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    Transparent conductive ceramic-coated substrate processes for preparing same and uses thereof
    1.
    发明授权
    Transparent conductive ceramic-coated substrate processes for preparing same and uses thereof 失效
    透明导电陶瓷涂布基板的制备方法及其用途

    公开(公告)号：US5013607A

    公开(公告)日：1991-05-07

    申请号：US391604

    申请日：1989-06-08

    申请人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Noboru Senjyuu

    发明人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Noboru Senjyuu

    IPC分类号： C03C17/25 ,  C09D5/24

    CPC分类号： C03C17/25 ,  C09D5/24 ,  C03C2217/23 ,  C03C2218/11 ,  C03C2218/113 ,  Y10T428/31612 ,  Y10T428/31663

    摘要： Disclosed are transparent conductive ceramiccoated substrates having a surface resistance of 10.sup.3 -10.sup.11 .OMEGA./.quadrature., a total light transmission of at least 85% and a haze of less than 10%, said coated substrates being prepared by coating on the substrate a water organic solvent mixture type coating liquid containing dialkoxy-bisacetylacetonato zirconium, a partial hydrolysate of silicon alkoxide and a conductive substance, processes for preparing said coated substrates, and display and copy machine using said coated substrates.

    摘要翻译： PCT No.PCT / JP88 / 00793 Sec。 371日期：1989年6月8日 102（e）日期1989年6月8日PCT PCT 1988年8月10日PCT公布。 公开号WO89 / 03114 日期为1989年4月6日。公开的是透明导电陶瓷涂层基材，其表面电阻为103-1011欧米茄/平方厘米，总透光率至少为85％，雾度小于10％，所述涂覆的基材通过涂布 在基材上，含有二烷氧基 - 双乙酰丙酮酸锆的部分水解有机溶剂混合物型涂料液，硅氧烷和导电物质的部分水解产物，制备所述涂覆的基材的方法，以及使用所述涂覆的基材的显示和复印机。

    Coating liquids for forming conductive coatings
    2.
    发明授权
    Coating liquids for forming conductive coatings 失效
    涂层液形成导电涂料

    公开(公告)号：US5078915A

    公开(公告)日：1992-01-07

    申请号：US298607

    申请日：1988-10-11

    申请人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Keiichi Mihara

    发明人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Keiichi Mihara

    IPC分类号： B32B15/00 ,  C03C17/23 ,  C03C17/25

    CPC分类号： C03C17/25 ,  C03C17/23 ,  C03C2217/23 ,  C03C2218/11

    摘要： In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrates, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face-plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.

    摘要翻译： PCT No.PCT / JP88 / 00122 Sec。 371日期：1988年10月11日 102（e）日期1988年10月11日PCT提交1988年2月9日PCT公布。 公开号WO88 / 06331 日本1988年8月25日。根据本发明，提供了用于形成导电涂层的涂料液体，其包含（i）锆氧基钾，（ii）导电物质，如果需要，（iii）至少一种 成员选自非沉积二氧化硅分散体和硅烷醇盐或其衍生物。 涂布液在基材上涂布时，在其上形成透明性，耐擦伤性，耐久性和对基材的粘合性优异的抗静电效果的透明导电性涂料。 特别地，当将用于形成上述导电涂层的涂布液通过喷涂方法涂覆在适当的基材上，然后进行干燥和/或加热时，获得具有优异的正常反射减少效果的显示装置用面板， 眩光）和抗静电效果。

    Coating liquids for forming conductive coatings
    3.
    发明授权
    Coating liquids for forming conductive coatings 失效
    用于形成导电涂层的涂料液体

    公开(公告)号：US5270072A

    公开(公告)日：1993-12-14

    申请号：US746403

    申请日：1991-08-16

    申请人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Keiichi Mihara

    发明人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Keiichi Mihara

    IPC分类号： C03C17/23 ,  C03C17/25 ,  B05D5/12

    CPC分类号： C03C17/25 ,  C03C17/23 ,  C03C2217/23 ,  C03C2218/11

    摘要： In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrates, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.

    摘要翻译： 根据本发明，提供了用于形成导电涂层的涂布液，其包括（i）锆氧化锡，（ii）导电物质，如果需要，（iii）至少一种选自非沉积二氧化硅 分散体和烷氧基硅烷或其衍生物。 涂布液在基材上涂布时，在其上形成透明性，耐擦伤性，耐久性和对基材的粘合性优异的抗静电效果的透明导电性涂料。 特别地，当用上述形成导电涂层的涂布液通过喷涂方法在适当的基材上进行干燥和/或加热涂覆时，得到具有优异的均匀反射减少效果（非眩光）的显示装置用面板 ）和抗静电效果。

    Coating liquids for forming conductive coatings
    4.
    发明授权
    Coating liquids for forming conductive coatings 失效
    用于形成导电涂层的涂料液体

    公开(公告)号：US5273828A

    公开(公告)日：1993-12-28

    申请号：US746402

    申请日：1991-08-16

    申请人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Keiichi Mihara

    发明人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Keiichi Mihara

    IPC分类号： B32B15/00 ,  C03C17/23 ,  C03C17/25

    CPC分类号： C03C17/25 ,  C03C17/23 ,  C03C2217/23 ,  C03C2218/11

    摘要： In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrates, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face-plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.

