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    Process for making polymers containing a norbornene repeating unit by addition polymerization using an organo (nickel or palladium) complex
    1.
    发明授权
    Process for making polymers containing a norbornene repeating unit by addition polymerization using an organo (nickel or palladium) complex 失效
    使用有机（镍或钯）络合物通过加成聚合制备含有降冰片烯重复单元的聚合物的方法

    公开(公告)号：US5468819A

    公开(公告)日：1995-11-21

    申请号：US153250

    申请日：1993-11-16

    申请人： Brian L. Goodall ,  George M. Benedikt ,  Lester H. McIntosh, III ,  Dennis A. Barnes

    发明人： Brian L. Goodall ,  George M. Benedikt ,  Lester H. McIntosh, III ,  Dennis A. Barnes

    IPC分类号： C08F4/70 ,  C08F4/30 ,  C08F4/42 ,  C08F4/80 ,  C08F32/00 ,  C08F32/08 ,  C08F36/04 ,  C08F36/20 ,  C08F210/14 ,  C08F232/08 ,  C08F236/20 ,  C08F4/76 ,  C08F4/78

    CPC分类号： C08F232/08 ,  C08F32/08

    摘要： A single component ionic catalyst consists essentially of an organonickel complex cation, and a weakly coordinating neutral counteranion. The cation is a neutral bidentate ligand removably attached to a Group VIII transition metal in an organometal complex. The ligand is easily displaced by a norbornene-type (NB-type) monomer in an insertion reaction which results in an unexpectedly facile addition polymerization. A NB-type monomer includes NB or substituted NB, or a multi-ringed cycloolefin having more than three rings in which one or more of the rings has a structure derived from NB, and a ring may have an alicyclic alkyl, alkylene or alkylidene substituent. The insertion reaction results in the formation of a unique propagating species more soluble in a polar than in a non-polar solvent and devoid of an available .beta.-hydrogen for termination. The ensuing propagation of a polymer chain proceeds without measurable unsaturation. The chain continues to grow until the insertion of a monoolefinic chain transfer reagent results in substantially all chains being terminated with the residue of the chain transfer reagent. This unique chain transfer reaction allows one to control the molecular weight in a relatively narrow range. The reaction mixture for controlling the mol wt of the polymer chains may contain any other catalyst which generates a propagating species by an insertion reaction in an essentially anhydrous solvent. Both, mol wt and glass transition temperature Tg are tailored to provide a weight average mol wt Mw>20,000 but preferably not greater than about 500,000, and a T.sub.g in the range from about 150.degree. C. to about 400.degree. C. or higher, if desired.

    摘要翻译： 单组分离子催化剂基本上由有机镍络合物阳离子和弱配位的中性抗衡阴离子组成。 该阳离子是一种中和二齿配体，可以与有机金属络合物中的第VIII族过渡金属可去除地连接。 配体在插入反应中容易被降冰片烯型（NB型）单体置换，导致出人意料的容易的加成聚合。 NB型单体包括NB或取代的NB，或具有多于三个环的多环环烯，其中一个或多个环具有源自NB的结构，并且环可以具有脂环族烷基，亚烷基或亚烷基取代基 。 插入反应导致形成比非极性溶剂更易溶于极性的独特的增殖物质，并且没有可用的β-氢终止。 随后的聚合物链的扩散进行而没有可测量的不饱和度。 链条继续生长，直到插入单烯烃链转移试剂导致基本上所有的链都被链转移试剂的残基终止。 这种独特的链转移反应允许在相对较窄的范围内控制分子量。 用于控制聚合物链的摩尔重量的反应混合物可以含有任何其它催化剂，其通过在基本上无水的溶剂中的插入反应产生传播物质。 二氧化钼和玻璃化转变温度Tg均适用于提供重均分子量Mw> 20,000但优选不大于约500,000，Tg在约150℃至约400℃或更高的范围内， 如果需要的话。

    Odor-free chlorosulfonated polyolefins
    2.
    发明授权
    Odor-free chlorosulfonated polyolefins 失效
    无气味氯磺化聚烯烃

