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    Raft polymerisation
    1.
    发明授权
    Raft polymerisation 有权
    筏聚合

    公开(公告)号：US09340498B2

    公开(公告)日：2016-05-17

    申请号：US13145993

    申请日：2010-01-22

    申请人： Ezio Rizzardo ,  John Chiefari ,  Massimo Benaglia ,  San Thang ,  Graeme Moad

    发明人： Ezio Rizzardo ,  John Chiefari ,  Massimo Benaglia ,  San Thang ,  Graeme Moad

    IPC分类号： C08F2/38 ,  C07C329/20 ,  C07C333/24 ,  C07D213/68 ,  C07D213/74 ,  C08F4/00 ,  C08F293/00 ,  C07D213/24 ,  C07D213/06 ,  C07D213/60

    CPC分类号： C07C329/20 ,  C07C333/24 ,  C07D213/06 ,  C07D213/24 ,  C07D213/60 ,  C07D213/68 ,  C07D213/74 ,  C08F2/38 ,  C08F4/00 ,  C08F293/005 ,  C08F2438/03

    摘要： A method of preparing polymer, the method comprising polymerizing one or more ethylenically unsaturated monomers of formula (I) where U is selected from H, C1-C4 alkyl or halogen; V is halogen or of the form O-G where G is selected from —C(O)R1 and —R1, or V is of the form NGGa where G is as defined above and Ga is selected from H and R1, G and Ga form together with N a heterocyclic ring, or V is of the form CH2Gb where Gb is selected from H, R1, OH, OR1, NR12, PR12, P(O)R12, P(OR1)2, SR1, SOR1, and SO2R1; and where the or each R1 is independently selected from optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted carbocyclyl, optionally substituted heterocyclyl, optionally substituted arylalkyl, optionally substituted heteroarylalkyl, optionally substituted alkylaryl, optionally substituted alkylheteroaryl, and an optionally substituted polymer chain, under the control of a RAFT agent of formula (II) or (III), where Y is a Lewis base moiety and Y* is an n-valent Lewis base moiety; X is O or NR1, R1 is as defined above or forms together with Y or Y* and N a heterocyclic ring; m is an integer ≧1; n is an integer ≧2; and where R* is a m-valent radical leaving group that affords R*. which initiates free radical polymerization of the one or more ethylenically unsaturated monomers of formula (I), and R is a free radical leaving group that affords R. which initiates free radical polymerization of the one or more ethylenically unsaturated monomers of formula (I).

    摘要翻译： 一种制备聚合物的方法，所述方法包括使U选自H，C 1 -C 4烷基或卤素的一种或多种式（I）的烯属不饱和单体聚合; V是卤素或其中G选自-C（O）R 1和-R 1的OG形式，或V是NGGa形式，其中G如上所定义，并且Ga选自H和R 1，G和Ga一起形成 其中G a选自H，R 1，OH，OR 1，NR 12，PR 12，P（O）R 12，P（OR 1）2，SR 1，SOR 1和SO 2 R 1; 任选取代的芳基，任选取代的杂芳基，任选取代的碳环基，任选取代的杂环基，任选取代的芳基烷基，任选取代的杂芳基烷基，任选取代的烷基芳基， 任选取代的烷基杂芳基和任选取代的聚合物链，其在式（II）或（III）的RAFT试剂的控制下，其中Y是路易斯碱部分，Y *是n价路易斯碱部分; X是O或NR 1，R 1如上定义或与Y或Y *一起形成，并且N a是杂环; m是整数≧1; n是整数≥2; 并且其中R *是提供R *的m价离去基团。 其引发式（I）的一种或多种烯属不饱和单体的自由基聚合，R是提供R.引发式（I）的一种或多种烯属不饱和单体的自由基聚合的自由基离去基团。

    Process for synthesizing thiol terminated polymers
    2.
    发明申请
    Process for synthesizing thiol terminated polymers 有权
    硫醇封端聚合物的合成方法

