公开(公告)号：US07115694B2

公开(公告)日：2006-10-03

申请号：US10650676

申请日：2003-08-29

申请人： Fumihiko Shimizu ,  Naomasa Sato ,  Akira Kuwahara ,  Fumiyoshi Yamada ,  Akio Tanna

发明人： Fumihiko Shimizu ,  Naomasa Sato ,  Akira Kuwahara ,  Fumiyoshi Yamada ,  Akio Tanna

IPC分类号： C08F110/06 ,  C08F210/16 ,  B32B27/08

CPC分类号： C08F110/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/06 ,  C08F210/06 ,  C08F283/02 ,  Y10T428/31855 ,  Y10T428/31913 ,  C08F4/65927 ,  C08F2500/15 ,  C08F222/06 ,  C08F210/16

摘要： An object of the present invention is to provide a novel propylene-based polymer capable of providing a propylene-based polymer with a good adhesion and coatability. The present invention lies in a propylene-based polymer having a propylene component with several characteristics including a weight-average molecular weight Mw from not smaller than 5,000 to less than 1,000,000 as measured by GPC, and Regio irregular units based on 2,1-inserted propylene monomer and/or 1,3-inserted propylene monomer present in its main chain and the sum of the ratio of regio irregular units based on 2,1-insertion and 1,3-insertion to all propylene insertions not smaller than 0.05%.

摘要翻译： 本发明的目的是提供一种能够提供具有良好粘合性和可涂布性的丙烯类聚合物的新型丙烯类聚合物。 本发明在于具有丙烯成分的丙烯类聚合物，该丙烯成分具有若干特性，包括通过GPC测定的重均分子量Mw不小于5,000至小于1,000,000;以及基于2,1-插入的Regio不规则单元 存在于其主链中的丙烯单体和/或1,3-插入的丙烯单体，以及基于2,1-插入和1,3-插入的所有丙烯插入的区域不规则单元的比例不小于0.05％。

公开(公告)号：US07122604B2

公开(公告)日：2006-10-17

申请号：US10986341

申请日：2004-11-12

申请人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

发明人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

IPC分类号： C08F255/02

CPC分类号： C09J151/006 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/083 ,  C08L51/006 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06 ,  C08F222/06

摘要： This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.

公开(公告)号：US20050075441A1

公开(公告)日：2005-04-07

申请号：US10986341

申请日：2004-11-12

申请人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

发明人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

IPC分类号： C08F8/00 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/08 ,  C08L51/00 ,  C08L51/06 ,  C09J151/00 ,  C09J151/06 ,  C08K5/34 ,  C08L51/08

CPC分类号： C09J151/006 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/083 ,  C08L51/006 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06 ,  C08F222/06

摘要： This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.

公开(公告)号：US06887943B2

公开(公告)日：2005-05-03

申请号：US10284241

申请日：2002-10-31

申请人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

发明人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

IPC分类号： C08F8/00 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/08 ,  C08L51/00 ,  C08L51/06 ,  C09J151/00 ,  C09J151/06

CPC分类号： C09J151/006 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/083 ,  C08L51/006 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06 ,  C08F222/06

摘要： This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.

摘要翻译： 本发明提供一种不含卤素的接枝改性聚丙烯聚合物，其溶解性等某些性能优异，能够提高结晶性丙烯类聚合物基材的粘合性和涂布能力，以及含有它们的组合物。 特别是提供一种丙烯聚合物，其含有具有含有全同立构嵌段的立体嵌段结构的丙烯聚合物主链和含有羧酸基，酸酐基或羧酸酯基的侧链，其中当其 在25℃下溶解于甲苯浓度为10重量％，不溶物为总重量的1重量％以下，以及含有该聚合物的组合物。

公开(公告)号：US20060270794A1

公开(公告)日：2006-11-30

申请号：US11497501

申请日：2006-08-02

申请人： Fumihiko Shimizu ,  Kenjirou Takayanagi ,  Naomasa Sato ,  Fumiyoshi Yamada ,  Shixuan Xin

发明人： Fumihiko Shimizu ,  Kenjirou Takayanagi ,  Naomasa Sato ,  Fumiyoshi Yamada ,  Shixuan Xin

IPC分类号： C08L51/00

CPC分类号： C08L53/00 ,  C08F210/06 ,  C08F297/08 ,  C08F297/083 ,  C08L2666/02 ,  C08F210/16 ,  C08F2500/15

摘要： Soft propylene-based resin compositions, which comprise substantially the following block (I) and block (II): Block (I): propylene-based polymer having propylene unit chain segments that bond in a mode of head-to-tail bonding, in which the chain segment has an isotactic block-containing stereoblock structure; Block (II): copolymer containing at least propylene and ethylene, exhibit good flexibility, transparency, and heat resistance.

