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8 条记录 (耗时 0.015 秒)

    Process for the manufacture of carboxylic acid chlorides
    1.
    发明授权
    Process for the manufacture of carboxylic acid chlorides 失效
    制备羧酸氯化物的方法

    公开(公告)号：US3962326A

    公开(公告)日：1976-06-08

    申请号：US463826

    申请日：1974-04-24

    申请人： Gunther Semler ,  Georg Schaeffer ,  Karl Waldmann

    发明人： Gunther Semler ,  Georg Schaeffer ,  Karl Waldmann

    IPC分类号： C07C53/38 ,  C07B61/00 ,  C07C51/00 ,  C07C51/60 ,  C07C55/36 ,  C07C57/64 ,  C07C63/00 ,  C07C67/00 ,  C07C51/58

    CPC分类号： C07C51/60

    摘要： Process for preparing carboxylic acid chlorides by reaction of carboxylic acids or carboxylic anhydrides with phosgene at temperatures of from 0.degree. to 180.degree.C in the presence of a catalyst, wherein 0.01 to 10 weight percent, calculated on the carboxylic acid or the carboxylic anhydride, of trisubstituted phosphine oxides or trisubstituted phosphine sulfides or reaction products of these compounds with phosgene and/or acids or acid anhydrides or mixtures of these compounds are used as catalyst.

    摘要翻译： 通过羧酸或羧酸酐与光气在0℃至180℃的温度下在催化剂存在下反应制备羧酸氯化物的方法，其中0.01至10％（重量）按羧酸或羧酸酐计算， 三取代膦氧化物或三取代膦硫化物或这些化合物与光气和/或酸或酸酐或这些化合物的混合物的反应产物用作催化剂。

    Process for the production of ceramic green films
    2.
    发明授权
    Process for the production of ceramic green films 失效
    陶瓷绿膜生产工艺

    公开(公告)号：US4968473A

    公开(公告)日：1990-11-06

    申请号：US281200

    申请日：1988-12-07

    申请人： Hans D. Hermann ,  Dieter Grote ,  Karl Waldmann

    发明人： Hans D. Hermann ,  Dieter Grote ,  Karl Waldmann

    IPC分类号： B01F17/00 ,  B01F17/46 ,  C04B35/634

    CPC分类号： C04B35/6342 ,  B01F17/0042 ,  C04B35/634 ,  C04B35/63488

    摘要： Ceramic green films having advantageous isotropic distribution of the inorganic pigment can be obtained by casting and drying a slip containing finely divided inorganic pigment, organic solvents, polyvinylbutyral, plasticizer and dispersing agent if compounds which contain in their molecules at least one structural unit of the formula Z ##STR1## in which A and B, which must be different, stand for either the oxyalkylene unit --C.sub.3-4 H.sub.6-8 O-- or the oxyalkylene unit --C.sub.2 H.sub.4 O-- and x and y, which can be identical or different, each denote a number from 1 to 200, are used as dispersing agents.Ceramic green films produced according to the invention can be converted to isotropic ceramic substrates by subsequent heat treatment and sintering.

    摘要翻译： 具有有机无机颜料的各向同性分布的陶瓷绿膜可以通过将含有细碎无机颜料，有机溶剂，聚乙烯醇缩丁醛，增塑剂和分散剂的滑爽液浇铸和干燥来获得，如果化合物在其分子中含有至少一个式 Z （Z）其中A和B必须不同，代表氧化烯单元-C3-4H6-8O-或氧化烯单元-C2H4O-，x和y可以相同或不同， 各自表示1〜200的数，用作分散剂。 通过随后的热处理和烧结，可以将根据本发明生产的陶瓷绿膜转化为各向同性的陶瓷衬底。

    Process for the preparation of organophosphorus derivatives of 2,4-di-tert-butylphenol, of 4,4'-dihalomagnesium compounds of biphenyl and the use of the organophosphorus derivatives for the stabilization of polyolefin molding
    3.
    发明授权
    Process for the preparation of organophosphorus derivatives of 2,4-di-tert-butylphenol, of 4,4'-dihalomagnesium compounds of biphenyl and the use of the organophosphorus derivatives for the stabilization of polyolefin molding 失效
    制备2,4-二 - 叔丁基苯酚的4,4'-二氢马来酸化合物的联苯衍生物的有机衍生物的方法和用于稳定聚烯烃成型的有机磷衍生物的用途