    公开(公告)号：US4680380A

    公开(公告)日：1987-07-14

    申请号：US459066

    申请日：1983-01-19

    申请人： George M. Benedikt ,  Dennis A. Barnes

    发明人： George M. Benedikt ,  Dennis A. Barnes

    IPC分类号： C08L23/00 ,  C08F8/38 ,  C08K3/00 ,  C08K3/22 ,  C08K3/26 ,  C08K3/32 ,  C08L101/00

    CPC分类号： C08K3/0083 ,  C08F8/38

    摘要： Vapor phase chlorosulfonated polyolefins usually contain as much as about 100 to 200 parts of more per million of sulfur dioxide in the chlorosulfonated polyolefin particles, even after degassing, that is released over a period of time. The amount of sulfur dioxide released from vapor phase chlorosulfonated polyolefins can be reduced to an amount of less than 0.5 ppm of sulfur dioxide in air, below the level that it can be detected by odor, when there is mixed with the powdered chlorosulfonated polyolefin, after the chlorosulfonation reaction and purging to reduce the sulfur dioxide content of the powder to less than about 300 ppm, less than about three weight parts per one hundred weight parts of chlorosulfonated powdered polyolefin of an inorganic material, or mixture thereof, selected from the group consisting of aluminum hydroxide, barium carbonate, barium hydroxide, magnesium hydroxide, magnesium oxide, potassium carbonate, dipotassium hydrogen phosphate, tripotassium phosphate, sodium carbonate, disodium hydrogen phosphate and trisodium phosphate.

    摘要翻译： 气相氯磺化聚烯烃在氯磺化聚烯烃颗粒中通常含有多达100-200份更多的百万分之二氧化硫，即使在脱气后，一段时间后也释放出来。 从气相氯磺化聚烯烃中释放的二氧化硫的量可以在空气中少于0.5ppm的二氧化硫的量，低于可以被气味检测到的水平，当与粉末氯磺化聚烯烃混合时， 氯磺化反应和吹扫以将粉末的二氧化硫含量降低到小于约300ppm，小于约3重量份/ 100重量份的无机材料的氯磺化粉末状聚烯烃或其混合物，其选自 氢氧化铝，碳酸钡，氢氧化钡，氢氧化镁，氧化镁，碳酸钾，磷酸氢二钾，磷酸三钾，碳酸钠，磷酸氢二钠和磷酸三钠。

    Vinyl addition polycyclic olefin polymers prepared with non-olefinic chain transfer agents and uses thereof
    6.
    发明授权
    Vinyl addition polycyclic olefin polymers prepared with non-olefinic chain transfer agents and uses thereof 有权
    用非烯烃链转移剂制备的乙烯基加成多环烯烃聚合物及其用途

    公开(公告)号：US07888415B2

    公开(公告)日：2011-02-15

    申请号：US12699909

    申请日：2010-02-04

    申请人： Larry F. Rhodes ,  Dennis A. Barnes ,  Andrew Bell ,  Brian K. Bennett ,  Chun Chang ,  John Henry Lipian ,  Xiaoming Wu

    发明人： Larry F. Rhodes ,  Dennis A. Barnes ,  Andrew Bell ,  Brian K. Bennett ,  Chun Chang ,  John Henry Lipian ,  Xiaoming Wu

    IPC分类号： C08F4/44

    CPC分类号： C08F2/38 ,  C08F232/00 ,  C08F232/08 ,  Y10S526/905

    摘要： A method of polymerizing poly(cyclic)olefin monomers encompassing (a) combining a monomer composition containing the poly(cyclic)olefin monomers, a non-olefinic chain transfer agent and an activator compound to faun a mixture; (b) heating the mixture; and (c) adding a polymerization catalyst containing Ni and/or Pd. The non-olefinic chain transfer agent includes one or more compounds selected from H2, alkylsilanes, alkylalkoxysilanes, alkylgermanes, alkylalkoxygermanes, alkylstannanes, and alkylalkoxystannanes. The activator is characterized as having an active hydrogen with a pKa of at least 5. The resulting poly(cyclic)olefin polymers can be used in photoresist compositions.

    摘要翻译： 聚合聚（环状）烯烃单体的方法包括（a）将含有聚（环状）烯烃单体，非烯烃链转移剂和活化剂化合物的单体组合物混合以形成混合物; （b）加热混合物; 和（c）加入含有Ni和/或Pd的聚合催化剂。 非烯烃链转移剂包括一种或多种选自H 2，烷基硅烷，烷基烷氧基硅烷，烷基锗烷，烷基烷氧基锗烷，烷基锡烷和烷基烷氧基烷烃的化合物。 活化剂的特征在于具有pKa至少为5的活性氢。所得聚（环状）烯烃聚合物可用于光致抗蚀剂组合物中。

    Vinyl addition polycyclic olefin polymers prepared with non-olefinic chain transfer agents and uses thereof
    9.
    发明授权
    Vinyl addition polycyclic olefin polymers prepared with non-olefinic chain transfer agents and uses thereof 有权
    用非烯烃链转移剂制备的乙烯基加成多环烯烃聚合物及其用途

