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    Polyamino-polyamide crosslinked with crosslinking agent
    1.
    发明授权
    Polyamino-polyamide crosslinked with crosslinking agent 失效

    公开(公告)号：US4277581A

    公开(公告)日：1981-07-07

    申请号：US57684

    申请日：1979-07-16

    申请人： Guy Vanlerberghe ,  Henri Sebag ,  Jean-Francois Grollier ,  Alexandre Zysman

    发明人： Guy Vanlerberghe ,  Henri Sebag ,  Jean-Francois Grollier ,  Alexandre Zysman

    IPC分类号： A61K8/88 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/12 ,  C08G69/48

    CPC分类号： A61Q5/12 ,  A61K8/88 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  C08G69/48

    摘要： A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di-carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis-primary and mono- and bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of (a') simple bi-functional compounds selected from bis-halohydrins, bis-azetidinium, bis-haloacyl diamine and alkyl bis-halides, (b') oligomers obtained by the reaction of (1') a compound selected from the group consisting of the compounds in (a') above or an epihalohydrin,a bis-epoxide, or a bis-unsaturated derivative with (2') a compound reactive with the compound in (1'), and (c') the quaternized compounds comprising said crosslinked polymer alkylated with an alkylating agent selected from the group consisting of (a) epoxides, (b) ethylenically unsaturated compounds, (c) chloroacetic acid, and (d) alkane sultone selected from the group consisting of propane sultone and butane sultone. The crosslinking agent is employed in amounts of 0.025-0.35 mole per amine group in said polyamino-polyamide. The said crosslinked polymer is soluble in water in amounts of 10 weight percent thereof without essentially any gel formation and a 10 weight percent aqueous solution of the said crosslinked polymer has a viscosity greater than 3 centipoises at 25.degree. C.

    Hair conditioning compositions containing crosslinked polyaminopolyamides
    2.
    发明授权
    Hair conditioning compositions containing crosslinked polyaminopolyamides 失效
    含有交联聚氨基多酰胺的调理组合物

    公开(公告)号：US4172887A

    公开(公告)日：1979-10-30

    申请号：US762804

    申请日：1977-01-26

    申请人： Guy Vanlerberghe ,  Henri Sebag ,  Jean-Francois Grollier ,  Alexandre Zysman

    发明人： Guy Vanlerberghe ,  Henri Sebag ,  Jean-Francois Grollier ,  Alexandre Zysman

    IPC分类号： A61K8/88 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/12 ,  A61K7/06 ,  A61K7/08 ,  A61K7/09 ,  A61K7/11

    CPC分类号： A61Q5/12 ,  A61K8/88 ,  A61Q5/06 ,  A61Q5/02 ,  A61Q5/04 ,  Y10S424/02

    摘要： A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer selected from the group consisting of (1) crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di- carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of epihalohydrins, diepoxides, dianhydrides and bis unsaturated derivatives, and being employed in amounts of 0.025-0.35 mole per amine group in said polyamino-polyamide and (2) the crosslinked polymer of (1) alkylated with an alkylating agent selected from the group consisting of (a) epoxides, (b) ethylenically unsaturated compounds, (c) chloroacetic acid, and (d) alkane sultone selected from the group consisting of propane sultone and butane sultone. The said crosslinked polymer is soluble in water in amounts of 10 weight percent thereof without essentially any gel formation and a 10 weight percent aqueous solution of the said crosslinked polymer has a viscosity greater than 3 centipoises at 25.degree. C.