    公开(公告)号：US5109043A

    公开(公告)日：1992-04-28

    申请号：US452751

    申请日：1989-12-19

    申请人： Manfred Bohshar ,  Hans-Jerg Kleiner ,  Karl Waldmann ,  Gerhard Pfahler

    发明人： Manfred Bohshar ,  Hans-Jerg Kleiner ,  Karl Waldmann ,  Gerhard Pfahler

    IPC分类号： C09K15/32 ,  C07F3/02 ,  C07F9/40 ,  C07F9/48 ,  C08K5/53 ,  C08K5/5393 ,  C08L23/00

    CPC分类号： C07F9/4875 ,  C07F3/02 ,  C07F9/4084 ,  C08K5/5393

    摘要： A process for the preparation of organophosphorus derivatives of 2,4-di-tert-butylphenol with a high proportion of organophosphorus derivatives of biphenyl, which comprises reacting, in a first step, a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35, under Grignard conditions with magnesium to form the corresponding Grignard compound and this is further reacted in a second step with bis(2,4-di-tert-butylphenyl) chlorophosphite with the formation of a mixture in which at least 50% by weight of the phosphorus is combined in the form of tetrakis(2,4-di-tert-butylphenyl) 4,4'-biphenylenediphosphonite. The invention further relates to a polyolefin molding composition containing tetrakis(2,4-di-tert-butylphenyl) 4,4'-biphenylenediphosphonite which was prepared by reaction of a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35 with magnesium to form the Grignard compound and by subsequent reaction with bis(2,4-di-tert-butylphenyl) chlorophosphite. The invention furthermore relates to a process for the preparation of 4,4'-dihalomagnesium compounds of biphenyl by reacting a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35 in the absence of an entrainer, with fine-particle magnesium which is held in suspension.

    摘要翻译： 一种制备2,4-二叔丁基苯酚有机磷衍生物与高比例联苯有机磷衍生物的方法，其包括在第一步中使卤素原子量为4,4'-二卤联苯 至少35，在Grignard条件下用镁形成相应的格氏化合物，并且在第二步中进一步与双（2,4-二叔丁基苯基）氯亚磷酸酯反应形成混合物，其中至少50 按重量计的磷重量合并为四（2,4-二叔丁基苯基）4,4'-联苯二亚磷酸盐的形式。 本发明还涉及一种含有四（2,4-二叔丁基苯基）4,4'-联苯二亚磷酸盐的聚烯烃模塑组合物，其通过使卤素原子量至少为原子量的4,4'-二卤代联苯 35与镁形成格氏化合物，随后与双（2,4-二叔丁基苯基）氯亚磷酸酯反应。 本发明还涉及通过在不存在夹带剂的情况下使卤素原子量至少为35的4,4'-二卤联苯与细颗粒反应来制备联苯的4,4'-二卤代镁化合物的方法 保持悬浮的镁。

    Copolymers containing perfluoroalkyl groups
    5.
    发明授权
    Copolymers containing perfluoroalkyl groups 失效
    含全氟烷基的共聚物

    公开(公告)号：US4100340A

    公开(公告)日：1978-07-11

    申请号：US773537

    申请日：1977-03-02

    申请人： Karl Waldmann ,  Gunter Schnabel

    发明人： Karl Waldmann ,  Gunter Schnabel

    IPC分类号： C08F14/00 ,  C08F2/06 ,  C08F20/00 ,  C08F20/22 ,  C08F20/52 ,  C08F220/18 ,  C09K3/18 ,  D06M15/277 ,  C08F214/08

    CPC分类号： D06M15/277 ,  C08F220/18 ,  Y10S428/904 ,  Y10T428/3154 ,  Y10T428/31909 ,  Y10T428/31982

    摘要： Copolymers of(A) perfluoroalkylethyl acrylate C.sub.n F.sub.2n+1 CH.sub.2 CH.sub.2 OCOCH.dbd.CH.sub.2(b) higher alkyl acrylate C.sub.m H.sub.2m+1 OCOCH.dbd.CH.sub.2(c) vinylidene chloride CH.sub.2 .dbd.CCl.sub.2(D) acroylbutylurethane CH.sub.2 .dbd.CH--CONHCOOC.sub.4 H.sub.9 at the weight ratio of 1(A) : 0.22-0.39(B) : 0.45-0.85(C) : 0.01-0.15(D) n being 6, 8, 10, 12 or 14 and m being a number from 10 to 16.They are prepared by conventional methods for preparing copolymers and are used as oil - and water repellents for porous materials, especially textile materials.

