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1.发明授权Polyisocyanate compositions having a long shelf life and obtainable by phosgene-free methods, their preparation and their use 失效多异氰酸酯组合物具有长的保质期，可通过无光气的方法获得，其制备及其用途
公开(公告)号：US5728317A
公开(公告)日：1998-03-17
申请号：US647877
申请日：1996-05-13
申请人： Gerhard Laqua , Franz Merger , Tom Witzel , Ursula Siebenhaar , David Agar
发明人： Gerhard Laqua , Franz Merger , Tom Witzel , Ursula Siebenhaar , David Agar
IPC分类号： C07C263/18 , C07C265/14 , C08G18/73 , C08G18/75 , C08G18/79 , C08K5/00 , C09K3/00 , C07C249/00 , C07C251/00 , C07C257/00
CPC分类号： C08G18/792 , C07C263/18 , C07C265/14 , C08G18/022 , C08G18/092 , C08G18/73 , C08G18/75 , C08K5/005 , C07C2101/14
摘要： (Cyclo)aliphatic polyisocyanate compositions which have a long shelf life, are obtainable by phosgene-free methods, preferably by thermal cleavage of (cyclo)aliphatic polycarbamates, and, for stabilization, contain at least one primary stabilizer (2a), preferably a sterically hindered phenol and/or an aromatic amine, or at least one secondary stabilizer (2b), preferably an organic phosphite and/or a thioether, or at least one acidic stabilizer (2c), preferably a carboxylic acid, an acyl chloride, an inorganic acid, an inorganic acid chloride and/or a diester of phosphoric acid, or a stabilizer system comprising at least 2 of the stabilizers (2a) to (2c), a process for the preparation of the (cyclo)aliphatic polyisocyanate compositions and their preferred use for the preparation of isocyanurate-containing polyisocyanates.
摘要翻译： 具有长保质期的（Cyclo）脂族多异氰酸酯组合物可通过无光气的方法获得，优选通过（环）脂族聚氨基甲酸酯的热裂解获得，并且为了稳定，含有至少一种主要稳定剂（2a），优选为空间 受阻酚和/或芳族胺，或至少一种仲级稳定剂（2b），优选有机亚磷酸酯和/或硫醚，或至少一种酸性稳定剂（2c），优选羧酸，酰氯，无机 酸，无机酰氯和/或磷酸二酯，或包含至少2种稳定剂（2a）至（2c）的稳定剂体系，制备（环）脂族多异氰酸酯组合物及其优选的 用于制备含异氰脲酸酯的多异氰酸酯。
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2.发明授权Preparation of polyisocyanates containing isocyanurate groups and use thereof 失效含有异氰脲酸酯基团的多异氰酸酯的制备及其用途
公开(公告)号：US5489663A
公开(公告)日：1996-02-06
申请号：US356084
申请日：1994-12-15
申请人： Peter Brandt , Bernd Bruchmann , Gerhard Laqua , Franz Merger , Andreas Otterbach , Konrad Stiefenhofer , Tom Witzel , Stefan Wolff , Rainer Becker
发明人： Peter Brandt , Bernd Bruchmann , Gerhard Laqua , Franz Merger , Andreas Otterbach , Konrad Stiefenhofer , Tom Witzel , Stefan Wolff , Rainer Becker
IPC分类号： B01J20060101 , B01J31/02 , C07B61/00 , C07D20060101 , C07D251/34 , C08G20060101 , C08G18/02 , C08G18/18 , C08G18/79 , C09D20060101 , C08G18/20 , C08G18/16
CPC分类号： C07D251/34 , C08G18/792
摘要： Polyisocyanates containing isocyanurate groups are prepared by a partial trimerization of (cyclo)aliphatic diisocyanates in the presence of at least one trimerization catalyst selected from the group consisting of tetraalkylammonium alkyl carbonates of the formula (I) ##STR1## (quaternary ammonioalkyl) carbonates having a betaine structure of the formula (II) ##STR2## and the preferred use of the polyisocyanates containing isocyanurate groups which are obtainable in this way is aspolyisocyanate component in polyurethane finishes.
