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    Preparation of biuret-containing polyisocyanates
    4.
    发明授权
    Preparation of biuret-containing polyisocyanates 失效
    制备含缩二脲的聚异氰酸酯

    公开(公告)号：US07022874B2

    公开(公告)日：2006-04-04

    申请号：US08894156

    申请日：1996-02-01

    申请人： Bernd Bruchmann ,  Stefan Wolff ,  Wolfgang Heider ,  Joachim Jähme ,  Werner Langer ,  Hans Renz

    发明人： Bernd Bruchmann ,  Stefan Wolff ,  Wolfgang Heider ,  Joachim Jähme ,  Werner Langer ,  Hans Renz

    IPC分类号： C07C273/18 ,  C07C273/00 ,  C07C275/62

    CPC分类号： C07C273/1863 ,  C07C265/14 ,  C07C273/1872 ,  C08G18/7831 ,  C07C275/62

    摘要： A process for the preparation of polyisocyanates which contain one or more biuret groups, by reacting a) an aliphatic or cycloaliphatic isocyanate containing two or more isocyanate groups (isocyanate a) with b) a tertiary alcohol or a mixture of water and a tertiary alcohol (biuretizing agent b) at from 100 to 250° C., which comprises carrying out the reaction in the presence c) of a stabilizer (c) which constitutes a catalytic amount of urea, ammonia, biuret, a urea derivative of the formula I in which R1, R2, R3 and R4 are hydrogen, C1 to C10 alkyl or C5 to C10 aryl, or a carboxamide of the formula II in which R5 is C1 to C12 alkyl which is unsubstituted or in which 1, 2 or 3 hydrogen atoms are replaced by a radical

    摘要翻译： 一种制备含有一个或多个缩二脲基团的多异氰酸酯的方法，通过使a）含有两个或多个异氰酸酯基团（异氰酸酯a）的脂族或脂环族异氰酸酯与b）叔醇或水与叔醇的混合物 缩合剂b）在100至250℃下进行，其包括在c）中进行反应，c）稳定剂（c）构成催化量的尿素，氨，缩二脲，式I的脲衍生物在 其中R 1，R 2，R 3和R 4是氢，C 1〜 C 1 -C 10烷基或C 5至C 10芳基或式II的甲酰胺，其中R 5， C 1 -C 12烷基是未被取代的或其中1,2或3个氢原子被基团取代的C 1 -C 12烷基

    Highly functional polyetherols and the production and use thereof
    8.
    发明授权
    Highly functional polyetherols and the production and use thereof 有权
    高功能性聚醚类及其生产和使用

    公开(公告)号：US08946377B2

    公开(公告)日：2015-02-03

    申请号：US12866464

    申请日：2009-02-12

    申请人： Rolf Muelhaupt ,  Anne Fiedler ,  Fabian Schueler ,  Bernd Bruchmann ,  Markus Schuette ,  Daniel Schoenfelder

    发明人： Rolf Muelhaupt ,  Anne Fiedler ,  Fabian Schueler ,  Bernd Bruchmann ,  Markus Schuette ,  Daniel Schoenfelder

    IPC分类号： C08G63/668 ,  C08G63/688 ,  C08G63/695 ,  C08G63/82 ,  C08G65/28 ,  C08G65/34 ,  C08G65/26 ,  C08G65/30 ,  C08G65/46 ,  C08G65/48

    CPC分类号： C08G65/2609 ,  C08G65/30 ,  C08G65/34 ,  C08G65/46 ,  C08G65/48 ,  Y10S424/16

    摘要： The present invention relates to a process for preparing high-functionality polyetherols by reacting at least one trifunctional or higher-functionality alcohol and if appropriate further di- and/or monofunctional alcohols and/or modifying reagents, with the aid of acidic catalysts, where the trifunctional or higher-functionality alcohol is not glycerol. The present invention further relates to high-functionality polyetherols obtainable by such a process and to the use of these high-functionality polyetherols as adhesion promoters, thixotropic agents, rheology modifiers of polymers, phase transfer reagents, micro- or nanocontainers for biologically active compounds, for example for active medical ingredients, biocides, herbicides or fungicides, as pigment dispersants, an additive in printing inks or as structural units for preparing polyaddition or polycondensation polymers or for treatment of seed.

    摘要翻译： 本发明涉及通过在酸性催化剂的帮助下使至少一种三官能或更高官能度的醇与适当的其它二 - 和/或单官能醇和/或改性试剂反应制备高官能度聚醚的方法，其中 三官能或高官能醇不是甘油。 本发明还涉及通过这种方法获得的高官能度聚醚醚，以及这些高官能度聚醚类作为粘合促进剂，触变剂，聚合物的流变改性剂，相转移试剂，生物活性化合物的微型或纳米容器的用途， 例如用于活性医疗成分，杀生物剂，除草剂或杀真菌剂，作为颜料分散剂，印刷油墨中的添加剂或用于制备加聚或缩聚聚合物或用于种子处理的结构单元。

    Branched polyesters with sulfonate groups
    9.
    发明授权
    Branched polyesters with sulfonate groups 有权
    具有磺酸基团的支化聚酯

    公开(公告)号：US08901066B2

    公开(公告)日：2014-12-02

    申请号：US13495512

    申请日：2012-06-13

    申请人： Monika Haberecht ,  Juergen Detering ,  Bernd Bruchmann ,  Helmut Witteler ,  Heike Weber ,  Karl Kolter

    发明人： Monika Haberecht ,  Juergen Detering ,  Bernd Bruchmann ,  Helmut Witteler ,  Heike Weber ,  Karl Kolter

    IPC分类号： C11D3/37 ,  C11D1/00 ,  B08B3/04 ,  C08G63/91 ,  C02F5/10 ,  C08G63/688

    CPC分类号： C02F5/10 ,  C08G63/6884 ,  C08G63/918 ,  C11D3/378

    摘要： Branched polyesters with sulfonate groups can be obtained by reacting components A, B, optionally C, and optionally D to yield branched polyesters, then reacting these branched polyesters with hydrogen sulfite. Component A is at least one α,β-olefinically unsaturated dicarboxylic acid, component B is at least one di- or higher-functional alcohol, optional component C is at least one di- or higher-functional carboxylic acid or hydroxycarboxylic acid without an α,β-olefinically unsaturated bond, and optional component D is at least one compound of formula CH3(—O—CH2—CH2)n—OH. In reacting the branched polyesters with hydrogen sulfite, a molar amount of hydrogen sulfite is at most 95 mol %, based on an amount of α,β-olefinically unsaturated dicarboxylic acid.

    摘要翻译： 具有磺酸盐基团的支链聚酯可以通过使组分A，B，任选地C和任选的D反应得到支链聚酯，然后使这些支化聚酯与亚硫酸氢钠反应而获得。 组分A是至少一种α，β-烯属不饱和二羧酸，组分B是至少一种二官能或更高官能的醇，任选的组分C是至少一种二官能或更高官能的羧酸或羟基羧酸，没有 α，β-烯属不饱和键，任选的组分D是至少一种式CH3（-O-CH2-CH2）n-OH的化合物。 在使支化聚酯与亚硫酸氢钠反应时，基于α，α-烯属不饱和二羧酸的量，亚硫酸氢的摩尔量为至多95摩尔％。