    摘要翻译： 根据本发明，提供了用于形成导电涂层的涂布液，其包括（i）锆氧化锡，（ii）导电物质，如果需要，（iii）至少一种选自非沉积二氧化硅 分散体和烷氧基硅烷或其衍生物。 涂布液在基材上涂布时，在其上形成透明性，耐擦伤性，耐久性和对基材的粘合性优异的抗静电效果的透明导电性涂料。 特别地，当将用于形成上述导电涂层的涂布液通过喷涂方法涂覆在适当的基材上，然后进行干燥和/或加热时，获得具有优异的正常反射减少效果的显示装置用面板， 眩光）和抗静电效果。

    Substrate having a transparent coating thereon
    5.
    发明授权
    Substrate having a transparent coating thereon 失效
    基材在其上具有透明涂层

    公开(公告)号：US5256484A

    公开(公告)日：1993-10-26

    申请号：US746406

    申请日：1991-08-16

    申请人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Keiichi Mihara

    发明人： Goro Sato ,  Michio Komatsu ,  Toshiharu Hirai ,  Yoneji Abe ,  Keiichi Mihara

    IPC分类号： C03C17/23 ,  C03C17/25 ,  B32B17/06

    CPC分类号： C03C17/23 ,  C03C17/25 ,  C03C2217/23 ,  C03C2218/11 ,  Y10T428/31598 ,  Y10T428/31609

    摘要： In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrate, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face-plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.

    摘要翻译： 根据本发明，提供了用于形成导电涂层的涂布液，其包括（i）锆氧化锡，（ii）导电物质，如果需要，（iii）至少一种选自非沉积二氧化硅 分散体和烷氧基硅烷或其衍生物。 涂布液在基材上涂布时，在透明性，耐刮擦性，耐久性和对基材的粘附性上具有优异的抗静电效果的透明导电性涂料。 特别地，当将用于形成上述导电涂层的涂布液通过喷涂方法涂覆在适当的基材上，然后进行干燥和/或加热时，获得具有优异的正常反射减少效果的显示装置用面板， 眩光）和抗静电效果。

    Conductive substrate and display device provided with transparent conductive substrate
    7.
    发明授权
    Conductive substrate and display device provided with transparent conductive substrate 失效
    具有透明导电性基板的导电性基板和显示装置

    公开(公告)号：US5492762A

    公开(公告)日：1996-02-20

    申请号：US315223

    申请日：1994-09-29

    申请人： Toshiharu Hirai ,  Michio Komatsu ,  Akira Nakashima ,  Yoneji Abe ,  Yukihiro Iwasaki

    发明人： Toshiharu Hirai ,  Michio Komatsu ,  Akira Nakashima ,  Yoneji Abe ,  Yukihiro Iwasaki

    IPC分类号： B05D3/02 ,  B05D3/04 ,  B05D3/06 ,  C03C17/00 ,  C09D5/24 ,  G02F1/1343 ,  H01B1/20 ,  H01B1/22 ,  H01B1/24 ,  H05K1/09 ,  B32B9/04 ,  B32B17/00

    CPC分类号： H01B1/24 ,  B05D3/046 ,  B05D3/067 ,  C03C17/007 ,  C03C17/009 ,  C09D5/24 ,  H01B1/20 ,  H01B1/22 ,  B05D3/0254 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/476 ,  G02F1/13439 ,  H05K1/095 ,  Y10T428/31612 ,  Y10T428/31663

    摘要： Conductive substrate having on their surface a coating formed from a coating solution for forming a transparent conductive coating prepared by dispersion of dissolving in water and/or organic solvent such conductive particles as having (a) an average particle diameter of not more than 500 .ANG., wherein (b) an amount of particles having a particle diameter of not more than 600 .ANG. is more than 60% by weight, (c) an amount of particles having a particle diameter of not more than 100 .ANG. is more than 5% by weight and (d) an amount of particles having a particle diameter of more than 1000 .ANG. is not more than 15% by weight, and a matrix comprising a silica polymer having (A) an average degree of polymerization of 1,500-10,000, and (B) an amount of the polymer having a degree of polymerization of not more than 3,000 being not more than 50% by weight, and (C) an amount of the polymer having a degree of polymerization of more than 10,000 being not more than 20% by weight, are excellent in adhesion and surface smoothness and also excellent in durability and transparency. Display devices provided with the above-mentioned transparent conductive substrates as the display panel are excellent in resolving power, and give constantly clear and sharp images.

