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公开(公告)号：US5500199A
公开(公告)日：1996-03-19
申请号：US217072
申请日：1994-03-24
IPC分类号： C01B39/00 , C01B35/10 , C01B39/02 , C01B39/04 , C01B39/06 , C01B39/36 , C01B39/38 , C01B39/40 , C01B39/42 , C01B33/26 , B01J29/06
CPC分类号： C01B39/026 , C01B35/1009
摘要： Zeolites having a pore diameter comprised within the range of from 5 to 12 .ANG. are bonded with amorphous oligomeric silica, by dispersing them in an aqueous solution of silica and alkylammonium hydroxide, and submitting the obtained suspension to a quick drying.
摘要翻译： 通过将其分散在二氧化硅和烷基氢氧化铵的水溶液中，将具有5-12个电极范围的孔径的沸石与无定形低聚二氧化硅结合，并将所得悬浮液快速干燥。
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公开(公告)号：US4743573A
公开(公告)日：1988-05-10
申请号：US854527
申请日：1986-04-22
摘要： The present invention relates to a catalyst for the selective decomposition of cumene hydroperoxide, composed of zeolite crystals wherein a portion of the silicon atoms in the crystal lattice of silica is replaced by Al and B. The zeolite crystals are bonded to each other by a siliceous bonding agent which allows the catalyst to assume the shape of mechanically stable microspheres.The invention relates also to a process in which the catalyst is used, and to the related operating conditions.
摘要翻译： 本发明涉及用于选择性分解氢过氧化枯烯的催化剂，其由沸石晶体组成，其中二氧化硅晶格中的一部分硅原子被Al和B代替。沸石晶体通过硅质 粘合剂，其允许催化剂呈现机械稳定的微球的形状。 本发明还涉及使用催化剂和相关操作条件的方法。
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3.发明授权Catalyst for the selective decomposition of cumene hydroperoxide and process using it 失效用于选择性分解氢过氧化枯烯的催化剂及其使用方法
公开(公告)号：US4849387A
公开(公告)日：1989-07-18
申请号：US112462
申请日：1987-10-26
摘要： The present invention relates to a catalyst for the selective decomposition of cumene hydroperoxide, composed of zeolite crystals wherein a portion of the silicon atoms in the crystal lattice of silica is replaced by Al and B. The zeolite crystals are bonded to each other by a siliceous bonding agent which allows the catalyst to assume the shape of mechanically stable microspheres.The invention relates also to a process in which the catalyst is used, and to the related operating conditions.
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4.发明授权
公开(公告)号：US4954653A
公开(公告)日：1990-09-04
申请号：US362509
申请日：1989-06-07
申请人： Giuseppe Bellussi , Franco Buonomo , Antonio Esposito , Mario Clerici , Ugo Romano , Bruno Notari
发明人： Giuseppe Bellussi , Franco Buonomo , Antonio Esposito , Mario Clerici , Ugo Romano , Bruno Notari
IPC分类号： B01J29/89 , C07C37/60 , C07D301/12 , C07D303/04
CPC分类号： C07D303/04 , B01J29/89 , C07C37/60 , C07C41/26 , C07D301/12
摘要： The invention discloses a catalyst on the basis of silicon and titanium having the form of microspheres and constituted by oligomeric silica and by titanium-silica-lite crystals having an oligomeric silica/titanium-silicalite molar ratio comprised within the range of from 0.05 to 0.11, wherein the crystals of titanium-silicalite are encaged by means of Si-O-Si bridges.
