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    Platinum-nitrogen complex catalysts
    1.
    发明授权
    Platinum-nitrogen complex catalysts 失效
    铂 - 氮配合物催化剂

    公开(公告)号：US4588800A

    公开(公告)日：1986-05-13

    申请号：US689184

    申请日：1985-01-07

    申请人： Frederick J. Palensky ,  Allen R. Siedle

    发明人： Frederick J. Palensky ,  Allen R. Siedle

    IPC分类号： C07F7/14 ,  C07F15/00 ,  C08G77/38 ,  C08L83/04 ,  C08G77/06

    CPC分类号： C08G77/38 ,  C07F15/0006 ,  C07F7/14 ,  C08L83/04 ,  C08G77/20

    摘要： A hydrosilation process is dislosed for the reaction between silicon-hydrogen bonds and compounds having aliphatic carbon atoms linked by multiple bonds using as catalysts novel platinum-nitrogen complex compounds of the following classes:(a) monometallic complexes, (L)PtX.sub.2 (Y),(b) bimetallic complexes, (L)(PtX.sub.2).sub.2 (Y).sub.2,(c) ionic complexes, (L)PtX.sub.2 (Y)(Z), and(d) reduced forms of said monometallic complexes having the formulae:H[(PNZ)PtX.sub.2 (Q)].sub.2, (1)[(PNZ)PtX.sub.2 (Q)].sub.2.sup.- A.sup.+, (2) and[H(PNZ)PtCl.sub.2 (C.sub.2 H.sub.4)].sub.3 PtCl.sub.3 (3) whereinL is a single or fused ring unsaturated heterocyclic ligand, wherein said hetero atoms are nitrogen, comprising at least one 5- or 6-member ring, said ligand having 2 to 4 nitrogen atoms in the same ring, and said ligand having up to a total of 44 carbon atoms,Y is an uncharged olefinically unsaturated hydrocarbon monodentate ligand that fills only one coordination position of the platinum atom and is selected from olefinically unsaturated hydrocarbons, triarylphosphines or triarylarsines wherein aryl is phenyl or phenyl substituted by up to 4 lower alkyl groups having 1 to 4 carbon atoms, dialkyl sulfides wherein each alkyl group independently has 1 to 16 carbon atoms, and carbon monoxide, the ligand having up to 25 carbon atoms,X is independently Cl, Br, I, CN, or SCN,Z is HCl, HBr, or silver trifluoromethanesulfonate,Q is an aliphatically unsaturated olefin ligand of 2 to 25 carbon atoms,A is a cation, andPNZ is phenazine.Preparation of the novel catalysts is described. The cured compositions are useful in the preparation of molded articles.

    摘要翻译： 硅氢键与具有通过多个键连接的脂族碳原子的化合物之间的反应的氢化硅烷化方法被用作催化剂，以下类别的新型铂 - 氮络合物化合物：（a）单金属络合物，（L）PtX 2（Y） ，（b）双金属络合物，（L）（PtX2）2（Y）2，（c）离子络合物，（L）PtX2（Y）（Z）和（d）所述具有下式的单金属络合物的还原形式： H [（PNZ）PtX2（Q）] 2，（1）[（PNZ）PtX2（Q）] 2-A +，（2）和[H（PN​​Z）PtCl2（C2H4）] 3PtCl3（3） 单环或稠环不饱和杂环配体，其中所述杂原子是氮，其包含至少一个5-或6-元环，所述配体在同一环中具有2-4个氮原子，所述配体具有总共44 碳原子，Y是不饱和的烯属不饱和烃单齿配体，其仅填充铂原子的一个配位位置，并且选自烯属不饱和烃，三芳基膦或 三芳基砜，其中芳基是苯基或被至多4个具有1-4个碳原子的低级烷基取代的苯基，其中每个烷基独立地具有1至16个碳原子的二烷基硫化物，和一氧化碳，具有至多25个碳原子的配体，X 独立地是Cl，Br，I，CN或SCN，Z是HCl，HBr或三氟甲磺酸银，Q是2至25个碳原子的脂族不饱和烯属配体，A是阳离子，PNZ是吩嗪。 描述了新型催化剂的制备。 固化的组合物可用于制备模制品。

    Platinum-nitrogen complex catalysts
    2.
    发明授权
    Platinum-nitrogen complex catalysts 失效
    铂 - 氮配合物催化剂