公开(公告)号：US07105604B2

公开(公告)日：2006-09-12

申请号：US10901086

申请日：2004-07-29

申请人： Fumihiko Shimizu ,  Kenjirou Takayanagi ,  Naomasa Sato ,  Fumiyoshi Yamada ,  Shixuan Xin

发明人： Fumihiko Shimizu ,  Kenjirou Takayanagi ,  Naomasa Sato ,  Fumiyoshi Yamada ,  Shixuan Xin

IPC分类号： C08F297/08 ,  C08F110/06 ,  C08L23/10 ,  C08L23/14

CPC分类号： C08L53/00 ,  C08F210/06 ,  C08F297/08 ,  C08F297/083 ,  C08L2666/02 ,  C08F210/16 ,  C08F2500/15

摘要： Soft propylene-based resin compositions, which comprise substantially the following block (I) and block (II): Block (I): propylene-based polymer having propylene unit chain segments that bond in a mode of head-to-tail bonding, in which the chain segment has an isotactic block-containing stereoblock structure; Block (II): copolymer containing at least propylene and ethylene, exhibit good flexibility, transparency, and heat resistance.

摘要翻译： 基本上包含以下嵌段（I）和嵌段（II）的软丙烯类树脂组合物：嵌段（I）：具有以头 - 尾键合模式键合的丙烯单元链段的基于丙烯的聚合物，在 链段具有含全同立构嵌段的立体嵌段结构; 嵌段（II）：至少含有丙烯和乙烯的共聚物表现出良好的柔韧性，透明性和耐热性。

公开(公告)号：US20050131160A1

公开(公告)日：2005-06-16

申请号：US10901086

申请日：2004-07-29

申请人： Fumihiko Shimizu ,  Kenjirou Takayanagi ,  Naomasa Sato ,  Fumiyoshi Yamada ,  Shixuan Xin

发明人： Fumihiko Shimizu ,  Kenjirou Takayanagi ,  Naomasa Sato ,  Fumiyoshi Yamada ,  Shixuan Xin

IPC分类号： C08F210/06 ,  C08F297/08 ,  C08L53/00 ,  C08F8/00

CPC分类号： C08L53/00 ,  C08F210/06 ,  C08F297/08 ,  C08F297/083 ,  C08L2666/02 ,  C08F210/16 ,  C08F2500/15

摘要： Soft propylene-based resin compositions, which comprise substantially the following block (I) and block (II): Block (I): propylene-based polymer having propylene unit chain segments that bond in a mode of head-to-tail bonding, in which the chain segment has an isotactic block-containing stereoblock structure; Block (II): copolymer containing at least propylene and ethylene, exhibit good flexibility, transparency, and heat resistance.

摘要翻译： 基本上包含以下嵌段（I）和嵌段（II）的软丙烯类树脂组合物：嵌段（I）：具有以头 - 尾键合模式键合的丙烯单元链段的基于丙烯的聚合物，在 链段具有含全同立构嵌段的立体嵌段结构; 嵌段（II）：至少含有丙烯和乙烯的共聚物表现出良好的柔韧性，透明性和耐热性。

公开(公告)号：US07659356B2

公开(公告)日：2010-02-09

申请号：US12185225

申请日：2008-08-04

申请人： Teruaki Ashihara ,  Masato Onoe ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Yukihito Zanka ,  Kouichi Nakayama

发明人： Teruaki Ashihara ,  Masato Onoe ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Yukihito Zanka ,  Kouichi Nakayama

IPC分类号： C08F210/00 ,  C08F110/06 ,  C08F20/06 ,  C08F283/04 ,  C08G65/32

CPC分类号： C08J3/05 ,  C08J3/005 ,  C08J7/047 ,  C08J2323/10 ,  C08J2423/00 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/04 ,  C09D123/10 ,  C09J151/06 ,  C09J153/00 ,  C08L2666/06 ,  C08L2666/24

摘要： A polypropylene type aqueous dispersion comprising the following components (a) to (c): (a)a polypropylene type polymer100parts by weight and/or a modified polypropylene type polymer (b)a surfactant1 to 100parts by weight, and (c)water100 to 1,000parts by weight, wherein the component (a) has a main chain having the following features (1) and (2) and dispersion particles in the dispersion have an average particle size of at most 0.5 μm, Feature (1) when observing a peak derived from a carbon atom of a methyl group in a propylene unit chain part comprising a head-to-tail bond by 13C-NMR and fixing a chemical shift of a peak top at a peak attributable to pentad expressed by mmmm to 21.8 ppm, a ratio (S1/S) of an area S1 of a peak of a peak top at 21.8 ppm to a total area S of peaks at from 19.8 ppm to 22.1 ppm is at least 10% and at most 60%, and when an area of a peak (mmmr) of a peak top at 21.5 to 21.6 ppm is expressed as S2, 4+2S1/S2>5, andFeature (2) a content ratio (mol ratio) of propylene unit (A): other olefin unit (B) is from 100:0 to 90:10.

