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公开(公告)号：US20170101313A1
公开(公告)日：2017-04-13
申请号：US15155715
申请日：2016-05-16
Applicant: GTLpetrol, LLC
Inventor： Rodney J. Allam
IPC: C01B3/56 , B01D53/00 , B01D53/047
CPC classification number: C01B3/56 , B01D53/002 , B01D53/04 , B01D53/047 , B01D2256/16 , B01D2257/108 , B01D2257/504 , B01D2257/80 , B01D2259/41 , C01B2203/0205 , C01B2203/042 , C01B2203/043 , C01B2203/0475 , C01B2203/0495 , C01B2203/062 , C01B2203/146 , C01B2203/147 , Y02C10/08 , Y02P20/152
Abstract: In some aspects, a method for incremental hydrogen production includes separating in a first Pressure Swing Absorption (PSA) system an existing reformer synthesis gas product stream into a first hydrogen stream and a first waste stream. The first waste stream is compressed to at least 40 bar to produce a compressed waste stream. Water is removed from the compressed waste stream to produce a dried waste stream. Carbon dioxide is removed from the dried waste stream to produce a remaining waste stream, and the removed carbon dioxide is at least 85% of carbon dioxide in the existing reformer synthesis gas product stream. A second PSA system separates the remaining waste stream into a second hydrogen stream and a second waste stream, and the second hydrogen stream comprises at least 11% of hydrogen from the existing reformer synthesis gas product stream.
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2.发明申请公开(公告)号：US20170057819A1
公开(公告)日：2017-03-02
申请号：US15144675
申请日：2016-05-02
Applicant: GTLpetrol LLC
Inventor： Rodney J. Allam
CPC classification number: C01B3/382 , B01J2208/00309 , B01J2208/0053 , B01J2219/00006 , C01B3/48 , C01B3/56 , C01B3/583 , C01B2203/0233 , C01B2203/0244 , C01B2203/025 , C01B2203/0255 , C01B2203/0283 , C01B2203/0288 , C01B2203/0415 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/06 , C01B2203/068 , C01B2203/0805 , C01B2203/0872 , C01B2203/0894 , C01B2203/1217 , C01B2203/1241 , C01B2203/1247 , C01B2203/1288 , C01B2203/146 , C01B2203/148 , C01B2203/1623 , C01B2203/1642 , C01B2203/86 , Y02E20/185 , Y02P30/30
Abstract: In various implementations, feed streams that include methane are reacted to produce synthesis gas. The synthesis gas may be further processed to produce ultrapure, high-pressure hydrogen streams.
Abstract translation: 在各种实施方案中，包括甲烷的进料流反应产生合成气。 可以进一步处理合成气以产生超纯的高压氢气流。
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Patent Agency Ranking
公开(公告)号：US20160177821A1
公开(公告)日：2016-06-23
申请号：US15056271
申请日：2016-02-29
Applicant: GTLpetrol, LLC
Inventor： Rodney J. Allam
CPC classification number: F02C3/20 , F01K23/10 , F02C3/28 , F02C3/30 , F02C6/06 , F02C6/18 , F02C7/141 , F02C7/22 , F05D2220/32 , F05D2220/722 , F05D2220/75 , F05D2240/24 , F05D2240/35 , Y02E20/16 , Y02E20/18 , Y02E50/11 , Y02E50/12
Abstract: In some implementations, a system may include a compressor, a heat exchanger and an ITM. The compressor is configured to receive an air stream and compress the air stream to generate a pressurized stream. The heat exchanger is configured to receive the pressured stream and indirectly heat the pressurized stream using heat from an oxygen stream from an Ion Transport Membrane (ITM). The ITM is configured to receive the heated pressurized stream and generate an oxygen stream and the non-permeate stream, wherein the non-permeate stream is passed to a gas turbine burner and the oxygen stream is passed to the heat exchanger.
Abstract translation: 在一些实施方案中，系统可以包括压缩机，热交换器和ITM。 压缩机被配置为接收空气流并压缩空气流以产生加压流。 热交换器被配置为接收加压流并且使用来自离子输送膜（ITM）的氧气流的热量间接加热加压流。 ITM被配置为接收加热的加压流并产生氧气流和非渗透物流，其中非渗透物流被传送到燃气轮机燃烧器，并且氧气流被传递到热交换器。
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公开(公告)号：US20170267524A1
公开(公告)日：2017-09-21
申请号：US15338073
申请日：2016-10-28
Applicant: GTLpetrol, LLC
Inventor： Rodney J. Allam
IPC: C01B3/50 , C01B3/56 , B01D53/047 , C01B3/12
CPC classification number: C01B3/506 , B01D53/002 , B01D53/047 , B01D53/75 , B01D53/864 , B01D2256/16 , B01D2257/502 , B01D2257/504 , B01D2257/80 , B01D2259/416 , C01B3/12 , C01B3/50 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/042 , C01B2203/043 , C01B2203/046 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/0827 , C01B2203/147 , Y02C10/08
Abstract: The GTLpetrol Process for Maximum H2 Production. The GTLpetrol process uses a proprietary combination of two stage pressure swing adsorption hydrogen purification plus a C02 condensation removal step to give H2 recoveries in the range of 95% to 98% based on H2+CO from synthesis gas generation.