    摘要翻译： （A）丙烯酸全氟烷基乙酯的共聚物CnF2n + 1CH2CH2OCOCH = CH2（B）丙烯酸高级烷基酯CmH2m + 1OCOCH = CH2（C）偏二氯乙烯CH2 = CCl2（D）丙烯酰基丁基氨基甲酸酯CH2 = CH-CONHCOOC4H9，重量比为1（A） 0.22-0.39（B）：0.45-0.85（℃）：0.01-0.15（D）n为6,8,10,12或14，m为10至16的数。

    Reaction product of olefinically unsaturated compounds with compounds containing active hydrogen, processes for their preparation and 2-component lacquers based thereon
    6.
    发明授权
    Reaction product of olefinically unsaturated compounds with compounds containing active hydrogen, processes for their preparation and 2-component lacquers based thereon 失效

    公开(公告)号：US5084536A

    公开(公告)日：1992-01-28

    申请号：US371517

    申请日：1989-06-26

    申请人： Gerhard Brindopke ,  Gerd Walz ,  Karl Waldmann ,  Manfred Schon ,  Hans-Jerg Kleiner

    发明人： Gerhard Brindopke ,  Gerd Walz ,  Karl Waldmann ,  Manfred Schon ,  Hans-Jerg Kleiner

    IPC分类号： C08G61/12 ,  C07D487/04 ,  C07D487/10 ,  C08F8/00 ,  C08F236/02 ,  C08F299/02 ,  C08G16/00 ,  C08G18/81 ,  C08G18/83 ,  C08G61/00 ,  C08G61/10 ,  C09D165/00

    CPC分类号： C07D487/04 ,  C07D487/10 ,  C08F299/02 ,  C08F8/00 ,  C08G16/00 ,  C08G18/8141 ,  C08G18/83 ,  C08G61/00

    摘要： A 3-component lacquer composed of A) compounds containing at least two R.sup.1 R.sup.2 C.dbd.CR.sup.3 --X groups (I) wherein R.sup.1 denotes hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms, R.sup.2 and R.sup.3 are individually hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, an ester group containing the radical R.sup.4 of a monohydric alcohol having up to 12 carbon atoms, --CN, --NO.sub.2 or a --CO--NHR.sup.1 or --CO--R.sup.1 group, X is --CO-- which is attached to a further R.sup.1 R.sup.2 C.dbd.CR.sup.3 -- group either directly or via the radical of a polyhydric alcohol or of an amine and B) compounds containing:(a) at least two active H atoms or(b) at least two groups having active H atoms of the type --AH (II) or(c) at least one active H atom and at least one group of the type (II)and A is --CH-- or --NH-- or --S-- and optionally with customary additives and C) at least one catalyst selected from the group consisting of diazabicyclooctane (DABCO), fluorides of quaternary ammonium compounds on their own or as a mixture with alkyl silicates, amidines, tertiary phosphanes of the formula P(CH.sub.2 --Y).sub.3 in which the Ys are identical or different and are --OH, --CH.sub.2 CN or --N(Z).sub.2 in which Z is an alkyl having 1 to 5 carbon atoms, tertiary phosphanes of the formula P(R.sup.4,R.sup.5,R.sup.6) in which R.sup.4, R.sup.5 and R.sup.6 are alkyl of 1 to 12 carbon atoms or a phenyl which is unsubstituted or substituted by at least one alkyl, alkoxy or dialkylamino, each of which has 1 to 4 carbon atoms in the alkyl, and R.sup.4, R.sup.5 and R.sup.6 are identical or different, but at least one of them is phenyl, and aminophosphoranes of the formula (R.sup.7,R.sup.8,R.sup.9) P.dbd.N--C (R.sup.10, R.sup.11,R.sup.12) in which R.sup.7, R.sup.8 and R.sup.9 are identical or different and denote an alkyl having 1 to 12 carbon atoms or a alkoxy or dialkylamino group, each of which has 1 to 4 carbon atoms in the alkyl, and R.sup.10, R.sup.11 and R.sup.12 are identical or different and each represents an alkyl having 1 to 5 carbon atoms or a phenyl.