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    Branched block copolymers and their manufacture
    1.
    发明授权
    Branched block copolymers and their manufacture 失效
    支链嵌段共聚物及其制备方法

    公开(公告)号：US4167545A

    公开(公告)日：1979-09-11

    申请号：US896478

    申请日：1978-04-14

    申请人： Gerhard Fahrbach ,  Karl Gerberding ,  Erhard Seiler ,  Dieter Stein

    发明人： Gerhard Fahrbach ,  Karl Gerberding ,  Erhard Seiler ,  Dieter Stein

    IPC分类号： C08F297/04 ,  C08G81/02

    CPC分类号： C08G81/022 ,  C08F297/044

    摘要： Branched block copolymers of from 60 to 95 percent by weight of a monovinyl-aromatic compound and from 40 to 5 percent by weight of a conjugated diene.The branched block copolymers have a structure of the general formula(A.sup.1 --A.sup.2 --B.fwdarw.A.sup.3).sub.n --X--(A.sup.3 .rarw.B--A.sup.2).sub.mwhere the A's are non-elastomeric polymer segments based on the monovinyl-aromatic compound, the B's are elastomeric polymer segments based on the conjugated diene, X is the radical of an at least trifunctional coupling agent and n and m are numbers.The branched block copolymers may be used for the manufacture of highly transparent impact-resistant shaped articles, especially packaging materials.

    摘要翻译： 60至95重量％的单乙烯基 - 芳族化合物和40至5重量％的共轭二烯的支链嵌段共聚物。

    Branched block copolymers and their manufacture
    2.
    发明授权
    Branched block copolymers and their manufacture 失效
    支链嵌段共聚物及其制备方法

    公开(公告)号：US4086298A

    公开(公告)日：1978-04-25

    申请号：US732890

    申请日：1976-10-15

    申请人： Gerhard Fahrbach ,  Karl Gerberding ,  Erhard Seiler ,  Dieter Stein

    发明人： Gerhard Fahrbach ,  Karl Gerberding ,  Erhard Seiler ,  Dieter Stein

    IPC分类号： C08F2/00 ,  C08F2/38 ,  C08F8/00 ,  C08F8/04 ,  C08F297/00 ,  C08F297/02 ,  C08F297/04 ,  C08G81/02

    CPC分类号： C08G81/022

    摘要： Branched block copolymers of from 60 to 95 percent by weight of a monovinyl-aromatic compound and from 40 to 5 percent by weight of a conjugated diene. The copolymers have a structure of the general formula(A.sup.1 -B.fwdarw.A.sup.2).sub.n --X--(A.sup.2 .rarw.B).sub.mwhere the A's are non-elastomeric polymer segments based on the monovinyl-aromatic compound, the B's are elastomeric polymer segments based on the conjugated diene, X is the radical of an at least trifunctional coupling agent and n and m are numbers. The copolymers may be used for the manufacture of highly transparent impact-resistant shaped articles, especially packaging materials.

    摘要翻译： 60至95重量％的单乙烯基 - 芳族化合物和40至5重量％的共轭二烯的支链嵌段共聚物。 共聚物具有通式（A1-B-> A2）nX-（A2 <-B）m的结构A是基于单乙烯基 - 芳族化合物的非弹性聚合物链段，B是基于弹性体聚合物链段 在共轭二烯上，X是至少三官能偶联剂的基团，n和m是数。 共聚物可用于制造高度透明的耐冲击成型制品，特别是包装材料。

    Block or graft copolymers of polyalkylene oxides and vinylaromatic or diene polymers
    4.
    发明授权
    Block or graft copolymers of polyalkylene oxides and vinylaromatic or diene polymers 失效
    聚环氧烷和乙烯基芳族或二烯聚合物的嵌段或接枝共聚物

    公开(公告)号：US4029720A

    公开(公告)日：1977-06-14

    申请号：US555026

    申请日：1975-03-03

    申请人： Erhard Seiler ,  Gerhard Fahrbach ,  Dieter Stein

    发明人： Erhard Seiler ,  Gerhard Fahrbach ,  Dieter Stein

    IPC分类号： C08G18/62 ,  C08G18/69 ,  C08G81/02 ,  D06M15/263 ,  D06M15/53 ,  C08L9/00 ,  C08L9/06

    CPC分类号： D06M15/53 ,  C08G18/6204 ,  C08G18/694 ,  C08G81/025 ,  D06M15/263

    摘要： A process for the manufacture of block or graft copolymers of polyalkylene oxides and vinylaromatic polymers or diene polymers. The block or graft copolymers are manufactured by reacting vinylaromatic polymers or diene polymers bearing methyl methacrylate end groups with polyalkylene oxides bearing alkali metal alcoholate end groups. The block or graft copolymers may be used as antistatic agents for plastics, as coating materials for non-woven webs, as intermediates in the manufacture of polyurethanes and as surfactants, protective colloids or emulsifiers.