    公开(公告)号：US07674847B2

    公开(公告)日：2010-03-09

    申请号：US10782547

    申请日：2004-02-19

    申请人： Larry F. Rhodes ,  Dennis A. Barnes ,  Andrew Bell ,  Brian K. Bennet ,  Chung Chang ,  John-Henry Lipian ,  Xiaoming Wu

    发明人： Larry F. Rhodes ,  Dennis A. Barnes ,  Andrew Bell ,  Brian K. Bennet ,  Chung Chang ,  John-Henry Lipian ,  Xiaoming Wu

    IPC分类号： C08F4/44

    CPC分类号： C08F2/38 ,  C08F232/00 ,  C08F232/08 ,  Y10S526/905

    摘要： A method of polymerizing poly(cyclic)olefin monomers encompassing (a) combining a monomer composition containing the poly(cyclic)olefin monomers, a non-olefinic chain transfer agent and an activator compound to form a mixture; (b) heating the mixture; and (c) adding a polymerization catalyst containing Ni and/or Pd. The non-olefinic chain transfer agent includes one or more compounds selected from H2, alkylsilanes, alkylalkoxysilanes, alkylgermanes, alkylalkoxygermanes, alkylstannanes, and alkylalkoxystannanes. The activator is characterized as having an active hydrogen with a pKa of at least 5. The resulting poly(cyclic)olefin polymers can be used in photoresist compositions.

    摘要翻译： 聚合聚（环状）烯烃单体的方法包括（a）将含有聚（环状）烯烃单体，非烯烃链转移剂和活化剂化合物的单体组合物混合以形成混合物; （b）加热混合物; 和（c）加入含有Ni和/或Pd的聚合催化剂。 非烯烃链转移剂包括一种或多种选自H 2，烷基硅烷，烷基烷氧基硅烷，烷基锗烷，烷基烷氧基锗烷，烷基锡烷和烷基烷氧基烷烃的化合物。 活化剂的特征在于具有pKa至少为5的活性氢。所得聚（环状）烯烃聚合物可用于光致抗蚀剂组合物中。

    Ni or Pd-catalyzed cationic polymerization of polycyclic olefins with silane chain transfer agents
    10.
    发明授权
    Ni or Pd-catalyzed cationic polymerization of polycyclic olefins with silane chain transfer agents 有权
    具有硅烷链转移剂的多环烯烃的Ni或Pd催化阳离子聚合

    公开(公告)号：US07863394B2

    公开(公告)日：2011-01-04

    申请号：US11517538

    申请日：2006-09-07

    申请人： Larry F. Rhodes ,  Dennis A. Barnes ,  Andrew Bell ,  Brian K. Bennett ,  Chun Chang ,  John-Henry Lipian ,  Xiaoming Wu

    发明人： Larry F. Rhodes ,  Dennis A. Barnes ,  Andrew Bell ,  Brian K. Bennett ,  Chun Chang ,  John-Henry Lipian ,  Xiaoming Wu

    IPC分类号： C08F4/70 ,  C08F10/14

    CPC分类号： C08F2/38 ,  C08F232/00 ,  C08F232/08 ,  Y10S526/905

    摘要： A method of polymerizing poly(cyclic)olefin monomers encompassing (a) combining a monomer composition containing the poly(cyclic)olefin monomers, a non-olefinic chain transfer agent and an activator compound to form a mixture; (b) heating the mixture; and (c) adding a polymerization catalyst containing Ni and/or Pd. The non-olefinic chain transfer agent includes one or more compounds selected from H2, alkylsilanes, alkylalkoxysilanes, alkylgermanes, alkylalkoxygermanes, alkylstannanes, and alkylalkoxystannanes. The activator is characterized as having an active hydrogen with a pKa of at least 5. The resulting poly(cyclic)olefin polymers can be used in photoresist compositions.

    摘要翻译： 聚合聚（环状）烯烃单体的方法包括（a）将含有聚（环状）烯烃单体，非烯烃链转移剂和活化剂化合物的单体组合物混合以形成混合物; （b）加热混合物; 和（c）加入含有Ni和/或Pd的聚合催化剂。 非烯烃链转移剂包括一种或多种选自H 2，烷基硅烷，烷基烷氧基硅烷，烷基锗烷，烷基烷氧基锗烷，烷基锡烷和烷基烷氧基烷烃的化合物。 活化剂的特征在于具有pKa至少为5的活性氢。所得聚（环状）烯烃聚合物可用于光致抗蚀剂组合物中。