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公开(公告)号:US4378250A
公开(公告)日:1983-03-29
申请号:US288697
申请日:1981-07-31
申请人: Gerald D. Treadway , Brian J. Carr
发明人: Gerald D. Treadway , Brian J. Carr
IPC分类号: C09D163/00 , C09D183/04 , C09D183/06 , C09D183/08 , C07G17/00 , C09K3/00
CPC分类号: C09D183/06 , C09D183/08 , Y10T428/31612 , Y10T428/31663
摘要: Coating compositions in accordance with the invention are usefully coated on substrates, such as plastic lenses, and cured. The cured coatings provide excellent abrasion resistance and good adherence and weathering properties. The coating compositions comprise an organic solvent and a mixture of at least two components derived by partial hydrolysis from precursor organosilicone compounds. The precursor compounds include a plurality of alkoxy groups, and the at least two components are partially hydrolyzed by greater than 40% of a stoichiometric amount of water required to hydrolyze the alkoxy groups. A first component of the two components is in an imine, aminal or enamine form, which extends working life of the coating compositions.
摘要翻译: 根据本发明的涂料组合物有用地涂覆在诸如塑料透镜的基材上并固化。 固化涂层提供优异的耐磨性和良好的粘附性和耐候性。 涂料组合物包含有机溶剂和由前体有机硅氧烷化合物部分水解得到的至少两种组分的混合物。 前体化合物包括多个烷氧基,并且所述至少两种组分通过水解所述烷氧基所需的化学计量量的水的大于40%部分水解。 两种组分的第一组分是亚胺,胺或烯胺形式,延长了涂料组合物的使用寿命。
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公开(公告)号:US20100068539A1
公开(公告)日:2010-03-18
申请号:US12404717
申请日:2009-03-16
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
CPC分类号: C09D183/06 , C08G59/306 , C08G59/3254 , C08K3/36 , C08K5/5435 , C09D163/00 , Y10T428/31507 , Y10T428/31663 , C08L2666/54
摘要: Coating compositions yielding cured coatings that exhibit excellent abrasion-resistance and hardness for use on polymeric substrates such as the front side of optical lenses, in a manner that meets or exceeds the stringent requirements for such use. The compositions include the hydrolysis product of an epoxy functional alkoxy silane, a viscosity-reducing amount up to 50% by weight, solids basis, of a monomeric (silanol free) epoxy functional epoxy silane, and colloidal silica present in an amount sufficient to improve abrasion resistance as compared to a composition lacking the colloidal silica.
摘要翻译: 产生固化涂层的涂料组合物以满足或超过对这种用途的严格要求的方式表现出优异的耐磨性和硬度,用于聚合物基材例如光学透镜的前侧。 组合物包括环氧官能的烷氧基硅烷的水解产物,至少50重量%的固体基础的单体(无硅烷醇的)环氧官能的环氧硅烷,和以足以改善的量的胶体二氧化硅的胶体二氧化硅的水解产物 与不含胶体二氧化硅的组合物相比,耐磨性。
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公开(公告)号:US07514482B2
公开(公告)日:2009-04-07
申请号:US11188549
申请日:2005-07-25
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
IPC分类号: C08F2/46 , C07D303/02 , C08K5/5435 , C08K5/54 , C08K5/541
CPC分类号: C09D183/06 , C08G59/306 , C08G59/3254 , C08K3/36 , C08K5/5435 , C09D163/00 , Y10T428/31507 , Y10T428/31663 , C08L2666/54
摘要: Coating compositions yielding cured coatings that exhibit excellent abrasion-resistance and hardness for use on polymeric substrates such as the front side of optical lenses, in a manner that meets or exceeds the stringent requirements for such use. The compositions include the hydrolysis product of an epoxy functional alkoxy silane, a viscosity-reducing amount up to 50% by weight, solids basis, of a monomeric (silanol free) epoxy functional epoxy silane, and colloidal silica present in an amount sufficient to improve abrasion resistance as compared to a composition lacking the colloidal silica.
摘要翻译: 产生固化涂层的涂料组合物以满足或超过对这种用途的严格要求的方式表现出优异的耐磨性和硬度,用于聚合物基材例如光学透镜的前侧。 组合物包括环氧官能的烷氧基硅烷的水解产物,至少50重量%的固体基础的单体(无硅烷醇的)环氧官能的环氧硅烷,和以足以改善的量的胶体二氧化硅的胶体二氧化硅的水解产物 与不含胶体二氧化硅的组合物相比,耐磨性。
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公开(公告)号:US6100313A
公开(公告)日:2000-08-08
申请号:US813559
申请日:1997-03-07
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
IPC分类号: C08F2/46 , C09D4/00 , C09D4/02 , C09D4/06 , C09D183/06
CPC分类号: C09D4/00 , C08G59/32 , C08G59/687 , C09D163/00 , C09D183/06 , C09D4/06 , C08K5/5435 , C08L2205/05
摘要: A coating composition for forming a transparent, abrasion-resistant coating upon eyeglass lenses or other transparent substrates, the composition comprising a binder component and a curing agent component and being substantially free of volatiles. The binder component comprises the hydrolysis product of an epoxy-functional alkoxy silane, a polyglycidyl ether, and an acrylic monomer having an acrylic functionality of not more than two. The curing agent component comprises a cationic photoinitiator and a free radical photoinitiator.