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5.发明授权Catalyst of silicon and titanium having high mechanical strength and a process for its preparation. 失效具有高机械强度的硅和钛催化剂及其制备方法。
公开(公告)号：US4701428A
公开(公告)日：1987-10-20
申请号：US854890
申请日：1986-04-23
申请人： Giuseppe Bellussi , Franco Buonomo , Antonio Esposito , Mario Clerici , Ugo Romano , Bruno Notari
发明人： Giuseppe Bellussi , Franco Buonomo , Antonio Esposito , Mario Clerici , Ugo Romano , Bruno Notari
IPC分类号： B01J29/89 , C07C37/60 , C07D301/12 , C07D303/04 , B01J21/06 , B01J35/08
CPC分类号： C07D303/04 , B01J29/89 , C07C37/60 , C07C41/26 , C07D301/12
摘要： The invention discloses a catalyst on the basis of silicon and titanium having the form of microspheres and constituted by oligomeric silica and by titanium-silicalite crystals having an oligomeric silica/titanium-silicalite molar ratio comprised within the range of from 0.05 to 0.11, wherein the crystals of titanium-silicalite are encaged by means of Si-O-Si bridges.
摘要翻译： 本发明公开了一种基于硅和钛的催化剂，其具有微球的形式，由低聚二氧化硅和钛 - 硅沸石晶体组成，其中低硅石/钛 - 硅沸石摩尔比在0.05至0.11的范围内，其中 钛硅质岩的晶体通过Si-O-Si桥结合。
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6.发明授权
公开(公告)号：US4859785A
公开(公告)日：1989-08-22
申请号：US75688
申请日：1987-07-20
申请人： Giuseppe Bellussi , Franco Buonomo , Antonio Esposito , Mario Clerici , Ugo Romano , Bruno Notari
发明人： Giuseppe Bellussi , Franco Buonomo , Antonio Esposito , Mario Clerici , Ugo Romano , Bruno Notari
IPC分类号： B01J29/89 , C07C37/60 , C07D301/12 , C07D303/04
CPC分类号： C07D303/04 , B01J29/89 , C07C37/60 , C07C41/26 , C07D301/12
摘要： The invention discloses a catalyst on the basis of silicon and titanium having the form of microspheres and constituted by oligomeric silica and by titanium-silicalite crystals having an oligomeric silica/titanium-silicalite molar ratio comprised within the range of from 0.05 to 0.11, wherein the crystals of titanium-silicalite are encaged by means of Si--O--Si bridges.
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7.发明授权Method for production of a coated substrate with controlled surface characteristics 失效具有受控表面特性的涂覆基材的生产方法
公开(公告)号：US5290533A
公开(公告)日：1994-03-01
申请号：US750240
申请日：1991-08-16
IPC分类号： B01J29/89 , C01B37/00 , C07D301/12 , C07D303/04 , C01B33/34
CPC分类号： C07D303/04 , B01J29/89 , C01B37/005 , C07D301/12 , Y10S423/22
摘要： A crystalline, porous, synthetic material is disclosed, together with its related preparation process.Such a material of zeolitic character, containing silicon, titanium and iron oxides, corresponds, in its calcined and anhydrous state, to the following empi rical formulapHFeO.sub.2.qTiO.sub.2.SiO.sub.2wherein p has a value greater than zero and lower than or equal to 0.050, q has a value greater than zero and lower than or equal to 0.025, and the H.sup.+ of HFeO.sub.2 can be at least partly replaceable or replaced by cations.
摘要翻译： 公开了一种结晶多孔合成材料及其相关的制备方法。 这种具有硅，钛和氧化铁的沸石特性的材料在其煅烧和无水状态下对应于以下公式：pHFeO2.qTiO2.SiO2，其中p具有大于零且小于或等于0.050的值 ，q具有大于零且小于或等于0.025的值，并且HFeO 2的H +可以至少部分替代或被阳离子替代。
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8.发明授权Process for the preparation of 4,4'-diaminodiphenyl-methane and its derivatives 失效4,4'-二氨基二苯基甲烷及其衍生物的制备方法
公开(公告)号：US5241119A
公开(公告)日：1993-08-31
申请号：US595665
申请日：1990-10-11
申请人： Mario G. Clerici , Giuseppe Bellussi , Ugo Romano
发明人： Mario G. Clerici , Giuseppe Bellussi , Ugo Romano
IPC分类号： B01J29/04
CPC分类号： B01J29/04 , Y02P20/582
摘要： Process for the preparation of 4,4'-diaminodiphenylmethane and its derivatives.4,4'-diaminodiphenylmethane and its derivatives are prepared by the condensation of aniline, or its derivative, and aldehyde, or its precursor and/or isomerization of appropriate intermediate products. The reaction proceeds with zeolites acting as catalysts; these catalysts, which are selected in accordance with the reaction to be effected, are preferably zeolites based on Si, Al and B; Si, Al and Ti; Ti and Fe; ZSM-5; or Y zeolites.
