Molecular optimization of multiply-functionalized mesostructured materials
    6.
    发明授权
    Molecular optimization of multiply-functionalized mesostructured materials 有权
    多官能化介孔结构材料的分子优化

    公开(公告)号:US08758653B2

    公开(公告)日:2014-06-24

    申请号:US12792590

    申请日:2010-06-02

    IPC分类号: B05D5/12 B82Y30/00 B82Y40/00

    CPC分类号: C01B37/00 C01B39/026 C07F7/21

    摘要: A material and method for producing mesostructured materials with multiple functionalities that are independently adjustable and collectively optimizable is provided. The method uses a series of discrete synthesis steps under otherwise mutually incompatible conditions, e.g., from acidic, alkaline, and/or non-aqueous solutions, allows different functionalities to be introduced to the materials and optimized. To illustrate the method, cubic mesoporous silica films were prepared from strongly acidic solutions that were separately functionalized under highly alkaline conditions to incorporate hydrophilic aluminosilica moieties and under non-aqueous conditions to introduce perfluorosulfonic-acid surface groups.

    摘要翻译: 提供了一种用于生产具有独立可调整和可共同优化的多种功能的介观材料的材料和方法。 该方法在另外相互不相容的条件下使用一系列离散的合成步骤,例如从酸性,碱性和/或非水溶液中,允许将不同的官能团引入材料并进行优化。 为了说明该方法,从强酸性溶液制备立方介孔二氧化硅膜,其在高碱性条件下分别官能化以掺入亲水性铝硅氧烷部分,并在非水条件下引入全氟磺酸表面基团。

    MOLECULAR OPTIMIZATION OF MULTIPLY-FUNCTIONALIZED MESOSTRUCTURED MATERIALS
    7.
    发明申请
    MOLECULAR OPTIMIZATION OF MULTIPLY-FUNCTIONALIZED MESOSTRUCTURED MATERIALS 有权
    多功能结构材料的分子优化

    公开(公告)号:US20100311856A1

    公开(公告)日:2010-12-09

    申请号:US12792590

    申请日:2010-06-02

    IPC分类号: C08J9/00

    CPC分类号: C01B37/00 C01B39/026 C07F7/21

    摘要: A material and method for producing mesostructured materials with multiple functionalities that are independently adjustable and collectively optimizable is provided. The method uses a series of discrete synthesis steps under otherwise mutually incompatible conditions, e.g., from acidic, alkaline, and/or non-aqueous solutions, allows different functionalities to be introduced to the materials and optimized. To illustrate the method, cubic mesoporous silica films were prepared from strongly acidic solutions that were separately functionalized under highly alkaline conditions to incorporate hydrophilic aluminosilica moieties and under non-aqueous conditions to introduce perfluorosulfonic-acid surface groups.

    摘要翻译: 提供了一种用于生产具有独立可调整和可共同优化的多种功能的介观材料的材料和方法。 该方法在另外相互不相容的条件下使用一系列离散的合成步骤,例如从酸性,碱性和/或非水溶液中,允许将不同的官能团引入材料并进行优化。 为了说明该方法,从强酸性溶液制备立方介孔二氧化硅膜,其在高碱性条件下分别官能化以掺入亲水性铝硅氧烷部分,并在非水条件下引入全氟磺酸表面基团。

    Mesostructured inorganic materials prepared with controllable orientational ordering
    8.
    发明授权
    Mesostructured inorganic materials prepared with controllable orientational ordering 失效
    用可控取向排列制备的中等结构无机材料

