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公开(公告)号：US4748291A
公开(公告)日：1988-05-31
申请号：US8877
申请日：1987-01-29
IPC分类号： C10G11/02 , B01J21/08 , B01J29/035 , B01J29/40 , C01B37/02 , C07C2/00 , C07C2/12 , C07C5/22 , C07C5/41 , C10G11/04 , C10G35/06 , C10G35/095 , C10G50/00 , C07C2/52
CPC分类号： C07C5/41 , B01J29/035 , B01J29/40 , C07C2/00 , C07C2/12 , C07C5/2206 , C10G35/095 , C07C2529/035
摘要： A catalytic treatment process is disclosed, which is carried out under pressure, in the presence of water, and with a molecular sieve catalyst which is TEA-silicate or silicalite previously stabilized by halogenation. This process may be applied to the aromatization or to the isomerization of hydrocarbon feedstocks, and to the oligomerization of olefins. The conversion rate of the process is very stable as a function of time.
摘要翻译： 公开了一种催化处理方法，其在压力下，在水的存在下，和分子筛催化剂进行，分子筛催化剂是TEA-硅酸盐或预先通过卤化稳定的硅沸石。 该方法可以应用于烃原料的芳构化或异构化，以及烯烃的低聚。 该过程的转换率作为时间的函数是非常稳定的。
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公开(公告)号：US4599473A
公开(公告)日：1986-07-08
申请号：US562650
申请日：1983-12-19
IPC分类号： C07C2/70 , B01J29/00 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/86 , C07C15/02 , C07C67/00 , C07C2/68
CPC分类号： C07C2/66 , C07C2/864 , C07C2529/035 , Y02P30/42
摘要： A process for the selective alkylation of monoalkylbenzene into dialkylbenzenes wherein the para isomer of the disubstituted product is present in a concentration greater than in a thermodynamic equilibrium is provided.The method comprises passing the monoalkylbenzene and an alkylating agent capable of methylation, ethylation or propylation through a reaction zone containing an unmodified crystalline silica catalyst of the silicalite type having the monoclinic symmetry.
摘要翻译： 提供了将单烷基苯选择性烷基化成二烷基苯的方法，其中二取代产物的对位异构体以大于热力学平衡的浓度存在。 该方法包括使单烷基苯和能够甲基化，乙基化或丙基化的烷基化剂通过含有具有单斜对称性的硅沸石型未改性的结晶二氧化硅催化剂的反应区。
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公开(公告)号：US06541413B1
公开(公告)日：2003-04-01
申请号：US08459526
申请日：1995-06-02
申请人： Abbas Razavi , Guy L. G. Debras
发明人： Abbas Razavi , Guy L. G. Debras
IPC分类号： B01J3100
CPC分类号： C08F210/16 , C08F4/63904 , C08F4/63912 , C08F4/63916 , C08F4/63922 , C08F10/00 , C08F110/02 , Y10S526/905 , Y10S526/943 , C08F2500/12 , C08F2500/18 , C08F2500/05 , C08F2500/19 , C08F2500/07 , C08F210/14
摘要： The present invention provides a process for preparing polyolefins having a multimodal or at least bimodal molecular weight distribution by contacting in a reaction mixture under polymeriation conditions at least one olefin and a catalyst system comprising a supported catalyst-component comprising an alumoxane and at least two metallocenes containing the same transition metal and selected from the group consisting of mono, di, and tri-cyclopentadienyls and substituted cyclopentadienyls of a transition metal and wherein at least one of the metallocenes is bridged and at least one of the metallocenes is unbridged.
摘要翻译： 本发明提供了一种制备具有多峰或至少双峰分子量分布的聚烯烃的方法，其通过在反应混合物中在聚合条件下使至少一种烯烃和包含负载型催化剂组分的催化剂体系接触，所述催化剂组分包含铝氧烷和至少两种茂金属 其含有相同的过渡金属，并且选自过渡金属的单，二和三环戊二烯基和取代的环戊二烯基，并且其中至少一个金属茂被桥接并且至少一个金属茂是未桥接的。
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4.发明授权
公开(公告)号：US5470456A
公开(公告)日：1995-11-28
申请号：US71435
申请日：1993-06-01
CPC分类号： C10G25/003
摘要： The present invention relates to a process for removing carbonyl sulfide from a liquid hydrocarbon feedstock, said process comprising the steps of (a) passing said hydrocarbon feedstock over an absorbent material comprising nickel deposited on a support material wherein nickel is present as both nickel oxide and metallic nickel and wherein the absorbent material has been conditioned by passing an inert gas flow containing a minor amount of propylene; and (b) recovering a liquid hydrocarbon stream having substantially reduced carbonyl sulfide content.
摘要翻译： 本发明涉及从液体烃原料中除去羰基硫的方法，所述方法包括以下步骤：（a）使所述烃原料通过沉积在载体材料上的包含镍的吸收材料上，其中镍以氧化镍和 金属镍，其中通过使含有少量丙烯的惰性气流通过吸收材料进行调理; 和（b）回收具有显着降低的羰基硫含量的液态烃流。
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5.发明授权
公开(公告)号：US4830735A
公开(公告)日：1989-05-16
申请号：US103239
申请日：1987-09-30
IPC分类号： C07C7/148
CPC分类号： C07C7/148
摘要： The present invention relates to a process for removing carbonyl sulfide from a liquid hydrocarbon feedstock, said process comprising the steps of (a) passing said hydrocarbon feedstock over an absorbent material comprising nickel deposited on a support material wherein nickel is present as both nickel oxide and metallic nickel and wherein the absorbent material has been conditioned by passing an inert gas flow containing a minor amount of propylene; and (b) recovering a liquid hydrocarbon stream having a substantially reduced carbonyl sulfide content.