    公开(公告)号：US20070232783A1

    公开(公告)日：2007-10-04

    申请号：US11710305

    申请日：2007-02-23

    申请人： Graeme Moad ,  Ezio Rizzardo ,  San Thang

    发明人： Graeme Moad ,  Ezio Rizzardo ,  San Thang

    IPC分类号： C08F6/00

    CPC分类号： C08F293/005 ,  C08F8/00 ,  C08F2438/03 ,  C08F120/14 ,  C08F112/08 ,  C08F120/18

    摘要： The present invention is directed to a process for the cleavage of one or more starting polymers having thiocarbonylthio groups of the formula —S—(C═S)— into derived polymers having thiol end groups of the formula —SH. The process includes contacting the aforedescribed starting polymers, with a reagent having the formula Xa Yb, wherein Xa is a nucleophilic group and Yb is an extracting group that results in the starting polymer and a byproduct, which is then separated from the derived polymer by conventional separation processes. The derived polymer is free from any odor or color that is sometimes associated with the starting polymer and it can be used in making optical lenses, such as contact lenses.

    摘要翻译： 本发明涉及将具有式-S-（C-S） - 的硫代羰基硫基的一种或多种起始聚合物切割成具有式-SH硫醇端基的衍生聚合物的方法。 该方法包括使上述起始聚合物与具有式X的试剂接触 Y＆lt; b＆lt; b＆lt; 是亲核基团，Y B是导致起始聚合物和副产物的提取基团，然后通过常规分离方法与衍生的聚合物分离。 衍生的聚合物没有任何有时与起始聚合物缔合的气味或颜色，并且可以用于制造光学透镜，例如隐形眼镜。

    RAFT POLYMERISATION
    4.
    发明申请
    RAFT POLYMERISATION 有权
    RAFT聚合

    公开(公告)号：US20120004381A1

    公开(公告)日：2012-01-05

    申请号：US13145993

    申请日：2010-01-22

    申请人： Ezio Rizzardo ,  John Chiefari ,  Massimo Benaglia ,  San Thang ,  Graeme Moad

    发明人： Ezio Rizzardo ,  John Chiefari ,  Massimo Benaglia ,  San Thang ,  Graeme Moad

    IPC分类号： C08F120/10 ,  C07D213/75 ,  C07D401/12 ,  C08F112/08 ,  C07D211/74 ,  C07C333/24 ,  C08F218/08 ,  C08F220/10 ,  C08F2/38 ,  C07C329/06

    CPC分类号： C07C329/20 ,  C07C333/24 ,  C07D213/06 ,  C07D213/24 ,  C07D213/60 ,  C07D213/68 ,  C07D213/74 ,  C08F2/38 ,  C08F4/00 ,  C08F293/005 ,  C08F2438/03

    摘要： A method of preparing polymer, the method comprising polymerising one or more ethylenically unsaturated monomers of formula (I) where U is selected from H, C1-C4 alkyl or halogen; V is halogen or of the form O-G where G is selected from —C(O)R1 and —R1, or V is of the form NGGa where G is as defined above and Ga is selected from H and R1, G and Ga form together with N a heterocyclic ring, or V is of the form CH2Gb where Gb is selected from H, R1, OH, OR1, NR12, PR12, P(O)R12, P(OR1)2, SR1, SOR1, and SO2R1; and where the or each R1 is independently selected from optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted carbocyclyl, optionally substituted heterocyclyl, optionally substituted arylalkyl, optionally substituted heteroarylalkyl, optionally substituted alkylaryl, optionally substituted alkylheteroaryl, and an optionally substituted polymer chain, under the control of a RAFT agent of formula (II) or (III), where Y is a Lewis base moiety and Y* is an n-valent Lewis base moiety; X is O or NR1, R1 is as defined above or forms together with Y or Y* and N a heterocyclic ring; m is an integer ≧1; n is an integer ≧2; and where R* is a m-valent radical leaving group that affords R*. which initiates free radical polymerisation of the one or more ethylenically unsaturated monomers of formula (I), and R is a free radical leaving group that affords R. which initiates free radical polymerisation of the one or more ethylenically unsaturated monomers of formula (I).