    公开(公告)号:US07837909B2

    公开(公告)日:2010-11-23

    申请号:US11735252

    申请日:2007-04-13

    IPC分类号: C04B35/634

    摘要: Mesostructured inorganic-organic materials, in the form of patterned films, monoliths, and fibers, can be prepared with controllable orientational ordering over macroscopic length scales. They are synthesized by controlling solvent removal rates across material interfaces, in conjunction with the rates of surfactant self-assembly and inorganic cross-linking and surface interactions. A method for controlling the rates and directions of solvent removal from a heterogeneous material synthesis mixture that allows the nucleation and directional alignment of self-assembling mesostructures to be controlled during synthesis is disclosed. The aligned mesostructured inorganic-organic materials and mesoporous inorganic or carbon materials can be prepared in the form of patterned films, monoliths, and fibers with controllable orientational ordering. Such materials possess anisotropic structural, mechanical, optical, reaction, or transport properties that can be exploited for numerous applications in opto-electronics, separations, fuel cells, catalysis, MEMS/microfluidics, for example.

    摘要翻译: 以图案化膜,整料和纤维的形式的中间结构的无机 - 有机材料可以通过宏观长度尺度以可控的取向顺序制备。 它们通过控制材料界面处的溶剂去除速率以及表面活性剂自组装速率和无机交联和表面相互作用而合成。 公开了一种用于控制从异质材料合成混合物中去除溶剂的速率和方向的方法,其允许在合成期间控制自组装介孔结构的成核和定向排列。 对准的介孔结构的无机 - 有机材料和介孔无机或碳材料可以以具有可控取向顺序的图案化膜,整料和纤维的形式制备。 这些材料具有各向异性的结构,机械,光学,反应或传输特性,可用于光电子,分离,燃料电池,催化,MEMS /微流体等众多应用。

    MESOSTRUCTURED MATERIALS WITH CONTROLLED ORIENTATIONAL ORDERING
    9.
    发明申请
    MESOSTRUCTURED MATERIALS WITH CONTROLLED ORIENTATIONAL ORDERING 审中-公开
    具有控制定向订购的结构材料

    公开(公告)号:US20090162616A1

    公开(公告)日:2009-06-25

    申请号:US12335225

    申请日:2008-12-15

    IPC分类号: B32B3/30 B32B5/02 B29C59/00

    摘要: Methods of controlling orientational ordering in self-assembled materials are described. These methods include controlling the nucleation rate and growth of block-copolymer-templated silica domains to yield macroscopically aligned mesostructured materials, and forming patterned mesostructured films or monoliths with control over the direction of alignment of a hexagonally-packed, block-copolymer-directed mesostructure across macroscopic lengths scales are described. Self-assembled materials with controlled orientational ordering are described, including those that contain a surfactant or block-copolymer species, and materials that include an organic (e.g., resin) or inorganic (e.g., silica or titania) network-forming component.

    摘要翻译: 描述了在自组装材料中控制取向排序的方法。 这些方法包括控制嵌段共聚物 - 模板二氧化硅域的成核速率和生长以产生宏观取向的介观结构材料,以及形成图案化的介孔结构化膜或整料,其对六边形填充的嵌段共聚物指向的介孔结构的取向方向进行控制 描述了宏观长度尺度。 描述了具有受控定向排列的自组装材料,包括含有表面活性剂或嵌段共聚物物质的材料,以及包括有机(例如树脂)或无机(例如二氧化硅或二氧化钛)网络形成组分的材料。

    Carbon materials with interconnected pores
    10.
    发明授权
    Carbon materials with interconnected pores 有权
    具有互连孔的碳材料

    公开(公告)号:US08563124B2

    公开(公告)日:2013-10-22

    申请号:US12367471

    申请日:2009-02-06

    IPC分类号: B32B3/26 B32B3/06

    摘要: Methods of forming an electrically-conductive mesoporous carbon structure with interconnected pores or highly interconnected pores, and the resulting structures are described. The structure is formed by providing a mesoporous template, filling the mesopores with an organic precursor, polymerizing the organic precursor, pyrolyzing the polymerized organic precursor, and etching away the template.

    摘要翻译: 描述形成具有互连孔或高度互连的孔的导电介孔碳结构的方法,以及所得结构。 通过提供介孔模板,用有机前体填充介孔,聚合有机前体,热解聚合的有机前体和蚀刻掉模板来形成结构。