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公开(公告)号：US4772456A
公开(公告)日：1988-09-20
申请号：US562652
申请日：1983-12-19
IPC分类号： B01J29/035 , B01J29/04 , B01J29/40 , B01J29/70 , C01B33/12 , C01B37/02 , C07C1/00 , C07C2/66 , C07C5/27 , C07C15/02 , C07C67/00 , C01B33/20
CPC分类号： C01B37/02 , B01J29/035 , B01J29/40 , B01J29/70 , C07C2/66 , B01J2229/36 , C07C2529/035 , Y10S423/22
摘要： Disclosed is a process for preparing crystalline silicas having the monoclinic symmetry which comprises the step of calcining in air for at least 3 hours at a temperature of at least 500.degree. C. a crystalline silica of the silicalite type having a silica to alumina atomic ratio of at least 80.
摘要翻译： 公开了一种制备具有单斜对称性的结晶二氧化硅的方法，其包括在至少500℃的温度下在空气中煅烧至少3小时的步骤。硅沸石型的结晶二氧化硅具有二氧化硅与氧化铝的原子比 至少80。
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公开(公告)号：US4781906A
公开(公告)日：1988-11-01
申请号：US562651
申请日：1983-12-19
IPC分类号： B01J29/035 , B01J29/04 , B01J29/70 , C01B33/12 , C01B37/02 , C07C1/00 , C07C2/66 , C07C5/27 , C07C15/02 , C07C67/00 , C01B33/26
CPC分类号： C01B37/02 , B01J29/035 , B01J29/70 , C07C2/66 , B01J2229/36 , C07C2529/035
摘要： A novel crystalline silica composition having a silica to alumina atomic ratio not lower than 80 and having a certain specific X-ray diffraction pattern after calcination in air for at least 3 hours at a temperature of at least 500.degree. C.
摘要翻译： 一种新型的二氧化硅与氧化铝原子比不低于80的结晶二氧化硅组合物，并且在至少500℃的温度下在空气中煅烧至少3小时后具有一定的特定X射线衍射图。
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公开(公告)号：US4748291A
公开(公告)日：1988-05-31
申请号：US8877
申请日：1987-01-29
IPC分类号： C10G11/02 , B01J21/08 , B01J29/035 , B01J29/40 , C01B37/02 , C07C2/00 , C07C2/12 , C07C5/22 , C07C5/41 , C10G11/04 , C10G35/06 , C10G35/095 , C10G50/00 , C07C2/52
CPC分类号： C07C5/41 , B01J29/035 , B01J29/40 , C07C2/00 , C07C2/12 , C07C5/2206 , C10G35/095 , C07C2529/035
摘要： A catalytic treatment process is disclosed, which is carried out under pressure, in the presence of water, and with a molecular sieve catalyst which is TEA-silicate or silicalite previously stabilized by halogenation. This process may be applied to the aromatization or to the isomerization of hydrocarbon feedstocks, and to the oligomerization of olefins. The conversion rate of the process is very stable as a function of time.
摘要翻译： 公开了一种催化处理方法，其在压力下，在水的存在下，和分子筛催化剂进行，分子筛催化剂是TEA-硅酸盐或预先通过卤化稳定的硅沸石。 该方法可以应用于烃原料的芳构化或异构化，以及烯烃的低聚。 该过程的转换率作为时间的函数是非常稳定的。
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公开(公告)号：US4599473A
公开(公告)日：1986-07-08
申请号：US562650
申请日：1983-12-19
IPC分类号： C07C2/70 , B01J29/00 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/86 , C07C15/02 , C07C67/00 , C07C2/68
CPC分类号： C07C2/66 , C07C2/864 , C07C2529/035 , Y02P30/42
摘要： A process for the selective alkylation of monoalkylbenzene into dialkylbenzenes wherein the para isomer of the disubstituted product is present in a concentration greater than in a thermodynamic equilibrium is provided.The method comprises passing the monoalkylbenzene and an alkylating agent capable of methylation, ethylation or propylation through a reaction zone containing an unmodified crystalline silica catalyst of the silicalite type having the monoclinic symmetry.
摘要翻译： 提供了将单烷基苯选择性烷基化成二烷基苯的方法，其中二取代产物的对位异构体以大于热力学平衡的浓度存在。 该方法包括使单烷基苯和能够甲基化，乙基化或丙基化的烷基化剂通过含有具有单斜对称性的硅沸石型未改性的结晶二氧化硅催化剂的反应区。
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公开(公告)号：US5171331A
公开(公告)日：1992-12-15
申请号：US583578
申请日：1990-09-17
CPC分类号： C07C2/12 , C10L1/023 , C07C2529/035
摘要： A process for production of gasoline comprising oligomerizing a C.sub.2 -C.sub.6 olefin containing feedstock over an intermediate pore size siliceous crystalline molecular sieve catalyst. The catalyst may take the form of silicalite, halogen stabilized silicalite, or a zeolite. Water may be supplied to the oligomerization reaction. The product from the oligomerization reaction is then subjected to an etherification reaction in the presence of methanol over an acid cation exchange catalyst to provide a gasoline product of enhanced octane number.