    摘要翻译： 一种制备聚环氧烷和乙烯基芳族聚合物或二烯聚合物的嵌段或接枝共聚物的方法。 嵌段或接枝共聚物通过使具有甲基丙烯酸甲酯端基的聚乙烯基芳族聚合物或二烯聚合物与具有碱金属醇化物端基的聚环氧烷反应来制备。 嵌段或接枝共聚物可以用作塑料的抗静电剂，作为无纺网的涂料，作为制备聚氨酯和表面活性剂，保护胶体或乳化剂的中间体。

    Graft copolymers based on methyl methacrylate polymers
    5.
    发明授权
    Graft copolymers based on methyl methacrylate polymers 失效
    基于甲基丙烯酸甲酯聚合物的接枝共聚物

    公开(公告)号：US4002703A

    公开(公告)日：1977-01-11

    申请号：US603857

    申请日：1975-08-12

    申请人： Gerhard Fahrbach ,  Erhard Seiler ,  Dieter Stein

    发明人： Gerhard Fahrbach ,  Erhard Seiler ,  Dieter Stein

    IPC分类号： C08G81/02 ,  C08L33/04

    CPC分类号： C08G81/025

    摘要： This invention relates to a process for the manufacture of graft copolymers based on methyl methacrylate polymers. The methyl methacrylate polymer is reacted with a high molecular weight organic compound containing at least one alkylene oxide unit having an alkali metal alcoholate end group, during which reaction transesterification occurs to eliminate alkali metal methoxide and cause chain joining. The graft copolymers may be used for the production of shaped articles or coating compositions and as additives, antistatic agents or adhesion promoters for plastics materials.

    摘要翻译： 本发明涉及一种制备基于甲基丙烯酸甲酯聚合物的接枝共聚物的方法。 甲基丙烯酸甲酯聚合物与含有至少一个具有碱金属醇化物端基的烯化氧单元的高分子量有机化合物反应，在此期间进行反应酯交换以除去碱金属甲醇盐并引起链接。 接枝共聚物可用于生产成形制品或涂料组合物，以及用作塑料材料的抗静电剂或粘合促进剂的添加剂。

    Graft copolymers based on methyl methacrylate polymers
    7.
    发明授权
    Graft copolymers based on methyl methacrylate polymers 失效
    基于甲基丙烯酸甲酯聚合物的接枝共聚物

    公开(公告)号：US3933943A

    公开(公告)日：1976-01-20

    申请号：US409257

    申请日：1973-10-24

    申请人： Gerhard Fahrbach ,  Erhard Seiler ,  Dieter Stein

    发明人： Gerhard Fahrbach ,  Erhard Seiler ,  Dieter Stein

    IPC分类号： C08G81/00 ,  C08G81/02 ,  C08L9/06

    CPC分类号： C08G81/021 ,  C08G81/02 ,  C08G81/025

    摘要： This invention relates to a process for the manufacture of graft copolymers based on methyl methacrylate polymers. The methyl methacrylate polymer is reacted with a high molecular weight organic compound containing at least one alkylene oxide unit having an alkali metal alcoholate end group, during which reaction transesterification occurs to eliminate alkali metal methoxide and cause chain joining. The graft copolymers may be used for the production of shaped articles or coating compositions and as additives, antistatic agents or adhesion promoters for plastics materials.

    摘要翻译： 本发明涉及一种制备基于甲基丙烯酸甲酯聚合物的接枝共聚物的方法。 甲基丙烯酸甲酯聚合物与含有至少一个具有碱金属醇化物端基的烯化氧单元的高分子量有机化合物反应，在此期间进行反应酯交换以除去碱金属甲醇盐并引起链接。 接枝共聚物可用于生产成形制品或涂料组合物，以及用作塑料材料的抗静电剂或粘合促进剂的添加剂。

    Laminates for the manufacture of flexographic printing plates using block copolymers
    9.
    发明授权
    Laminates for the manufacture of flexographic printing plates using block copolymers 失效
    用于制造使用嵌段共聚物的柔版印刷版的层压板

    公开(公告)号：US4162919A

    公开(公告)日：1979-07-31

    申请号：US851824

    申请日：1977-11-16

    申请人： Peter Richter ,  August Wigger ,  Gerhard Fahrbach ,  Erhard Seiler ,  Helmut Barzynski

    发明人： Peter Richter ,  August Wigger ,  Gerhard Fahrbach ,  Erhard Seiler ,  Helmut Barzynski

    IPC分类号： G03F7/11 ,  G03C1/78 ,  G03C1/68 ,  G03C1/76 ,  G03C5/00

    CPC分类号： G03F7/11 ,  Y10S430/108

    摘要： Laminates for the manufacture of flexographic printing plates and containing (a) a layer consisting essentially of a photocrosslinkable mixture of a two-block copolymer of from 30 to 95% w/w of a diene hydrocarbon and from 5 to 70% w/w of a styrene monomer or a partially hydrogenated product thereof with a compatible monomer having at least one C--C double bond, said mixture containing a photo-initiator, (b) a non-photocrosslinkable elastomeric underlayer having a Shore A hardness of from 15 to 70 and (c) a non-photocrosslinkable stablizing layer preferably between layers (a) and (b).

    摘要翻译： 用于制造柔版印刷版的层压板，并含有（a）基本上由30-95％w / w的二烯烃和5-70％w / w的二嵌段共聚物的可光致交联混合物组成的层， 苯乙烯单体或其部分氢化产物与具有至少一个CC双键的相容单体，所述混合物含有光引发剂，（b）肖氏A硬度为15至70的非光可交联弹性体底层和（ c）优选在层（a）和（b）之间的非光可交联稳定层。