摘要翻译: 一种用于在眼镜镜片或其他透明基底上形成透明耐磨涂层的涂料组合物,所述组合物包含粘合剂组分和固化剂组分,并且基本上不含挥发物。 粘合剂组分包括环氧官能烷氧基硅烷,聚缩水甘油醚和丙烯酸官能度不超过2的丙烯酸单体的水解产物。 固化剂组分包含阳离子光引发剂和自由基光引发剂。
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公开(公告)号:US20080311408A1
公开(公告)日:2008-12-18
申请号:US11996626
申请日:2006-03-22
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
CPC分类号: C09D183/06 , C08G59/306 , C08G59/3254 , C08K3/36 , C08K5/5435 , C09D163/00 , Y10T428/31507 , Y10T428/31663 , C08L2666/54
摘要: Coating compositions yielding cured coatings that exhibit excellent abrasion-resistance and hardness for use on polymeric substrates such as the front side of optical lenses, in a manner that meets or exceeds the stringent requirements for such use. The compositions include a monomeric organofunctional silane, and colloidal silica present in an amount sufficient to improve abrasion resistance as compared to a composition lacking the colloidal silica.
摘要翻译: 产生固化涂层的涂料组合物以满足或超过对这种用途的严格要求的方式表现出优异的耐磨性和硬度,用于聚合物基材例如光学透镜的前侧。 与不含胶态二氧化硅的组合物相比,组合物包括单体有机官能硅烷和胶体二氧化硅,其量足以提高耐磨性。
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公开(公告)号:US07384695B2
公开(公告)日:2008-06-10
申请号:US11417272
申请日:2006-05-02
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
IPC分类号: B32B27/38
CPC分类号: G02B1/14 , C08G59/306 , C08G59/3254 , C08J7/047 , C08J2483/00 , C08K5/5435 , C09D4/00 , C09D4/06 , C09D163/00 , C09D183/06 , G02B1/105 , G02B1/111 , Y10T428/31507 , Y10T428/31511 , Y10T428/31663 , Y10T428/31667 , C08G77/00 , C08F283/12 , C08L2666/44 , C08L2666/28 , C08G77/04
摘要: A coating composition based upon at least partially hydrolyzed epoxy-functional alkoxy silanes and having particular utility in forming tintable, abrasion resistant coatings on lenses. Incorporation in the composition of a non-hydrolyzed epoxy-functional alkoxy silane provides a desired reduction in viscosity. Incorporation in the composition of a polyether surfactant provides a cured coating of the composition with increased tintability.
摘要翻译: 一种基于至少部分水解的环氧官能的烷氧基硅烷的涂料组合物,并且在透镜上形成可着色的耐磨涂层具有特别的用途。 掺入未水解的环氧官能的烷氧基硅烷的组合物提供所需的粘度降低。 掺入聚醚表面活性剂的组合物中提供了具有增加的着色性的组合物的固化涂层。
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公开(公告)号:US06780232B2
公开(公告)日:2004-08-24
申请号:US09378318
申请日:1999-08-20
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
IPC分类号: B32B1312
CPC分类号: G02B1/14 , C08G59/306 , C08G59/3254 , C08J7/047 , C08J2483/00 , C08K5/5435 , C09D4/00 , C09D4/06 , C09D163/00 , C09D183/06 , G02B1/105 , G02B1/111 , Y10T428/31507 , Y10T428/31511 , Y10T428/31663 , Y10T428/31667 , C08G77/00 , C08F283/12 , C08L2666/44 , C08L2666/28 , C08G77/04
摘要: A coating composition based upon at least partially hydrolyzed epoxy-functional alkoxy silanes and having particular utility in forming tintable, abrasion resistant coatings on lenses. Incorporation in the composition of a non-hydrolyzed epoxy-functional alkoxy silane provides a desired reduction in viscosity. Incorporation in the composition of a polyether surfactant provides a cured coating of the composition with increased tintability.
