摘要:
A holographic recording medium includes an optically transparent substrate. The optically transparent substrate includes an optically transparent plastic material, a photochemically active dye, and a protonated form of the photochemically active dye. The protonated form of the photochemically active dye is a composition having a structure as shown in formula I and the photochemically active dye is a composition having a structure as shown in formula II in both formulae I and II, R1 and R2 are independently at each occurrence an aliphatic radical having from 1 to about 10 carbons, a cycloaliphatic radical having from about 3 to about 10 carbons, or an aromatic radical having from about 3 to about 12 carbons; R3, R4, and R5 are independently at each occurrence a hydrogen atom, an aliphatic radical having from 1 to about 10 carbons, a cycloaliphatic radical having from about 3 to about 10 carbons, or an aromatic radical having from about 3 to about 12 carbons; R6 and R7 are independently at each occurrence a hydrogen atom or an aliphatic radical having from 1 to about 6 carbons; X is a halogen; and “n” is an integer having a value of from 0 to about 4.
摘要:
A composition has a structure as shown in formula I: R1 and R2 are independently at each occurrence an aliphatic radical having from 1 to about 10 carbons, a cycloaliphatic radical having from about 3 to about 10 carbons, or an aromatic radical having from about 3 to about 12 carbons; R3, R4, and R5 are independently at each occurrence a hydrogen atom, an aliphatic radical having from 1 to about 10 carbons, a cycloaliphatic radical having from about 3 to about 10 carbons, or an aromatic radical having from about 3 to about 12 carbons; R6 and R7 are independently at each occurrence a hydrogen atom or an aliphatic radical having from 1 to about 6 carbons; X is a halogen; and “n” is an integer having a value of from 0 to about 4.
摘要:
The present invention provides a formulation for a reactive dye layer for a limited-play optical storage medium, the reactive formulation including at least one carrier material or curable acrylate monomer, at least one reactive material disposed within the carrier material or acrylate monomer, and at least one photo-bleaching retarder material disposed within the at least one adhesive material. The at least one photo-bleaching retarder material includes at least one polymeric polyhydroxy compound selected from the group consisting of polyhydroxystyrenes, cellulose, and functionalized cellulose derivatives.
摘要:
A method of making a holographic data storage medium is provided. The method comprises: (a) providing an optically transparent substrate comprising at least one photochemically active dye; and (b) irradiating the optically transparent substrate at at least one wavelength at which the optically transparent substrate has an absorbance in a range from about 0.1 to 1, to produce a modified optically transparent substrate comprising at least one optically readable datum and at least one photo-product of the photochemically active dye. The at least one wavelength is in a range from about 300 nanometers to about 800 nanometers. The optically transparent substrate is at least 100 micrometers thick, and comprises the photochemically active dye in an amount corresponding to from about 0.1 to about 10 weight percent based on a total weight of the optically transparent substrate.
摘要:
Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4′-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.
摘要:
Holographic storage media including a substrate and a dye material capable of undergoing a photo-induced change are disclosed. Data may be written into the holographic storage media using light of one wavelength and read using light of a different wavelength.
摘要:
A method of making a holographic data storage medium is provided. The method comprises: (a) providing an optically transparent substrate comprising at least one photochemically active dye; and (b) irradiating the optically transparent substrate at least one wavelength at which the optically transparent substrate has an absorbance in a range from about 0.1 to 1, to produce a modified optically transparent substrate comprising at least one optically readable datum and at least one photo-product of the photochemically active dye. The at least one wavelength is in a range from about 300 nanometers to about 800 nanometers. The optically transparent substrate is at least 100 micrometers thick, and comprises the photochemically active dye in an amount corresponding to from about 0.1 to about 10 weight percent based on a total weight of the optically transparent substrate.
摘要:
A limited play optical storage medium for data is described which comprises a first substrate, a reflective layer, a data layer disposed between said substrate and said reflective layer; a reactive layer comprising at least one carrier, and at least one reactive material, and an optically transparent second substrate comprised of a polymethacrylate copolymer or blend comprising a polymethacrylate copolymer or homopolymer. The second substrate is disposed between the reactive layer and a laser incident surface and is tailored to provide an oxygen permeability in a range between about 0.1 Barrers and about 1.35 Barrers at 25° C.
摘要:
The present invention provides a reactive adhesive formulation for use in a limited play data storage medium, the reactive adhesive formulation including at least one adhesive material, at least one reactive material disposed within the at least one adhesive material and at least one photo-bleaching retarder material disposed within the at least one adhesive material. The at least one photo-bleaching retarder material includes resorcinol, 4-hexylresorcinol and/or polyhydroxystyrene.