摘要翻译： 本发明涉及从液体烃原料中除去羰基硫的方法，所述方法包括以下步骤：（a）使所述烃原料通过沉积在载体材料上的包含镍的吸收材料上，其中镍以氧化镍和 金属镍，其中通过使含有少量丙烯的惰性气流通过吸收材料进行调理; 和（b）回收具有显着降低的羰基硫含量的液态烃流。
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公开(公告)号：US4772456A
公开(公告)日：1988-09-20
申请号：US562652
申请日：1983-12-19
IPC分类号： B01J29/035 , B01J29/04 , B01J29/40 , B01J29/70 , C01B33/12 , C01B37/02 , C07C1/00 , C07C2/66 , C07C5/27 , C07C15/02 , C07C67/00 , C01B33/20
CPC分类号： C01B37/02 , B01J29/035 , B01J29/40 , B01J29/70 , C07C2/66 , B01J2229/36 , C07C2529/035 , Y10S423/22
摘要： Disclosed is a process for preparing crystalline silicas having the monoclinic symmetry which comprises the step of calcining in air for at least 3 hours at a temperature of at least 500.degree. C. a crystalline silica of the silicalite type having a silica to alumina atomic ratio of at least 80.
摘要翻译： 公开了一种制备具有单斜对称性的结晶二氧化硅的方法，其包括在至少500℃的温度下在空气中煅烧至少3小时的步骤。硅沸石型的结晶二氧化硅具有二氧化硅与氧化铝的原子比 至少80。
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公开(公告)号：US4587375A
公开(公告)日：1986-05-06
申请号：US719198
申请日：1985-04-03
IPC分类号： B01J21/00 , B01J21/08 , B01J29/035 , C07B61/00 , C07C1/00 , C07C5/27 , C07C11/09 , C07C67/00
CPC分类号： C07C5/277
摘要： A process for the isomerization of n-butenes, comprising contacting, at elevated temperatures, a feed containing n-butenes with a catalyst comprising a crystalline silica polymorph of the silicalite type in the presence of stream to recover a steam containing isobutene. The reaction can be carried out in either liquid or vapor phase.
摘要翻译： 一种正丁烯异构化方法，包括在高温下使含有正丁烯的进料与含有硅沸石型结晶二氧化硅多晶型物的催化剂在流的存在下接触以回收含异丁烯的蒸汽。 反应可以在液相或蒸气相中进行。
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8.发明授权
公开(公告)号：US5674379A
公开(公告)日：1997-10-07
申请号：US473682
申请日：1995-06-07
CPC分类号： C10G25/00 , C10G25/003
摘要： The present invention relates to a process for removing carbonyl sulfide from a liquid hydrocarbon feedstock, said process comprising the steps of (a) passing said hydrocarbon feedstock over an absorbent material comprising nickel deposited on a support material wherein nickel is present as both nickel oxide and metallic nickel and wherein the absorbent material has been conditioned by passing an inert gas flow containing a minor amount of propylene; and (b) recovering a liquid hydrocarbon stream having substantially reduced carbonyl sulfide content.
摘要翻译： 本发明涉及从液体烃原料中除去羰基硫的方法，所述方法包括以下步骤：（a）使所述烃原料通过沉积在载体材料上的包含镍的吸收材料上，其中镍以氧化镍和 金属镍，其中通过使含有少量丙烯的惰性气流通过吸收材料进行调理; 和（b）回收具有显着降低的羰基硫含量的液态烃流。
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公开(公告)号：US5492984A
公开(公告)日：1996-02-20
申请号：US115279
申请日：1993-08-31
申请人： Patrick Brems , Guy L. G. Debras
发明人： Patrick Brems , Guy L. G. Debras
CPC分类号： C08F10/00
摘要： The present invention provides new magnesium chloride-cyclic ether complexes having utility as a component of Ziegler-Natta catalysts for the polymerization of olefins.
摘要翻译： 本发明提供了新的氯化镁 - 环醚络合物，其作为用于烯烃聚合的齐格勒 - 纳塔催化剂的组分具有实用价值。
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公开(公告)号：US4831200A
公开(公告)日：1989-05-16
申请号：US139507
申请日：1987-12-30
IPC分类号： C07C7/167 , B01J23/44 , B01J23/66 , B01J23/70 , C07B61/00 , C07C1/00 , C07C5/08 , C07C11/167 , C07C67/00 , C10G45/34 , C10G45/40 , C10G65/04
CPC分类号： C07C5/08 , C10G65/04 , C07C2521/04 , C07C2523/42 , C07C2523/44 , C07C2523/52 , Y10S526/912
摘要： Alkynes are selectively hydrogenated in alkene rich hydrocarbon feeds, such as 1,3-butadiene-rich C.sub.4 cuts, by passing the hydrocarbon feed at least partially in liquid phase over a palladium-based catalyst in the presence of hydrogen, preferably in trickle mode, followed by passing the effluent, at least partially in liquid phase preferably containing about 300-400 ppmw alkynes, over a copper-based catalyst in the presence of hydrogen thereby producing a hydrocarbon product of significantly reduced alkyne concentration.
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