摘要翻译： 含有异氰脲酸酯基的多异氰酸酯是通过在至少一种选自式（I）的四烷基烷基碳酸酯（I）（季铵烷基））的三聚催化剂存在下，通过（环）脂族二异氰酸酯的部分三聚制备的， 具有式（II）的甜菜碱结构的碳酸酯（II）和以这种方式获得的含有异氰脲酸酯基团的多异氰酸酯的优选用途是聚氨酯涂料中的多异氰酸酯组分。
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公开(公告)号：US5516928A
公开(公告)日：1996-05-14
申请号：US395322
申请日：1995-02-28
申请人： Klaus Mundinger , Gerhard Laqua , Tom Witzel , Franz Merger
发明人： Klaus Mundinger , Gerhard Laqua , Tom Witzel , Franz Merger
IPC分类号： C07C253/10 , C07C255/46
CPC分类号： C07C253/10 , C07C2101/14
摘要： A process for the preparation of 3-cyano-3,5,5-trimethylcyclohexanone by the reaction of isophorone with hydrogen cyanide in the presence of quaternary ammonium catalysts at temperatures ranging from 80.degree. to 180.degree. C. and pressures ranging from 0.5 to 20 bar, in which the ammonium catalysts used are salts of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 denote C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.8 cycloalkyl, aryl, C.sub.7 -C.sub.18 aralkyl or C.sub.2 -C.sub.18 hydroxyalkyl andX denotes HCO.sub.3 or ##STR2## with the proviso that R.sup.4 stands for C.sub.1 -C.sub.8 alkyl when X is ##STR3##
摘要翻译： 在季铵催化剂存在下，通过异佛尔酮与氰化氢反应制备3-氰基-3,5,5-三甲基环己酮的方法，温度范围为80-180℃，压力范围为0.5-20 其中使用的铵催化剂是通式I的盐，其中R 1，R 2，R 3，R 4表示C 1 -C 18烷基，C 5 -C 8环烷基，芳基，C 7 -C 18芳烷基或C 2-8芳烷基， C18羟烷基，X表示HCO3或者“IMAGE”，条件是当X为
时，R4代表C1-C8烷基， -
4.发明授权Long-term operation of a heterogeneously catalyzed gas phase partial oxidation of at least one organic compound 失效长期运行至少一种有机化合物的异质催化气相部分氧化公开(公告)号：US07518016B2
公开(公告)日：2009-04-14
申请号：US11121986
申请日：2005-05-05
IPC分类号： C07C51/16
CPC分类号： B01J8/0285 , B01J2208/00061 , B01J2208/00539 , C07B41/00 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of at least one organic compound over a catalyst bed, in which, in order to counteract the deactivation of the catalyst bed, the working pressure in the gas phase is increased during the operating time of the catalyst bed.
摘要翻译： 在催化剂床上长期运行至少一种有机化合物的非均相催化气相部分氧化的方法，其中为了抵消催化剂床的失活，气相中的工作压力增加 在催化剂床的操作时间内。
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5.发明申请PROCESS FOR HETEROGENEOUSLY CATALYZED GAS PHASE PARTIAL OXIDATION OF AT LEAST ONE ORGANIC STARTING COMPOUND 有权用于异源催化气相的方法部分氧化至少一种有机起始化合物公开(公告)号：US20070155988A1
公开(公告)日：2007-07-05
申请号：US11612824
申请日：2006-12-19
IPC分类号： C07C51/16
CPC分类号： C07C51/252 , B01J8/067 , B01J23/002 , B01J23/24 , B01J23/887 , B01J23/92 , B01J35/0006 , B01J2208/00221 , B01J2208/025 , B01J2523/00 , C07C45/35 , C07C51/215 , Y02P20/584 , C07C57/04 , C07C47/22 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/27 , B01J2523/51 , B01J2523/847
摘要： A process for heterogeneously catalyzed gas phase partial oxidation of an organic starting compound over a fixed catalyst bed freshly installed into a reaction chamber, in which the reduction in the quality of the fixed catalyst bed is restored with increasing operating time by replacing a portion of the fixed catalyst bed by a replacement fixed catalyst bed part whose volume-specific activity is lower than the volume-specific activity of the replaced fixed catalyst bed part in its freshly installed state.
摘要翻译： 一种在新鲜安装到反应室中的固定催化剂床上的有机起始化合物的非均相催化气相部分氧化的方法，其中固定催化剂床的质量的降低通过增加操作时间而恢复， 固定催化剂床通过替代的固定催化剂床部分，其体积比活度低于其新安装状态下更换的固定催化剂床部分的体积比活性。
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公开(公告)号：US06888006B2
公开(公告)日：2005-05-03
申请号：US10275564
申请日：2001-05-10
申请人： Herbert Helfert , Martin Schmidt-Radde , Gerhard Laqua , Ulrich Eiden , Stephan Scholl , Christoph Übler
发明人： Herbert Helfert , Martin Schmidt-Radde , Gerhard Laqua , Ulrich Eiden , Stephan Scholl , Christoph Übler
IPC分类号： B01D3/14 , B01J3/00 , C07D201/16 , C07D207/26 , C07D207/267
CPC分类号： C07D207/267 , C07D201/16
摘要： A process for working up residues from the preparation of pyrrolidone and/or N-vinylpyrrolidone comprises subjecting the residues to a thermolysis.