摘要翻译： 制备4,4'-二氨基二苯甲烷及其衍生物的方法。 4,4'-二氨基二苯基甲烷及其衍生物通过苯胺或其衍生物与醛或其前体的缩合和/或合适的中间产物的异构化来制备。 反应进行作为催化剂的沸石; 根据要进行的反应选择的这些催化剂优选基于Si，Al和B的沸石; Si，Al和Ti; Ti和Fe; ZSM-5; 或Y沸石。
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9.发明授权Synthetic, crystalline, porous material containing silicon oxide, titanium oxide and aluminum oxide 失效含有氧化硅，氧化钛和氧化铝的合成，结晶多孔材料
公开(公告)号：US5246690A
公开(公告)日：1993-09-21
申请号：US740860
申请日：1991-07-31
CPC分类号： B01J29/89 , C01B37/005 , C07C1/20 , C07C37/60 , C07C2529/89 , Y10S423/22
摘要： A crystalline, porous, synthetic material is disclosed, together with its related preparation process.Such a material of zeolitic character, containing silicon, titanium and aluminum oxides, corresponds, in its calcined and anhydrous state, to the following empirical formula:p HAlO.sub.2.q TiO.sub.2.SiO.sub.2wherein p has a value greater than zero and lower than or equal to 0.050, q has a value greater than zero and lower than or equal to 0.025, and the H.sup.+ of HAlO.sub.2 can be at least partly replaceable or replaced by cations.
摘要翻译： 公开了一种结晶多孔合成材料及其相关的制备方法。 这种沸石特性的材料，含硅，钛和氧化铝，其煅烧和无水状态对应于以下经验式：p HA102.q TiO2.SiO2，其中p的值大于零且小于或等于 至0.050，q具有大于零且小于或等于0.025的值，并且HA10的H +可以至少部分替代或被阳离子取代。
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公开(公告)号：US5578744A
公开(公告)日：1996-11-26
申请号：US444414
申请日：1995-05-19
IPC分类号： B01J21/08 , B01J23/08 , B01J23/14 , B01J23/22 , B01J27/18 , B01J37/00 , B01J37/03 , C01B33/16 , C07B33/00 , C07B37/02 , C07B61/00 , C07C2/10 , C07C2/58 , C07C2/66 , C07C11/02 , C07C15/02 , C07C37/60 , C07C249/04 , C07C251/44 , C07D301/19 , C07D303/04 , C07D303/14 , C07C2/00 , C07C2/12
CPC分类号： C07D301/19 , B01J21/08 , B01J37/033 , C07C2/10 , C07C2/66 , C07C249/04 , C07C37/60 , C07D303/04 , C07D303/14 , C07C2521/08 , C07C2523/08 , C07C2523/745
摘要： A catalytically active gel is described consisting of a silica matrix with uniform porosity, monomodal pore distribution and high surface area, within which one or metal oxides possessing catalytic activity are dispersed. A process for preparing this catalytic gel is also described.
摘要翻译： 描述了一种催化活性凝胶，其由具有均匀孔隙率，单峰孔分布和高表面积的二氧化硅基质组成，其中分散有一种或具有催化活性的金属氧化物。 还描述了制备该催化凝胶的方法。
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