Production of blue iron hexacyanoferrate-III pigments
    3.
    发明授权
    Production of blue iron hexacyanoferrate-III pigments 失效
    生产蓝铁六氰酸铁-III颜料

    公开(公告)号:US4466867A

    公开(公告)日:1984-08-21

    申请号:US467744

    申请日:1983-02-18

    IPC分类号: C09C1/26 C25B1/00

    CPC分类号: C25B1/00 C09C1/26 C01P2006/80

    摘要: Blue iron hexacyanoferrate-III pigments are produced by a process wherein complex iron-II hexacyanoferrate-II (Berlin white) is prepared by electrolysis of an aqueous catholyte solution containing (a) an iron-II salt, (b) an alkali metal salt, an ammonium salt or a mixture of these, and (c) hydrogen cyanide, in an electrolysis cell in which the anode chamber and cathode chamber are separated by an ion exchange membrane, using an electrically conductive aqueous liquid in the anode chamber, and the iron-II hexacyanoferrate-II obtained is then converted to the blue pigment.The process gives Berlin white, which is substantially free from salt, in high yield and high purity. Pollution caused by the process is very low, since only a small amount of salt is produced. Compared with the corresponding blue pigments produced by prior art processes, the pigments obtained give purer colorations with better gloss, and are of higher color strength.

    摘要翻译: 通过电解含有(a)铁-II盐,(b)碱金属盐的水性阴极电解液的方法制备复合铁 - 六氰基铁酸盐-II(柏林白)的方法制备蓝色六氰合铁酸盐III- 铵盐或它们的混合物,和(c)氰化氢在电解池中,其中阳极室和阴极室由离子交换膜分离,使用阳极室中的导电含水液体,铁 -II六氰基铁酸盐-II然后转化成蓝色颜料。 该方法给出柏林白色,其基本上不含盐,以高产率和高纯度。 该过程造成的污染非常低,因为只产生少量的盐。 与通过现有技术方法生产的相应的蓝色颜料相比,获得的颜料产生更好的着色,并具有较高的着色强度。

    Preparation of water-soluble food-grade triphenylmethane colors
    5.
    发明授权
    Preparation of water-soluble food-grade triphenylmethane colors 失效
    制备水溶性食品级三苯甲烷颜色

    公开(公告)号:US4775451A

    公开(公告)日:1988-10-04

    申请号:US79996

    申请日:1987-07-31

    IPC分类号: C25B3/02

    CPC分类号: C25B3/02

    摘要: A process for the preparation of a water soluble food-grade diaminotriphenylmethane colorant containing from 2 to 4 sulfo groups, comprising anodically oxidizing the corresponding leuco compound in an electrolysis cell divided into an anode space and a cathode space in the presence of from 0.01 to 2% by weight, based on the solution being oxidized, of a C.sub.2 -C.sub.4 -alkanol, urea, a urea derivative or a mixture thereof, at a potential .epsilon..sub.h .ltoreq.1250 mV and at a temperature .ltoreq.+40.degree. C. The colorants obtained are produced in high yield and are of food quality.

    摘要翻译: 一种制备含有2至4个磺基的水溶性食品级二氨基三苯基甲烷着色剂的方法,包括在0.01至2的存在下阳极氧化分解成阳极空间和阴极空间的电解槽中的相应的无色化合物 尿素,尿素衍生物或其混合物,基于待氧化溶液的重量%,电位ε1250mV,温度为+ 40℃ 得到的着色剂以高产率生产并具有食品质量。

    Biological reactor
    9.
    发明授权
    Biological reactor 失效
    生物反应器

    公开(公告)号:US5217900A

    公开(公告)日:1993-06-08

    申请号:US380730

    申请日:1989-07-13

    IPC分类号: C12M1/00 C12M1/40

    摘要: A biological reactor which is operated using microorganisms and/or enzymes and used for the oxidative conversion of organic compounds, and in which the organic compounds to be converted are employed in the presence of a biocatalyst in the reactor space (4) (anode space) and the enzymes are regenerated at a polarized electrode (1), the polarization of the electrode (1) being effected by means of a catalyst electrode (2) which is separated from the reactor space (4) by a polyelectrolyte (3) and is located in an electrolyte space (5), wherein the electrode (1) is prepared from an electrically conductive carbon material which has been partially oxidized on the surface at a potential .epsilon..sub.h of from +1.3 to +10 V in an aqueous oxygen-containing mineral acid.

    摘要翻译: 使用微生物和/或酶操作并用于有机化合物的氧化转化的生物反应器,其中待转化的有机化合物在反应器空间(4)(阳极空间)中的生物催化剂存在下使用, 并且酶在极化电极(1)再生,电极(1)的极化通过由聚电解质(3)与反应器空间(4)分离的催化剂电极(2)进行,并且是 位于电解质空间(5)中,其中所述电极(1)由导电碳材料制备,所述导电碳材料在表面上在含氧含氧量的水溶液中以+1.3至+10V的电位εh部分氧化 无机酸。