个阴离子或酸性基团的上光剂，其任选为盐形式，并且至少两个疏水性取代基，其中至少两个最相邻的取代基彼此键合，桥连构件至少具有 1个碳原子和2个杂原子，至少一个作为杂原子存在的硫原子，特别是脂肪酸衍生物的亚磺酰亚胺或双亚硫酰亚胺，非常适合与市售的助留剂一起用于纸张或纸板的尺寸 。