    公开(公告)号：US4511715A

    公开(公告)日：1985-04-16

    申请号：US402231

    申请日：1982-07-27

    申请人： Frederick J. Palensky ,  Allen R. Siedle

    发明人： Frederick J. Palensky ,  Allen R. Siedle

    IPC分类号： C07F7/14 ,  C07F15/00 ,  C08G77/38 ,  C08L83/04 ,  B01J31/22 ,  B01J31/24

    CPC分类号： C08G77/38 ,  C07F15/0006 ,  C07F7/14 ,  C08L83/04

    摘要： A hydrosilation process is disclosed for the reaction between silicon-hydrogen bonds and compounds having aliphatic carbon atoms linked by multiple bonds using as catalysts novel platinum-nitrogen complex compounds of the following classes:(a) monometallic complexes, (L)PtX.sub.2 (Y),(b) bimetallic complexes, (L)(PtX.sub.2).sub.2 (Y).sub.2,(c) ionic complexes, (L)PtX.sub.2 (Y)(Z), and(d) reduced forms of said monometallic complexes having the formulae:(1) H[(PNZ)PtX.sub.2 (Q)].sub.2,(2) [(PNZ)PtX.sub.2 (Q)].sub.2.sup.- A.sup.+, and(3) [H(PNZ)PtCl.sub.2 (C.sub.2 H.sub.4)].sub.3 PtCl.sub.3whereinL is a single or fused ring unsaturated heterocyclic ligand, wherein said hetero atoms are nitrogen, comprising at least one 5- or 6-member ring, said ligand having 2 to 4 nitrogen atoms in the same ring, and said ligand having up to a total of 44 carbon atoms,Y is an uncharged olefinically unsaturated hydrocarbon monodentate ligand that fills only one coordination position of the platinum atom and is selected from olefinically unsaturated hydrocarbons, triarylphosphines or triarylarsines wherein aryl is phenyl or phenyl substituted by up to 4 lower alkyl groups having 1 to 4 carbon atoms, dialkyl sulfides wherein each alkyl group independently has 1 to 16 carbon atoms, and carbon monoxide, the ligand having up to 25 carbon atoms,X is independently Cl, Br, I, CN, or SCN,Z is HCl, HBr, or silver trifluoromethanesulfonate,Q is an aliphatically unsaturated olefin ligand of 2 to 25 carbon atoms,A is a cation, andPNZ is phenazine.Preparation of the novel catalysts is described. The cured compositions are useful in the preparation of molded articles.

    摘要翻译： 公开了硅氢键与具有通过多个键连接的脂族碳原子的化合物之间的反应的硅氢化方法，使用以下类别的新型铂 - 氮络合物：（a）单金属络合物，（L）PtX 2（Y） ，（b）双金属络合物，（L）（PtX2）2（Y）2，（c）离子络合物，（L）PtX2（Y）（Z）和（d）所述具有下式的单金属络合物的还原形式： （1）H [（PNZ）PtX2（Q）] 2，（2）[（PNZ）PtX2（Q）] 2-A +和（3）[H（PN​​Z）PtCl2（C2H4）] 3PtCl3，其中L是 单环或稠环不饱和杂环配体，其中所述杂原子是氮，其包含至少一个5-或6-元环，所述配体在同一环中具有2-4个氮原子，所述配体具有总共44 碳原子，Y是不饱和的烯属不饱和烃单齿配体，其仅填充铂原子的一个配位位置，并且选自烯属不饱和烃，三芳基膦或 三芳基砜，其中芳基是苯基或被至多4个具有1-4个碳原子的低级烷基取代的苯基，其中每个烷基独立地具有1至16个碳原子的二烷基硫化物，和一氧化碳，具有至多25个碳原子的配体，X 独立地是Cl，Br，I，CN或SCN，Z是HCl，HBr或三氟甲磺酸银，Q是2至25个碳原子的脂族不饱和烯属配体，A是阳离子，PNZ是吩嗪。 描述了新型催化剂的制备。 固化的组合物可用于制备模制品。

    Method of hydrophilizing or hydrophobizing polymers
    3.
    发明授权
    Method of hydrophilizing or hydrophobizing polymers 失效
    亲水化或疏水化聚合物的方法