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公开(公告)号：US20160107890A1
公开(公告)日：2016-04-21
申请号：US14922389
申请日：2015-10-26
Applicant: GTLpetrol LLC
Inventor： Rodney J. Allam
CPC classification number: C01B3/34 , B01J19/24 , C01B3/36 , C01B3/382 , C01B3/384 , C01B3/48 , C01B3/50 , C01B3/56 , C01B2203/0233 , C01B2203/025 , C01B2203/0283 , C01B2203/0288 , C01B2203/042 , C01B2203/0475 , C01B2203/0844 , C01B2203/0872 , C01B2203/1235 , C01B2203/1241 , C01B2203/1294 , C01B2203/141 , C01B2203/82 , C01B2203/84 , C01B2203/86 , F02C6/18 , Y02E20/14 , Y02E20/16 , Y02P20/129 , Y02P30/30
Abstract: In some implementations, one or more methods can include producing a hydrogen rich fuel gas for a gas turbine ballasted with nitrogen and steam and superheated to a temperature above its dew point. The fuel gas may have a minimal or reduced content of CO2 or fuel components CO and CH4 which contain carbon so that when combusted in a suitable gas turbine there may be minimal or reduced emissions of CO2 to the atmosphere. These example methods may result in a capture of the bulk of the carbon present in the total natural gas feed as CO2 compressed to pipeline delivery pressure for sequestration.
Abstract translation: 在一些实施方案中，一种或多种方法可以包括为用氮气和蒸汽镇压的燃气轮机产生富氢燃料气体，并过热至高于其露点的温度。 燃料气体可以具有包含碳的二氧化碳或燃料组分CO和CH 4的最小或减少的含量，使得当在合适的燃气轮机中燃烧时，CO 2的排放可能最小化或减少到大气中。 这些示例性方法可以导致捕获总天然气进料中存在的大部分碳，因为二氧化碳被压缩成管道输送压力以用于螯合。
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公开(公告)号：US09169778B2
公开(公告)日：2015-10-27
申请号：US14294843
申请日：2014-06-03
Applicant: GTLpetrol LLC
Inventor： Rodney J. Allam
CPC classification number: C01B3/34 , B01J19/24 , C01B3/36 , C01B3/382 , C01B3/384 , C01B3/48 , C01B3/50 , C01B3/56 , C01B2203/0233 , C01B2203/025 , C01B2203/0283 , C01B2203/0288 , C01B2203/042 , C01B2203/0475 , C01B2203/0844 , C01B2203/0872 , C01B2203/1235 , C01B2203/1241 , C01B2203/1294 , C01B2203/141 , C01B2203/82 , C01B2203/84 , C01B2203/86 , F02C6/18 , Y02E20/14 , Y02E20/16 , Y02P20/129 , Y02P30/30
Abstract: A hydrogen rich fuel gas for a gas turbine ballasted with nitrogen and steam can be produced and superheated to a temperature above its dew point. The fuel gas may have a minimal or reduced content of CO2 or fuel components CO and CH4 which contain carbon so that when combusted in a suitable gas turbine there may be minimal or reduced emissions of CO2 to the atmosphere. These example methods may result in a capture of the bulk of the carbon present in the total natural gas feed as CO2 compressed to pipeline delivery pressure for sequestration.
Abstract translation: 用氮气和蒸汽压载的燃气轮机的富氢燃料气体可以被制造并过热到高于其露点的温度。 燃料气体可以具有包含碳的二氧化碳或燃料组分CO和CH 4的最小或减少的含量，使得当在合适的燃气轮机中燃烧时，CO 2的排放可能最小化或减少到大气中。 这些示例性方法可以导致捕获总天然气进料中存在的大部分碳，因为二氧化碳被压缩成管道输送压力以用于螯合。
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公开(公告)号：US09283536B2
公开(公告)日：2016-03-15
申请号：US14288765
申请日：2014-05-28
Applicant: GTLpetrol LLC
Inventor： Rodney J. Allam
IPC: B01J19/00 , C01B3/38 , C07C29/151 , C01B3/36 , C01B13/02
CPC classification number: C07C29/1518 , B01J19/0053 , B01J19/245 , B01J2219/00051 , B01J2219/00873 , B01J2219/00905 , B01J2219/0875 , B01J2219/24 , C01B3/36 , C01B3/382 , C01B3/384 , C01B13/0248 , C01B2203/0233 , C01B2203/0244 , C01B2203/025 , C01B2203/04 , C01B2203/0495 , C01B2203/061 , C01B2203/0844 , C01B2203/0894 , C01B2210/0046 , Y02P20/123 , Y02P20/124 , Y02P20/129 , C07C31/04
Abstract: In various implementations, methanol is produced using a (CO+H2) containing synthesis gas produced from a combined POX plus EHTR or a combined ATR plus EHTR at a pressure of 70 bar to 100 bar at the correct stoichiometric composition for methanol synthesis so that no feed gas compressor is required for the feed to the methanol synthesis reactor loop.
Abstract translation: 在各种实施方案中，使用由组合的POX加EHTR或组合的ATR加EHTR产生的（CO + H 2）的合成气在70巴至100巴的压力下以合适的化学计量组成用于甲醇合成来生产甲醇，因此不存在 进料气压缩机是进料到甲醇合成反应器回路所必需的。
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