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公开(公告)号：US20080167484A1
公开(公告)日：2008-07-10
申请号：US11994129
申请日：2006-06-20
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The present invention relates to a process for producing propylene oxide comprising (I) reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (GI) comprising propylene oxide, unreacted propene, and oxygen; (II) separating propylene oxide from mixture (GI) to give a mixture (GII) comprising propene and oxygen; (III) reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising Sn and at least one noble metal.
摘要翻译： 本发明涉及一种生产环氧丙烷的方法，其包括（I）在催化剂存在下使丙烯与过氧化氢反应，得到包含环氧丙烷，未反应的丙烯和氧的混合物（GI） （II）将环氧丙烷与混合物（GI）分离，得到包含丙烯和氧的混合物（GII）; （III）在包含Sn和至少一种贵金属的催化剂的存在下至少部分地通过与氢反应来还原混合物（GII）中包含的氧。
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公开(公告)号：US20070004926A1
公开(公告)日：2007-01-04
申请号：US11168454
申请日：2005-06-29
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The present invention relates to a process for producing propylene oxide comprising (I) reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (GI) comprising propylene oxide, unreacted propene, and oxygen; (II) separating propylene oxide from mixture (GI) to give a mixture (GII) comprising propene and oxygen; (III) reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising Sn and at least one noble metal.
摘要翻译： 本发明涉及一种生产环氧丙烷的方法，其包括（I）在催化剂存在下使丙烯与过氧化氢反应，得到包含环氧丙烷，未反应的丙烯和氧的混合物（GI） （II）将环氧丙烷与混合物（GI）分离，得到包含丙烯和氧的混合物（GII）; （III）在包含Sn和至少一种贵金属的催化剂的存在下至少部分地通过与氢反应来还原混合物（GII）中包含的氧。
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3.发明申请公开(公告)号：US20080262281A1
公开(公告)日：2008-10-23
申请号：US11547500
申请日：2005-03-22
CPC分类号： B01J23/626 , B01J21/04 , B01J35/1009 , B01J35/1014 , B01J37/0009 , C07C5/3337 , C07C2523/60 , C07C15/46
摘要： A catalyst for the oxidation of hydrogen in a process for the dehydrogenation of hydrocarbons, wherein the catalyst comprises, supported on α-aluminum oxide, from 0.01 to 0.1% by weight of platinum and from 0.01 to 0.1% by weight of tin, based on the total weight of the catalyst, a process for the oxidation of hydrogen and a process for the dehydrogenation of hydrocarbons with an integrated oxidation process using the catalyst described.
摘要翻译： 一种在烃脱氢方法中氧化氢气的催化剂，其中催化剂包含负载在α-氧化铝上的0.01至0.1重量％的铂和0.01至0.1重量％的锡，基于 催化剂的总重量，氢氧化的方法和使用所述催化剂的使用一体化氧化方法使烃脱氢的方法。
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公开(公告)号：US20070032681A1
公开(公告)日：2007-02-08
申请号：US10565730
申请日：2004-07-22
IPC分类号： C07C45/72
CPC分类号： C07C45/65 , B01J23/626 , B01J23/96 , B01J38/14 , Y02P20/584 , C07C49/597
摘要： Process for preparing alpha, beta-unsaturated acyclic or cyclic carbonyl compounds by dehydrogenation of the corresponding saturated carbonyl compounds in the gas phase over a heterogeneous dehydrogenation catalyst comprising platinum and/or palladium and tin on an oxidic support.
摘要翻译： 通过相对于气相中的饱和羰基化合物在氧化载体上包含铂和/或钯和锡的异相脱氢催化剂脱氢来制备α，β-不饱和非环或环状羰基化合物的方法。
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公开(公告)号：US20050124837A1
公开(公告)日：2005-06-09
申请号：US10501878
申请日：2003-01-20
申请人： Christian Walsdorff , Michael Baier , Klaus Harth , Susanne Weber , Wilhelm Ruppel , Gotz-Peter Schindler
发明人： Christian Walsdorff , Michael Baier , Klaus Harth , Susanne Weber , Wilhelm Ruppel , Gotz-Peter Schindler
IPC分类号： C07B35/04 , C07C2/68 , C07C5/333 , C07C15/46 , C07D233/04
CPC分类号： C07C5/3332 , B01J23/83 , B01J37/0009 , B01J2523/00 , C07C2523/02 , C07C2523/10 , C07C2523/28 , C07C2523/745 , C07C15/46 , C07C15/52 , C07C15/44 , B01J2523/13 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/842
摘要： A process for preparing alkenylaromatic compounds by reacting alkylaromatic compounds in the presence of steam and natural gas or methane over a suitable catalyst at a temperature of from 400 to 800° C. and a pressure of from 0.01 to 10 bar, wherein the molar ratio of steam to alkylaromatic compound is from 6.9:1 to 1:1 or the molar ratio of methane to alkylaromatic compound is from 0.1:1 to 8:1.