    公开(公告)号：US4451619A

    公开(公告)日：1984-05-29

    申请号：US429986

    申请日：1982-09-30

    申请人： Steven M. Heilmann ,  Jerald K. Rasmussen ,  Frederick J. Palensky

    发明人： Steven M. Heilmann ,  Jerald K. Rasmussen ,  Frederick J. Palensky

    IPC分类号： C08F8/00 ,  C08F8/32 ,  C08F26/00 ,  C08F8/30

    CPC分类号： C08F8/00

    摘要： A method of modifying the overall hydrophilic or hydrophobic nature of a high molecular weight free radical addition interpolymer, which is an azlactone-functional interpolymer, with a hydrophilic or hydrophobic nucleophilic compound is disclosed. Only the surface of the interpolymer can by hydrophilized or hydrophobized, as when the interpolymer is a coating, or the modification can take place throughout the entire bulk of the interpolymer.

    摘要翻译： 公开了一种改进具有亲水或疏水亲核化合物的高分子量自由基加成互聚物（其是吖内酯官能互聚物）的整体亲水性或疏水性的方法。 只有互聚物的表面可以通过亲水化或疏水化，如互聚物是涂层时，或者可以在互聚物的整个整体上进行改性。

    Acrylamidoacylated oligomers
    4.
    发明授权
    Acrylamidoacylated oligomers 失效
    丙烯酰氨基酰化低聚物

    公开(公告)号：US4837290A

    公开(公告)日：1989-06-06

    申请号：US217560

    申请日：1988-07-11

    申请人： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

    发明人： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

    IPC分类号： C08F2/00 ,  C08F299/02 ,  C09D4/00 ,  C09J4/00

    CPC分类号： C09D4/00 ,  C08F299/024 ,  C09J4/00

    摘要： A composition of matter comprising an acrylamido-acyl or methacrylamido-acyl oligomer derived from at least one nucleophilic oligomer having at least one amino-, hydroxyl-, or thiol-substituted polyoxyalkylene, polyalkyleneimine, polyester, polyolefin, polyacrylate, or polysiloxane oligomer, said nucleophilic oligomer having a molecular weight in the range of 200 to 20,000 is disclosed. Also disclosed are free radically polymerizable monomer-containing compositions containing said oligomers as well as acrylamido- and methacrylamido-acylated polymers which are thermal or photocured products of said oligomers. In addition, a process is disclosed for providing said acrylamido- and methacrylamido-acylated oligomers which are useful, for example, in coatings, films, printing inks, adhesives, and saturants.

    摘要翻译： 包含衍生自至少一种具有至少一个氨基，羟基或硫醇取代的聚氧化烯，聚亚烷基亚胺，聚酯，聚烯烃，聚丙烯酸酯或聚硅氧烷低聚物的亲核低聚物的丙烯酰氨基 - 酰基或甲基丙烯酰氨基 - 酰基低聚物的物质组合物， 公开了分子量在200至20,000范围内的亲核低聚物。 还公开了含有所述低聚物以及作为所述低聚物的热或光固化产物的丙烯酰氨基和甲基丙烯酰氨基酰化聚合物的可自由基聚合的含单体的组合物。 此外，公开了一种用于提供所述丙烯酰氨基和甲基丙烯酰氨基酰化的低聚物的方法，其可用于例如涂料，膜，印刷油墨，粘合剂和饱和物。

    Acrylamidoacylated oligomers
    5.
    发明授权
    Acrylamidoacylated oligomers 失效
    丙烯酰氨基酰化低聚物

    公开(公告)号：US4914223A

    公开(公告)日：1990-04-03

    申请号：US233218

    申请日：1988-08-17

    申请人： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

    发明人： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

    IPC分类号： C08F299/02 ,  C09D4/00 ,  C09J4/00 ,  C07C121/413 ,  C07C121/66

    CPC分类号： C09D4/00 ,  C08F299/024 ,  C09J4/00

    摘要： A composition of matter comprising an acrylamido-acyl or methacrylamido-acyl oligomer derived from at least one nucleophilic oligomer having at least one amino-, hydroxyl-, or thio-substituted polyoxyalkylene, polyalkyleneimine, polyester, polyolefin, polyacrylate, or polysiloxane oligomer, said nucleophilic oligomer having a molecular weight in the range of 200 to 20,000 is disclosed. Also disclosed are free radically polymerizable monomer-containing compositions containing said oligomers as well as acrylamido- and methacrylamido-acylated polymers which are the thermal or photocured products of said oligomers. In addition, a process is disclosed for providing said acrylamido- and methacrylamido-acylated oligomers which are useful, for example, in coatings, films, printing inks, adhesives, and saturants.