摘要翻译: 一种基于至少部分水解的环氧官能的烷氧基硅烷的涂料组合物,并且在透镜上形成可着色的耐磨涂层具有特别的用途。 掺入未水解的环氧官能的烷氧基硅烷的组合物提供所需的粘度降低。 掺入聚醚表面活性剂的组合物中提供了具有增加的着色性的组合物的固化涂层。
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公开(公告)号:US06250760B1
公开(公告)日:2001-06-26
申请号:US09377993
申请日:1999-08-20
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
IPC分类号: G02C702
CPC分类号: G02B1/14 , C09D183/06 , C09D183/08 , G02B1/105 , G02B1/111 , C08L83/00 , C08L2666/54
摘要: A hard, transparent coating for eyeglass lenses and the like, derived from a blend of a hydrolysis product of an epoxy-functional alkoxysilane and an imine derivative of a hydrolysis product of an amine-functional alkoxysilane. Bodying of the coating composition to avoid mudcracking of the coating is rendered unnecessary and pot life is improved by incorporating in the coating composition a metal oxide colloid.
摘要翻译: 衍生自环氧官能烷氧基硅烷的水解产物和胺官能烷氧基硅烷的水解产物的亚胺衍生物的混合物的用于眼镜镜片等的硬透明涂层。 通过在涂料组合物中加入金属氧化物胶体,使涂料组合物变得不必要,从而避免了涂层的泥浆破裂。
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公开(公告)号:US07981514B2
公开(公告)日:2011-07-19
申请号:US12829894
申请日:2010-07-02
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
IPC分类号: B32B27/38
CPC分类号: G02B1/14 , C08G59/306 , C08G59/3254 , C08J7/047 , C08J2483/00 , C08K5/5435 , C09D4/00 , C09D4/06 , C09D163/00 , C09D183/06 , G02B1/105 , G02B1/111 , Y10T428/31507 , Y10T428/31511 , Y10T428/31663 , Y10T428/31667 , C08G77/00 , C08F283/12 , C08L2666/44 , C08L2666/28 , C08G77/04
摘要: A coating composition based upon at least partially hydrolyzed epoxy-functional alkoxy silanes and having particular utility in forming tintable, abrasion resistant coatings on lenses. Incorporation in the composition of a non-hydrolyzed epoxy-functional alkoxy silane provides a desired reduction in viscosity. Incorporation in the composition of a polyether surfactant provides a cured coating of the composition with increased tintability.
摘要翻译: 一种基于至少部分水解的环氧官能的烷氧基硅烷的涂料组合物,并且在透镜上形成可着色的耐磨涂层具有特别的用途。 掺入未水解的环氧官能的烷氧基硅烷的组合物提供所需的粘度降低。 掺入聚醚表面活性剂的组合物中提供了具有增加的着色性的组合物的固化涂层。
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公开(公告)号:US5907000A
公开(公告)日:1999-05-25
申请号:US814166
申请日:1997-03-07
申请人: Gerald D. Treadway
发明人: Gerald D. Treadway
CPC分类号: G02B1/105 , C08F265/06 , C09D4/00 , C09D4/06
摘要: A curable composition for coating eyeglass lenses and other transparent substrates and capable of producing a hard coating, the index of refraction of which can be easily matched, through proper formulating, to the index refraction of the substrate to be coated to thereby avoid visible interference fringes. The composition comprises, in an organic solvent, a plurality of acrylate or methacrylate-functional monomers or oligomers and specifically including a (meth)acrylate-functional monomer having an (meth)acrylate-functionality of at least three and, when cured by itself, having a predetermined index of refraction. Optionally and preferably, the coating composition includes as well a different (meth)acrylate monomer having a functionality of one or more and, when cured by itself, exhibiting a different predetermined index of refraction. Desirably included in the composition is a polymerization catalyst capable of catalyzing polymerization of the (meth)acrylate monomers or oligomers in response to actinic radiation or thermal activation. The composition also includes a colloidal sol of a metal compound, preferably the oxide, of a metal such as antimony, antimony pentoxide being preferred.
摘要翻译: 一种用于涂覆眼镜镜片和其他透明基材并且能够制造硬涂层的可固化组合物,其折射率可以通过适当的配制容易地匹配到待涂布的基底的折射率折射,从而避免可见的干涉条纹 。 该组合物在有机溶剂中包含多种丙烯酸酯或甲基丙烯酸酯官能单体或低聚物,具体包括(甲基)丙烯酸酯官能度至少为3的(甲基)丙烯酸酯官能单体,并且当其自身固化时, 具有预定的折射率。 任选且优选地,涂料组合物还包括具有一个或多个官能度的不同的(甲基)丙烯酸酯单体,并且当其自身固化时,呈现不同的预定折射率。 理想地包括在组合物中的是能够响应于光化辐射或热活化而催化(甲基)丙烯酸酯单体或低聚物聚合的聚合催化剂。 组合物还包括金属化合物的胶体溶胶,优选氧化物,金属如锑,五氧化二锑是优选的。
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