摘要翻译： 在蒸气和天然气或甲烷的存在下，在合适的催化剂上，在400-800℃的温度和0.01至10巴的压力下使烷基芳族化合物反应制备链烯基芳族化合物的方法，其中摩尔比 蒸汽至烷基芳族化合物的摩尔比为6.9:1至1:1，或甲烷与烷基芳族化合物的摩尔比为0.1:1至8:1。
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公开(公告)号：US20070244349A1
公开(公告)日：2007-10-18
申请号：US11718814
申请日：2005-11-11
IPC分类号： C07C5/333 , C07C11/167
CPC分类号： C07C7/09 , C07C5/333 , C07C11/167
摘要： Processes for producing butadiene from n-butane comprising: (a) providing a feed gas stream comprising n-butane; (b) non-oxidatively dehydrogenating the feed gas stream in the presence of a catalyst in a first dehydrogenation zone to form a first intermediate gas stream comprising n-butane, 1-butene, 2-butene, butadiene and hydrogen; (c) oxidatively dehydrogenating the first intermediate gas stream in the presence of an oxygenous gas having an oxygen content of at least 75% by volume in a second dehydrogenation zone to form a second intermediate gas stream comprising n-butane, butadiene, hydrogen, carbon dioxide and steam; (d) compressing and cooling the second intermediate gas to form a first condensate stream comprising water and a third intermediate gas stream comprising n-butane, butadiene, hydrogen, carbon dioxide and steam; (e) compressing and cooling the third intermediate gas to form a second condensate stream comprising n-butane, butadiene and water and a fourth intermediate gas stream comprising n-butane, butadiene, hydrogen and carbon dioxide; (f) cooling the fourth intermediate gas stream to form a third condensate stream comprising n-butane and butadiene, and an offgas stream comprising carbon dioxide and hydrogen; (g) removing water from the second condensate stream and combining the second condensate stream and third condensate stream to form a C4 hydrocarbon stream comprising n-butane and butadiene; and (h) separating the C4 hydrocarbon stream to form a recycle stream comprising n-butane and a product stream comprising butadiene; wherein at least a portion of the recycle stream is fed to the first dehydrogenation zone.
摘要翻译： 用于从正丁烷生产丁二烯的方法包括：（a）提供包含正丁烷的进料气流; （b）在催化剂存在下在第一脱氢区中使进料气流非氧化脱氢，以形成包含正丁烷，1-丁烯，2-丁烯，丁二烯和氢的第一中间气流; （c）在第二脱氢区中在氧含量至少为75体积％的氧气存在下，使第一中间气流氧化脱氢以形成包含正丁烷，丁二烯，氢，碳的第二中间气流 二氧化碳和蒸汽; （d）压缩和冷却第二中间气体以形成包含水的第一冷凝物流和包含正丁烷，丁二烯，氢气，二氧化碳和蒸汽的第三中间气流; （e）压缩和冷却第三中间气体以形成包含正丁烷，丁二烯和水的第二冷凝物流和包含正丁烷，丁二烯，氢气和二氧化碳的第四中间气流; （f）冷却第四中间气流以形成包含正丁烷和丁二烯的第三冷凝物流和包含二氧化碳和氢气的废气流; （g）从第二冷凝物流中除去水并将第二冷凝物流和第三冷凝物流合并以形成包含正丁烷和丁二烯的C 4烃流; 和（h）分离C 4 O 4烃流以形成包含正丁烷和包含丁二烯的产物流的再循环料流; 其中所述再循环流的至少一部分被供给到所述第一脱氢区。
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7.发明申请Modified method for producing surfactant alcohols and surfactant alcohol ethers, the products of said method and use of the same 审中-公开用于生产表面活性剂醇和表面活性剂醇醚的改性方法，所述方法的用途和使用方法相同公开(公告)号：US20050107628A1
公开(公告)日：2005-05-19
申请号：US10503213
申请日：2003-02-19
申请人： Michael Roper , Jurgen Stephan , Gotz-Peter Schindler , Jurgen Tropsch , Thomas Heidemann , Martina Prinz , Soeren Zimdahl
发明人： Michael Roper , Jurgen Stephan , Gotz-Peter Schindler , Jurgen Tropsch , Thomas Heidemann , Martina Prinz , Soeren Zimdahl
IPC分类号： C07B61/00 , C07C2/00 , C07C2/06 , C07C2/10 , C07C6/04 , C07C11/02 , C07C11/107 , C07C29/141 , C07C29/16 , C07C31/125 , C07C41/03 , C07C45/50 , C07C47/21 , C07C9/00 , C07C27/12 , C07F9/02 , C07H13/02
CPC分类号： C07C29/141 , C07C2/06 , C07C6/04 , C07C29/16 , C07C45/50 , C07C31/125 , C07C47/02
摘要： A process for preparing surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having about 10 to 20 carbon atoms or of mixtures of such olefins and optional subsequent alkoxylation is described. As features, the process involves (a) subjecting a C4-olefin mixture with a 1-butene/2-butene ratio of ≧1.2 to a metathesis, (b) separating off olefins having 5 to 8 carbon atoms from the metathesis mixture, (c) subjecting the separated-off olefins individually or in a mixture to a dimerization to give olefin mixtures having 10 to 16 carbon atoms, (d) subjecting the resulting olefin mixture, optionally after a fractionation, to derivatization to give a mixture of surfactant alcohols and (e) optionally alkoxylating the surfactant alcohols. The olefin mixture obtained in the dimerization comprises a high content of branched components and less than 10% by weight of compounds which contain a vinylidene group. Also described is the use of surfactant alcohols and surfactant alcohol ethers to give surfactans by glycosidation or polyglycosidation, sulfation or phosphation.