摘要翻译： 从制备吡咯烷酮和/或N-乙烯基吡咯烷酮处理残留物的方法包括使残余物进行热分解。
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7.发明授权Process for heterogeneously catalyzed gas phase partial oxidation of at least one organic starting compound 有权至少一种有机起始化合物的非均相催化气相部分氧化的方法公开(公告)号：US07518015B2
公开(公告)日：2009-04-14
申请号：US11612824
申请日：2006-12-19
IPC分类号： C07C51/16
CPC分类号： C07C51/252 , B01J8/067 , B01J23/002 , B01J23/24 , B01J23/887 , B01J23/92 , B01J35/0006 , B01J2208/00221 , B01J2208/025 , B01J2523/00 , C07C45/35 , C07C51/215 , Y02P20/584 , C07C57/04 , C07C47/22 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/27 , B01J2523/51 , B01J2523/847
摘要： A process for heterogeneously catalyzed gas phase partial oxidation of an organic starting compound over a fixed catalyst bed freshly installed into a reaction chamber, in which the reduction in the quality of the fixed catalyst bed is restored with increasing operating time by replacing a portion of the fixed catalyst bed by a replacement fixed catalyst bed part whose volume-specific activity is lower than the volume-specific activity of the replaced fixed catalyst bed part in its freshly installed state.
摘要翻译： 一种在新鲜安装到反应室中的固定催化剂床上的有机起始化合物的非均相催化气相部分氧化的方法，其中固定催化剂床的质量的降低通过增加操作时间而恢复， 固定催化剂床通过替代的固定催化剂床部分，其体积比活度低于其新安装状态下更换的固定催化剂床部分的体积比活性。
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8.发明申请Long-term operation of a heterogeneously catalyzed gas phase partial oxidation of at least one organic compound 失效长期运行至少一种有机化合物的异质催化气相部分氧化公开(公告)号：US20050261517A1
公开(公告)日：2005-11-24
申请号：US11121986
申请日：2005-05-05
IPC分类号： B01J8/02 , C07B41/00 , C07C45/34 , C07C45/35 , C07C51/16 , C07C51/235 , C07C51/25 , C07C51/255
CPC分类号： B01J8/0285 , B01J2208/00061 , B01J2208/00539 , C07B41/00 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of at least one organic compound over a catalyst bed, in which, in order to counteract the deactivation of the catalyst bed, the working pressure in the gas phase is increased during the operating time of the catalyst bed.
摘要翻译： 在催化剂床上长期运行至少一种有机化合物的非均相催化气相部分氧化的方法，其中为了抵消催化剂床的失活，气相中的工作压力增加 在催化剂床的操作时间内。
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9.发明申请APPARATUS FOR LONG-TERM OPERATION OF A HETEROGENEOUSLY CATALYZED GAS PHASE PARTIAL OXIDATION OF AT LEAST ONE ORGANIC COMPOUND 审中-公开用于长时间操作异源催化气相的装置相对于至少一种有机化合物的部分氧化公开(公告)号：US20080187467A1
公开(公告)日：2008-08-07
申请号：US12043417
申请日：2008-03-06
IPC分类号： B01J19/24
CPC分类号： B01J8/0285 , B01J2208/00061 , B01J2208/00539 , C07B41/00 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： Apparatus for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of at least one organic compound over a catalyst bed, in which, in order to counteract the deactivation of the catalyst bed, the working pressure in the gas phase is increased during the operating time of the catalyst bed.
摘要翻译： 用于在催化剂床上长期运行至少一种有机化合物的非均相催化气相部分氧化的装置，其中为了抵消催化剂床的失活，气相中的工作压力在 催化剂床的操作时间。
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公开(公告)号：US06750365B2
公开(公告)日：2004-06-15
申请号：US10133329
申请日：2002-04-29
申请人： Gerhard Laqua , Matthias Klötzer , Volker Krase , Peter Pfab , Joachim Pfeffinger , Andreas Schmidt
发明人： Gerhard Laqua , Matthias Klötzer , Volker Krase , Peter Pfab , Joachim Pfeffinger , Andreas Schmidt
IPC分类号： C07C26100
CPC分类号： C07C263/00 , C07C269/00 , C07C265/04 , C07C271/12
摘要： The present invention relates to a process for the dissociation of allophanates, in which a thermal dissociation is carried out in a reaction vessel and the gaseous dissociation products obtained are removed from the reaction vessel using an inert carrier gas or the vapor of a liquid as stripping medium and are condensed.
摘要翻译： 本发明涉及一种用于解离脲基甲酸酯的方法，其中在反应容器中进行热解离，并且使用惰性载气或液体的蒸气作为汽提从所述反应容器中除去所得的气体解离产物 中等浓度。
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