    摘要翻译： 包含衍生自至少一种具有至少一个氨基，羟基或硫代取代的聚氧化烯，聚亚烷基亚胺，聚酯，聚烯烃，聚丙烯酸酯或聚硅氧烷低聚物的亲核低聚物的丙烯酰氨基 - 酰基或甲基丙烯酰氨基 - 酰基低聚物的组合物， 公开了分子量在200至20,000范围内的亲核低聚物。 还公开了含有所述低聚物以及作为所述低聚物的热或光固化产物的丙烯酰氨基和甲基丙烯酰氨基酰化聚合物的可自由基聚合的含单体的组合物。 此外，公开了一种用于提供所述丙烯酰氨基和甲基丙烯酰氨基酰化的低聚物的方法，其可用于例如涂料，膜，印刷油墨，粘合剂和饱和物。

    Curable acrylamido oligomer compositions with initiator, and cured products
    7.
    发明授权
    Curable acrylamido oligomer compositions with initiator, and cured products 失效
    具有引发剂的固化丙烯酰氨基低聚物组合物和固化产物

    公开(公告)号：US4996243A

    公开(公告)日：1991-02-26

    申请号：US465041

    申请日：1990-01-16

    申请人： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

    发明人： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

    IPC分类号： C08F2/50 ,  C08F299/02 ,  C09D4/00 ,  C09J4/00

    CPC分类号： C09D4/00 ,  C08F299/024 ,  C09J4/00

    摘要： A composition of matter comprising an acrylamido-acyl or methacrylamido-acyl oligomer derived from at least one nucleophilic oligomer having at least one amino-, hydroxyl-, or thiol-substituted polyoxyalkylene, polyalkyleneimine, polyester, polyolefin, polyacrylate, or polysiloxane oligomer, said nucleophilic oliogmer having a molecular weight in the range of 200 to 20,000 is disclosed. Also disclosed are free radially polymerizable monomer-containing compositions containing said oligomers as well as acrylamido- and methacrylamido-acylated polymers which are the thermal or photocured products of said oligomers. In addition, a process is disclosed for providing said acrylamido- and methacrylamido-acylated oligomers which are useful, for example, in coatings, films, printing inks, adhesives, and saturants.

    摘要翻译： 包含衍生自至少一种具有至少一个氨基，羟基或硫醇取代的聚氧化烯，聚亚烷基亚胺，聚酯，聚烯烃，聚丙烯酸酯或聚硅氧烷低聚物的亲核低聚物的丙烯酰氨基 - 酰基或甲基丙烯酰氨基 - 酰基低聚物的物质组合物， 公开了分子量在200至20,000范围内的亲核醇。 还公开了含有所述低聚物以及作为所述低聚物的热或光固化产物的丙烯酰氨基和甲基丙烯酰氨基酰化聚合物的自由的可径向聚合的含单体组合物。 此外，公开了一种用于提供所述丙烯酰氨基和甲基丙烯酰氨基酰化的低聚物的方法，其可用于例如涂料，膜，印刷油墨，粘合剂和饱和物。

    Latently curable organosilicone compositions
    9.
    发明授权
    Latently curable organosilicone compositions 失效
    可固化的有机硅组合物

    公开(公告)号：US4337332A

    公开(公告)日：1982-06-29

    申请号：US252294

    申请日：1981-04-09

    申请人： Kurt C. Melancon ,  Frederick J. Palensky

    发明人： Kurt C. Melancon ,  Frederick J. Palensky

    IPC分类号： C08L83/00 ,  C08K5/20 ,  C08L83/04 ,  C08G77/06

    CPC分类号： C08K5/20 ,  Y10T428/31663

    摘要： A latently curable organosilicone composition is stabilized against premature gelation by the presence of an amount of an unsaturated amide that is sufficient to inhibit gelation of the composition at low, ambient or room temperature but insufficient to prevent hydrosilation at an elevated temperature.

    摘要翻译： 稳定的可固化的有机硅组合物通过存在一定量的不饱和酰胺来稳定，防止过早的凝胶化，该不饱和酰胺足以在低的环境温度或室温下抑制组合物的凝胶化，但不足以防止在高温下的硅氢化。