摘要翻译： 描述了通过衍生具有约10至20个碳原子的烯烃或这种烯烃的混合物和任选的随后的烷氧基化来制备表面活性剂醇和表面活性剂醇醚的方法。 作为特征，该方法包括（a）使具有> = 1.2的1-丁烯/ 2-丁烯比的C 4 - 4 - 烯烃混合物复分解，（b）将具有5至 （c）将单独或混合物中的分离的烯烃进行二聚，得到具有10至16个碳原子的烯烃混合物，（d）任选地在分馏之后对所得烯烃混合物进行处理， 衍生化得到表面活性剂醇的混合物和（e）任选地使表面活性剂醇烷氧基化。 在二聚中获得的烯烃混合物包含高含量的支链组分和小于10重量％的含有亚乙烯基的化合物。 还描述了表面活性剂醇和表面活性剂醇醚通过糖基化或多糖苷化，硫酸化或磷酸化来提供表面活性剂的用途。
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8.发明申请公开(公告)号：US20080188695A1
公开(公告)日：2008-08-07
申请号：US12025448
申请日：2008-02-04
CPC分类号： B01J23/96 , B01J38/20 , C07C5/48 , C07C51/252 , C07C2521/06 , C07C2521/08 , C07C2523/04 , C07C2523/63 , Y02P20/52 , Y02P20/584 , C07C11/06 , C07C57/04
摘要： A process for regenerating a catalyst bed deactivated in the course of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon, in which a gas comprising molecular oxygen is conducted at elevated temperature through the deactivated catalyst bed and, in the course of the regeneration, the content of molecular oxygen in the regeneration gas is increased repeatedly and the increase in the carbon oxide content of the regeneration gas as it flows through the deactivated catalyst bed is restricted to values of ≦5% by volume.
摘要翻译： 在烃的非均相催化部分脱氢过程中使催化剂床再生失活的方法，其中包含分子氧的气体在高温下通过失活的催化剂床进行，并且在再生过程中， 再生气体中的分子氧反复增加，并且再生气体在流过失活催化剂床时的碳氧化物含量的增加被限制为<= 5体积％的值。
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公开(公告)号：US20080207975A1
公开(公告)日：2008-08-28
申请号：US11722367
申请日：2005-12-20
IPC分类号： C07C5/00
CPC分类号： C07C5/3337 , C07C7/04 , C07C11/06
摘要： The invention relates to a process for preparing propene from propane, comprising the steps:A) a feed gas stream a comprising propane is provided;B) the feed gas stream a comprising propane and an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a nonoxidative catalytic, autothermal dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide, steam and hydrogen;C) product gas stream b is cooled and steam is removed by condensation to obtain a steam-depleted product gas stream c;D) uncondensable or low-boiling gas constituents are removed by contacting product gas stream c with an inert absorbent and subsequently desorbing the gases dissolved in the inert absorbent to obtain a C3 hydrocarbon stream d1 and an offgas stream d2 comprising methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide and hydrogen;E) the C3 hydrocarbon stream d1 is cooled and compressed to obtain a liquid C3 hydrocarbon stream e1;F) the liquid C3− hydrocarbon stream e1 is fed into a first distillation zone and separated distillatively into a stream f1 composed of propane and propene and a stream f2 comprising ethane and ethene;G) stream f1 is fed into a (second) distillation zone and separated distillatively into a product stream g1 composed of propene and a stream g2 composed of propane, and stream g2 is recycled at least partly into the dehydrogenation zone.