    摘要翻译： 导电基材在其表面上具有由用于形成透明导电涂层的涂布溶液形成的涂层，该透明​​导电涂层通过溶解在水和/或有机溶剂中而形成，例如（a）平均粒径不大于500的导电颗粒， 其中（b）粒径不大于600的颗粒的量大于60wt％，（c）粒径不大于100的颗粒的量大于5wt％ 和（d）粒径大于1000的颗粒的量不超过15重量％，包含（A）平均聚合度为1,500〜10,000的二氧化硅聚合物的基体和（B ）聚合度不大于3,000的聚合物的量不超过50重量％，（C）聚合度大于10,000的聚合物的量不超过20％，其量 重量， 粘合性和表面平滑性优异，耐久性和透明性也优异。 设置有作为显示面板的上述透明导电基板的显示装置具有优异的分辨率，并且给出不断清晰和清晰的图像。

    Coating solution for forming transparent conductive coating and process for preparing same
    9.
    发明授权
    Coating solution for forming transparent conductive coating and process for preparing same 失效
    用于形成透明导电涂层的涂布溶液及其制备方法

    公开(公告)号：US5376308A

    公开(公告)日：1994-12-27

    申请号：US910300

    申请日：1992-07-20

    申请人： Toshiharu Hirai ,  Michio Komatsu ,  Akira Nakashima ,  Yoneji Abe ,  Yukihiro Iwasaki

    发明人： Toshiharu Hirai ,  Michio Komatsu ,  Akira Nakashima ,  Yoneji Abe ,  Yukihiro Iwasaki

    IPC分类号： B05D3/02 ,  B05D3/04 ,  B05D3/06 ,  C03C17/00 ,  C09D5/24 ,  G02F1/1343 ,  H01B1/20 ,  H01B1/22 ,  H01B1/24 ,  H05K1/09 ,  H01B1/02 ,  C08K3/20 ,  H01B1/06

    CPC分类号： H01B1/24 ,  B05D3/046 ,  B05D3/067 ,  C03C17/007 ,  C03C17/009 ,  C09D5/24 ,  H01B1/20 ,  H01B1/22 ,  B05D3/0254 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/476 ,  G02F1/13439 ,  H05K1/095 ,  Y10T428/31612 ,  Y10T428/31663

    摘要： Conductive substrate having on their surface a coating formed from a coating solution for forming a transparent conductive coating prepared by dispersion of dissolving in water and/or organic solvent such conductive particles as having (a) an average particle diameter of not more than 500 .ANG., wherein (b) an amount of particles having a particle diameter of not more than 600 .ANG. is more than 60% by weight, (c) an amount of particles having a particle diameter of not more than 100 .ANG. is more than 5% by weight and (d) an amount of particles having a particle diameter of more than 1000 .ANG. is not more than 15% by weight, and a matrix comprising a silica polymer having (A) an average degree of polymerization of 1,500-10,000, and (B) an amount of the polymer having a degree of polymerization of not more than 3,000 being not more than 50% by weight, and (C) an amount of the polymer having a degree of polymerization of more than 10,000 being not more than 20% by weight, are excellent in adhesion and surface smoothness and also excellent in durability and transparency. Display devices provided with the above-mentioned transparent conductive substrates as the display panel are excellent in resolving power, and give constantly clear and sharp images.

    摘要翻译： PCT No.PCT / JP91 / 01603 Sec。 371日期：1992年7月20日 102（e）日期1992年7月20日PCT 1991年11月21日PCT PCT。 出版物WO92 / 09665 日期：1992年6月11日。导电基材在其表面上具有由用于形成透明导电涂层的涂布液形成的涂层，所述涂料溶液通过将溶解在水和/或有机溶剂中的分散体制备，所述导电颗粒具有（a）平均粒径 不超过500，其中（b）粒径不大于600的颗粒的量大于60wt％，（c）粒径不大于100的颗粒数量ANGSTROM 大于5重量％，（d）粒径大于1000的颗粒的量不超过15重量％，并且包含二氧化硅聚合物的基质，其具有（A）平均聚合度 （B）聚合度不大于3,000的聚合物的量不大于50重量％，（C）聚合度大于10,000的聚合物的量 不是更多的t 韩20重量％，粘合性和表面平滑性优异，耐久性和透明性优异。 设置有作为显示面板的上述透明导电基板的显示装置具有优异的分辨率，并且给出不断清晰和清晰的图像。