摘要翻译： 包含以下组分（a）至（c）的聚丙烯型水性分散体：（a）100重量份的聚丙烯类聚合物和/或改性聚丙烯类聚合物（b）1至100重量份的表面活性剂和（ c）水100-1000重量份，其中组分（a）具有具有以下特征（1）和（2）的主链，并且分散体中的分散体颗粒具有至多0.5μm的平均粒径特征（ 1）当通过13 C-NMR观察由包含头 - 尾键的丙烯单元链部分中的甲基的碳原子衍生出的峰时，并且将峰顶的化学位移固定为归因于由 在21.8ppm的峰值峰值的面积S1与19.8ppm至22.1ppm的峰面积S的比值（S1 / S）至少为10％且至多为60％ ，21.5〜21.6ppm的峰顶的面积（mmmr）表示为S2，4 + 2S1 / S2> 5，特征（2）的含量比（mol 丙烯单元（A）的比例）：其它烯烃单元（B）为100:0至90:10。

公开(公告)号：US20050124753A1

公开(公告)日：2005-06-09

申请号：US10972914

申请日：2004-10-26

申请人： Teruaki Ashihara ,  Masato Onoe ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Yukihito Zanka ,  Kouichi Nakayama

发明人： Teruaki Ashihara ,  Masato Onoe ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Yukihito Zanka ,  Kouichi Nakayama

IPC分类号： C08J3/00 ,  C08J3/05 ,  C08J7/04 ,  C08K3/00 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  C08L53/00 ,  C09D123/10 ,  C09J151/06 ,  C09J153/00

CPC分类号： C08J3/05 ,  C08J3/005 ,  C08J7/047 ,  C08J2323/10 ,  C08J2423/00 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/04 ,  C09D123/10 ,  C09J151/06 ,  C09J153/00 ,  C08L2666/06 ,  C08L2666/24

摘要： A polypropylene type aqueous dispersion comprising the following components (a) to (c): (a) a polypropylene type polymer100parts by weight and/or a modified polypropylene type polymer (b) a surfactant1 to 100parts by weight, and (c) water100 to 1,000parts by weight, wherein the component (a) has a main chain having the following features (1) and (2) and dispersion particles in the dispersion have an average particle size of at most 0.5 μm, Feature (1) when observing a peak derived from a carbon atom of a methyl group in a propylene unit chain part comprising a head-to-tail bond by 13C-NMR and fixing a chemical shift of a peak top at a peak attributable to pentad expressed by mmmm to 21.8 ppm, a ratio (S1/S) of an area S1 of a peak of a peak top at 21.8 ppm to a total area S of peaks at from 19.8 ppm to 22.1 ppm is at least 10% and at most 60%, and when an area of a peak (mmmr) of a peak top at 21.5 to 21.6 ppm is expressed as S2, 4+2S1/S2>5, and Feature (2) a content ratio (mol ratio) of propylene unit (A): other olefin unit (B) is from 100:0 to 90:10.

公开(公告)号：US06580188B2

公开(公告)日：2003-06-17

申请号：US09851883

申请日：2001-05-09

申请人： Ichiro Katagiri ,  Naomasa Sato ,  Tetsuo Endo ,  Hiroyuki Itoh ,  Toshiro Hayashi ,  Yuichi Nanae ,  Hiroyoshi Hayashi

发明人： Ichiro Katagiri ,  Naomasa Sato ,  Tetsuo Endo ,  Hiroyuki Itoh ,  Toshiro Hayashi ,  Yuichi Nanae ,  Hiroyoshi Hayashi

IPC分类号： H02K516

CPC分类号： B62M6/45 ,  B60L11/007 ,  B60L11/1801 ,  B60L11/1872 ,  B60L2200/12 ,  B60L2240/36 ,  B62M6/50 ,  B62M6/65 ,  G01R31/36 ,  H02J7/1415 ,  H02K7/14 ,  H02K11/048 ,  H02K21/22 ,  H02K29/10 ,  Y02T10/641 ,  Y02T10/7005 ,  Y02T10/705 ,  Y10T428/249923

摘要： A moving apparatus with a driving force assist mechanism traveled mainly by human power. This moving apparatus detects, in a non-contact manner, with respect to rotating portion such as traveling wheel, etc., rotation speed of the rotating portion to detect traveling state to deliver, from the driving force assist mechanism, assistant driving force corresponding to speed change information that a person who operates the moving apparatus intends to give on the basis of the detected traveling information to carry out traveling to thereby permit smooth traveling even in the case where traveling by only human power becomes difficult.

摘要翻译： 具有主要由人力驱动的驱动力辅助机构的移动装置。 该移动装置以非接触的方式相对于诸如行进轮等的旋转部来检测旋转部的旋转速度，以检测行驶状态，从驱动力辅助机构传递对应于 操作移动装置的人员的变速信息旨在基于检测到的行驶信息进行行驶，从而即使在仅通过人力行驶变得困难的情况下也允许顺利行驶。