摘要翻译： 本发明涉及一种从丙烷制备丙烯的方法，包括以下步骤：A）提供包含丙烷的原料气流a; B）将包含丙烷和含氧气流的原料气流a进料到脱氢区，丙烷经受非氧化催化，自热脱氢至丙烯以获得包含丙烷，丙烯，甲烷，乙烷，乙烯的产物气流b ，氮气，一氧化碳，二氧化碳，蒸气和氢气; C）产物气流b被冷却并通过冷凝除去蒸汽，得到蒸汽消耗产物气流c; D）通过使产物气流c与惰性吸收剂接触并随后将溶解在惰性吸收剂中的气体解吸，得到C 3 N 3烃流d 1和废气，除去不可冷凝或低沸点气体成分 流d 2包含甲烷，乙烷，乙烯，氮气，一氧化碳，二氧化碳和氢气; E）将C 3 C 3烃流d 1冷却并压缩，得到液体C 3烃流e1; F）将液体C 3 - C 3 - 烃流e 1进料到第一蒸馏区并蒸馏分离成由丙烷和丙烯组成的料流f 1和包含乙烷和乙烯的料流f 2; G）流f 1进料到（第二）蒸馏区并蒸馏分离成由丙烯构成的产物流g 1和由丙烷组成的料流g 2，并且流g 2至少部分地再循环到脱氢区中。
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公开(公告)号：US20080097133A1
公开(公告)日：2008-04-24
申请号：US11721240
申请日：2005-12-07
IPC分类号： C07C5/333
CPC分类号： C07C11/167 , C07C5/48
摘要： A process for preparing butadiene from n-butane, comprising the steps of A) providing a feed gas stream a comprising n-butane; B) feeding the feed gas stream a comprising n-butane into at least one first dehydrogenation zone and nonoxidatively, catalytically dehydrogenating n-butane to obtain a gas stream b comprising n-butane, 1-butene, 2-butene, butadiene and hydrogen, with or without carbon dioxide and with or without steam; C) feeding the gas stream b and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to obtain a gas stream c comprising n-butane, butadiene, hydrogen, carbon dioxide and steam, D) compressing in at least one first compression stage and cooling the gas stream c to obtain at least one condensate stream d1 comprising water and a gas stream d2 comprising n-butane, butadiene, hydrogen, carbon dioxide and steam, E) separating the gas stream d2 by extractive distillation into a product stream e1 consisting substantially of butadiene and a stream e2 comprising n-butane, hydrogen, carbon dioxide and steam, F) compressing in at least one further compression stage and cooling the gas stream e2 to obtain at least one condensate stream f1 comprising n-butane and water, and a gas stream f2 comprising n-butane, hydrogen and carbon dioxide, G) cooling the gas stream f2 to obtain a condensate stream g1 comprising n-butane and an offgas stream g2 comprising carbon dioxide and hydrogen, H) removing water from the at least one condensate stream f1 and, if appropriate, from the condensate stream g1 by phase separation to obtain at least one recycle stream hi comprising n-butane and at least one wastewater stream h2, and recycling the at least one recycle stream h1 into the first dehydrogenation zone.
摘要翻译： 一种从正丁烷制备丁二烯的方法，包括以下步骤：A）提供包含正丁烷的进料气流a; B）将包含正丁烷的进料气流a进料到至少一个第一脱氢区和非氧化催化脱氢的正丁烷中，以获得包含正丁烷，1-丁烯，2-丁烯，丁二烯和氢的气流b， 有或没有二氧化碳，有或没有蒸汽; C）将气流b和氧气送入至少一个第二脱氢区并使1-丁烯和2-丁烯氧化脱氢得到包含正丁烷，丁二烯，氢气，二氧化碳和蒸汽的气流c，D） 在至少一个第一压缩级中压缩并冷却气流c以获得至少一个包含水的冷凝物流d 1和包含正丁烷，丁二烯，氢气，二氧化碳和蒸汽的气流d 2，E）将气体分离 流d 2通过萃取蒸馏成基本上由丁二烯组成的产物流e 1和包含正丁烷，氢气，二氧化碳和蒸汽的流e 2，F）在至少一个另外的压缩级中压缩并冷却气流e 2 以获得包含正丁烷和水的至少一个冷凝物流f 1和包含正丁烷，氢气和二氧化碳的气流f 2，G）冷却气流f 2以获得包含正丁烷和水的冷凝物流g 1， 丁烷和 废气流g 2包括二氧化碳和氢气，H）从至少一个冷凝物流f 1中除去水，如果合适的话，通过相分离从冷凝物流g 1中除去水，以获得至少一个包含正丁烷和 至少一个废水流h 2，并将所述至少一个循环流h 1再循环到第一脱氢区中。
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