    摘要翻译： 一种制备聚合物的方法，所述方法包括聚合一种或多种式（I）的烯属不饱和单体，其中U选自H，C 1 -C 4烷基或卤素; V是卤素或其中G选自-C（O）R 1和-R 1的OG形式，或V是NGGa形式，其中G如上所定义，并且Ga选自H和R 1，G和Ga一起形成 其中G a选自H，R 1，OH，OR 1，NR 12，PR 12，P（O）R 12，P（OR 1）2，SR 1，SOR 1和SO 2 R 1; 任选取代的芳基，任选取代的杂芳基，任选取代的碳环基，任选取代的杂环基，任选取代的芳基烷基，任选取代的杂芳基烷基，任选取代的烷基芳基， 任选取代的烷基杂芳基和任选取代的聚合物链，其在式（II）或（III）的RAFT试剂的控制下，其中Y是路易斯碱部分，Y *是n价路易斯碱部分; X是O或NR 1，R 1如上定义或与Y或Y *一起形成，并且N a是杂环; m是整数≧1; n是整数≥2; 并且其中R *是提供R *的m价离去基团。 其引发一种或多种式（I）的烯键式不饱和单体的自由基聚合，R是提供R.引发式（I）的一种或多种烯属不饱和单体的自由基聚合的自由基离去基团。

    PROCESS OF MICROGEL SYNTHESIS AND PRODUCTS PRODUCED THEREFROM
    5.
    发明申请
    PROCESS OF MICROGEL SYNTHESIS AND PRODUCTS PRODUCED THEREFROM 有权
    微胶囊合成方法及其制备的产品

    公开(公告)号：US20060142404A1

    公开(公告)日：2006-06-29

    申请号：US10257991

    申请日：2001-04-06

    申请人： Charles Berge ,  John Chiefari ,  Jeffery Johnson ,  Albert Mau ,  Roshan Mayadunne ,  Catherine Moad ,  Graeme Moad ,  Ezio Rizzardo ,  Gerry Swiegers ,  San Thang ,  Gerry Wilson

    发明人： Charles Berge ,  John Chiefari ,  Jeffery Johnson ,  Albert Mau ,  Roshan Mayadunne ,  Catherine Moad ,  Graeme Moad ,  Ezio Rizzardo ,  Gerry Swiegers ,  San Thang ,  Gerry Wilson

    IPC分类号： B29C44/34

    CPC分类号： C08L53/00 ,  C08F293/005 ,  C08F2438/03 ,  C09D153/00 ,  C08L2666/02

    摘要： The invention provides in one aspect a process for preparing a microgel by RAFT polymerizing in the presence of a RAFT chain transfer agent, one or more solvophobic monomers and one or more solvophilic monomers to form one or more block copolymers comprising one or more solvophobic blocks and one or more solvophilic blocks wherein the solvophobic block is insoluble in a dispersing medium and the solvophilic block is soluble in the dispersing medium. The block copolymer is dispersed in the dispersing medium to form micelles, which is then stabilized to form the microgel. The dispersing medium can be aqueous or lipophilic. The method of the present invention also permits one to encapsulate a wide variety of materials, such as pigments, dye molecules, and aluminum flakes used in metallized paints.

    摘要翻译： 本发明在一个方面提供了一种通过RAFT聚合制备微凝胶的方法，其在RAFT链转移剂，一种或多种疏水单体和一种或多种溶剂亲油性单体的存在下聚合以形成一种或多种包含一种或多种疏乳嵌段的嵌段共聚物和 一种或多种溶剂亲和性嵌段，其中所述疏水性嵌段不溶于分散介质，并且所述溶剂性嵌段可溶于所述分散介质中。 将嵌段共聚物分散在分散介质中以形成胶束，然后将其稳定化以形成微凝胶。 分散介质可以是水性或亲油性的。 本发明的方法还允许包封各种材料，例如用于金属化涂料中的颜料，染料分子和铝薄片。

    PROCESS FOR TRANSFORMING THE END GROUPS OF POLYMERS
    6.
    发明申请
    PROCESS FOR TRANSFORMING THE END GROUPS OF POLYMERS 有权
    改造聚合物末端组的方法

    公开(公告)号：US20100137548A1

    公开(公告)日：2010-06-03

    申请号：US12528249

    申请日：2007-02-23

    申请人： Graeme Moad ,  San Hoa Thang ,  Ezio Rizzardo

    发明人： Graeme Moad ,  San Hoa Thang ,  Ezio Rizzardo

    IPC分类号： C08G18/10 ,  C08G75/28

    CPC分类号： C08F8/00 ,  C08F2/38 ,  C08F8/04 ,  C08F8/12 ,  C08F112/08 ,  C08F2438/03 ,  C08F2810/40 ,  C08G18/6287 ,  C08G65/3322 ,  C08G65/33337 ,  C08G65/33368 ,  C08G65/334 ,  C08G65/3344 ,  C08G65/3348 ,  C08L25/06 ,  C08L71/02 ,  C08L2205/05 ,  C08L2666/04 ,  C08F120/18