摘要翻译： 一种生产汽油的方法，其包括在中等孔径的硅质结晶分子筛催化剂上使含C2-C6烯烃的原料低聚。 催化剂可以采用硅沸石，卤素稳定的硅沸石或沸石的形式。 可以向低聚反应中供应水。 然后将低聚反应的产物在甲酸存在下通过酸性阳离子交换催化剂进行醚化反应，得到增强的辛烷值的汽油产物。
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6.发明授权
公开(公告)号：US5674379A
公开(公告)日：1997-10-07
申请号：US473682
申请日：1995-06-07
CPC分类号： C10G25/00 , C10G25/003
摘要： The present invention relates to a process for removing carbonyl sulfide from a liquid hydrocarbon feedstock, said process comprising the steps of (a) passing said hydrocarbon feedstock over an absorbent material comprising nickel deposited on a support material wherein nickel is present as both nickel oxide and metallic nickel and wherein the absorbent material has been conditioned by passing an inert gas flow containing a minor amount of propylene; and (b) recovering a liquid hydrocarbon stream having substantially reduced carbonyl sulfide content.
摘要翻译： 本发明涉及从液体烃原料中除去羰基硫的方法，所述方法包括以下步骤：（a）使所述烃原料通过沉积在载体材料上的包含镍的吸收材料上，其中镍以氧化镍和 金属镍，其中通过使含有少量丙烯的惰性气流通过吸收材料进行调理; 和（b）回收具有显着降低的羰基硫含量的液态烃流。
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公开(公告)号：US4831200A
公开(公告)日：1989-05-16
申请号：US139507
申请日：1987-12-30
IPC分类号： C07C7/167 , B01J23/44 , B01J23/66 , B01J23/70 , C07B61/00 , C07C1/00 , C07C5/08 , C07C11/167 , C07C67/00 , C10G45/34 , C10G45/40 , C10G65/04
CPC分类号： C07C5/08 , C10G65/04 , C07C2521/04 , C07C2523/42 , C07C2523/44 , C07C2523/52 , Y10S526/912
摘要： Alkynes are selectively hydrogenated in alkene rich hydrocarbon feeds, such as 1,3-butadiene-rich C.sub.4 cuts, by passing the hydrocarbon feed at least partially in liquid phase over a palladium-based catalyst in the presence of hydrogen, preferably in trickle mode, followed by passing the effluent, at least partially in liquid phase preferably containing about 300-400 ppmw alkynes, over a copper-based catalyst in the presence of hydrogen thereby producing a hydrocarbon product of significantly reduced alkyne concentration.
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8.发明授权
公开(公告)号：US4613724A
公开(公告)日：1986-09-23
申请号：US753288
申请日：1985-07-09
CPC分类号： C07C7/148
摘要： The present invention relates to a process for removing carbonyl sulfide from a liquid olefinic hydrocarbon feedstock comprising (a) passing said hydrocarbon feedstock over an absorbent material comprising zinc oxide and a promoter selected from the group consisting of alumina, silico-aluminas and any combination thereof; and (b) recovering a liquid olefinic hydrocarbon stream having a substantially reduced carbonyl sulfide content.
摘要翻译： 本发明涉及一种从液态烯烃原料中除去羰基硫的方法，包括（a）使所述烃原料通过包含氧化锌的吸收材料和选自氧化铝，硅铝酸盐及其任何组合的助催化剂 ; 和（b）回收具有显着降低的羰基硫含量的液态烯烃流。
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公开(公告)号：US4556753A
公开(公告)日：1985-12-03
申请号：US719192
申请日：1985-04-03
IPC分类号： B01J21/00 , B01J21/08 , B01J29/035 , C07B61/00 , C07C1/00 , C07C2/08 , C07C4/06 , C07C6/04 , C07C11/09 , C07C67/00 , C07C6/00
CPC分类号： C07C6/04
摘要： A process for producing isobutene, comprising contacting, at elevated temperatures, a feed containing propylene with a catalyst comprising a crystalline silica polymorph of the silicalite type in the presence of steam to recover a stream containing isobutene. The reaction can be carried out in either liquid or vapor phase.
摘要翻译： 一种生产异丁烯的方法，包括在升高的温度下使含有丙烯的进料与含有硅沸石型结晶二氧化硅多晶型物的催化剂在蒸汽存在下接触以回收含有异丁烯的物流。 反应可以在液相或蒸气相中进行。
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10.发明授权
公开(公告)号：US5470456A
公开(公告)日：1995-11-28
申请号：US71435
申请日：1993-06-01
CPC分类号： C10G25/003
摘要： The present invention relates to a process for removing carbonyl sulfide from a liquid hydrocarbon feedstock, said process comprising the steps of (a) passing said hydrocarbon feedstock over an absorbent material comprising nickel deposited on a support material wherein nickel is present as both nickel oxide and metallic nickel and wherein the absorbent material has been conditioned by passing an inert gas flow containing a minor amount of propylene; and (b) recovering a liquid hydrocarbon stream having substantially reduced carbonyl sulfide content.
摘要翻译： 本发明涉及从液体烃原料中除去羰基硫的方法，所述方法包括以下步骤：（a）使所述烃原料通过沉积在载体材料上的包含镍的吸收材料上，其中镍以氧化镍和 金属镍，其中通过使含有少量丙烯的惰性气流通过吸收材料进行调理; 和（b）回收具有显着降低的羰基硫含量的液态烃流。
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