    摘要： The present invention is directed to a process for the cleavage of one or more starting polymers having thiocarbonylthio groups of the formula (I) into derived polymers in which the —S—(C═S)— group is transformed. The process includes contacting the starting polymer containing groups Yb with one or more reagents containing groups Xa to produce the derived polymer and a byproduct containing the groups Yb, wherein the groups Xa is one or more reactive groups and the groups Yb is an extracting group and a byproduct, which is then separated from the derived polymer by conventional separation processes. The derived polymer is free from odor or color that is sometimes associated with the starting polymer and it can be used in making optical lenses, such as high refractive index spectacle lenses.

    摘要翻译： 本发明涉及将具有式（I）的硫代羰基硫基的一种或多种起始聚合物切割成其中-S-（C = S） - 基团被转化的衍生聚合物的方法。 该方法包括使含有基团Yb的起始聚合物与含有基团Xa的一种或多种试剂接触以制备衍生的聚合物和含有基团Yb的副产物，其中基团Xa是一个或多个反应性基团，基团Yb是提取基团， 副产物，然后通过常规分离方法与衍生的聚合物分离。 衍生的聚合物没有有时与起始聚合物相关的气味或颜色，并且可以用于制造光学透镜，例如高折射率眼镜镜片。

    Polymerization with living characteristics
    7.
    发明授权
    Polymerization with living characteristics 有权
    具有生活特性的聚合

    公开(公告)号：US07666962B2

    公开(公告)日：2010-02-23

    申请号：US11805949

    申请日：2007-05-25

    申请人： Tam Phuong Le ,  Graeme Moad ,  Ezio Rizzardo ,  San Hoa Thang

    发明人： Tam Phuong Le ,  Graeme Moad ,  Ezio Rizzardo ,  San Hoa Thang

    IPC分类号： C08F2/00

    CPC分类号： C08K5/38 ,  C07C327/36 ,  C07C329/00 ,  C07F9/4065 ,  C08F2/38 ,  C08F12/08 ,  C08F293/00 ,  C08F293/005 ,  C08L25/06

    摘要： This invention concerns a free radical polymerization process, selected chain transfer agents employed in the process and polymers made thereby, in which the process comprises preparing polymer of general Formula (A) and Formula (B) comprising contacting: (i) a monomer selected from the group consisting of vinyl monomers (of structure CH2=CUV), maleic anhydride, N-alkylmaleimide, N-arylmaleimide, dialkyl fumarate and cyclopolymerizable monomers; (ii) a thiocarbonylthio compound selected from Formula (C) and Formula (D) having a chain transfer constant greater than about 0.1; and (iii) free radicals produced from a free radical source; the polymer of Formula (A) being made by contacting (i), (ii) C and (iii) and that of Formula (B) by contacting (i), (ii) D, and (iii); and (iv) controlling the polydispersity of the polymer being formed by varying the ratio of the number of molecules of (ii) to the number of molecules of (iii); wherein Q, R, U, V, Z, Z′, m, p and q am as defined in the text.

    摘要翻译： 本发明涉及自由基聚合方法，该方法中使用的选择的链转移剂和由此制备的聚合物，其中该方法包括制备通式（A）和式（B）的聚合物，其包括：（i）选自 由乙烯基单体（结构CH 2 = CUV），马来酸酐，N-烷基马来酰亚胺，N-芳基马来酰亚胺，富马酸二烷基酯和可环化聚合的单体组成的组; （ii）选自式（C）和式（D）的硫代羰基硫代化合物，其链转移常数大于约0.1; 和（iii）自由基产生的自由基; 式（A）的聚合物通过使（i），（ii）D和（iii）接触而使（i），（ii）C和（iii）与式（B） 和（iv）通过改变（ii）的分子数与（iii）的分子数之比来控制形成的聚合物的多分散性; 其中如文中所定义的Q，R，U，V，Z，Z'，m，p和q am。