    摘要翻译： 用于毛发的化妆品组合物包含至少一种水溶性交联聚合物，其选自（1）通过交联聚氨基 - 聚酰胺与交联剂交联而获得的交联聚合物，所述聚氨基聚酰胺是通过（a ）选自（i）有机二羧酸，（ii）烯键式不饱和脂族单或二羧酸的酸性化合物，（iii）所述酸（i）和（ii）的酯和（iv （i），（ii）和（iii）的混合物在（b）选自双原料和单 - 或二 - 仲聚亚烷基多胺的多胺中，所述多胺（b）可以由选自 由（1）0-20摩尔％六亚甲基二胺，（2）0-40摩尔％双 - 伯胺和（3）0-40摩尔％双仲胺组成的组，所述交联剂选自 的表卤代醇，二环氧化物，二酐和双 不饱和衍生物，并且在所述聚氨基聚酰胺中以每个胺基计0.025-0.35摩尔的量使用（2）（1）烷基化剂与（a）环氧化物，（b）的烷基化剂烷基化的交联聚合物 ）烯键式不饱和化合物，（c）氯乙酸和（d）选自丙烷磺内酯和丁烷磺内酯的烷基磺内酯。 所述交联聚合物以10重量％的量溶解在水中而基本上没有任何凝胶形成，并且所述交联聚合物的10重量％水溶液的粘度在25℃下具有大于3厘泊的粘度。

    Crosslinked polyamino-polyamide in hair conditioning compositions
    3.
    发明授权
    Crosslinked polyamino-polyamide in hair conditioning compositions 失效

    公开(公告)号：US4189468A

    公开(公告)日：1980-02-19

    申请号：US881513

    申请日：1978-02-27

    申请人： Guy Vanlerberghe ,  Henri Sebag ,  Jean-Francois Grollier ,  Alexandre Zysman

    发明人： Guy Vanlerberghe ,  Henri Sebag ,  Jean-Francois Grollier ,  Alexandre Zysman

    IPC分类号： A61K8/88 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/12 ,  C08G69/48 ,  A61K7/06

    CPC分类号： A61Q5/02 ,  A61K8/88 ,  A61Q5/00 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/12 ,  C08G69/48 ,  Y10S424/01 ,  Y10S424/02

    摘要： A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di-carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis-primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of (a') simple bi-functional compounds selected from bis-halohydrins, bis-azetidinium, bis-haloacyl diamine and alkyl bis-halides, (b') oligomers obtained by the reaction of (1') a compound selected from the group consisting of the compounds in (a') above or an epihalohydrin, a bis-epoxide, or a bis-unsaturated derivative with (2') a compound reactive with the compound in (1'), and (c') the quaternized compounds comprising said crosslinked polymer alkylated with an alkylating agent selected from the group consisting of (a) epoxides, (b) ethylenically unsaturated compounds, (c) chloroacetic acid, and (d) alkane sultone selected from the group consisting of propane sultone and butane sultone. The crosslinking agent is employed in amounts of 0.025-0.35 mole per amine group in said polyamino-polyamide. The said crosslinked polymer is soluble in water in amounts of 10 weight percent thereof without essentially any gel formation and a 10 weight percent aqueous solution of the said crosslinked polymer has a viscosity greater than 3 centipoises at 25.degree. C.

    Cosmetic compositions based on poly-(quaternary ammonium) polymers
    8.
    发明授权
    Cosmetic compositions based on poly-(quaternary ammonium) polymers 失效
    基于聚（季铵）聚合物的化妆品组合物

    公开(公告)号：US4349532A

    公开(公告)日：1982-09-14

    申请号：US942319

    申请日：1978-09-14

    申请人： Guy Vanlerberghe ,  Henri Sebag ,  Alexandre Zysman

    发明人： Guy Vanlerberghe ,  Henri Sebag ,  Alexandre Zysman

    IPC分类号： C08L79/00 ,  A61K20060101 ,  A61K8/00 ,  A61K8/72 ,  A61K8/84 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/10 ,  A61Q5/12 ,  B01F17/18 ,  C07D295/16 ,  C08G20060101 ,  C08G73/00 ,  C08G73/02 ,  C08G73/06 ,  C08L20060101 ,  C08L67/00 ,  C08L77/00 ,  C11D3/37 ,  A61K7/06 ,  A61K7/09 ,  A61K7/11 ,  A61K7/13

    CPC分类号： A61K8/84 ,  A61Q5/06 ,  A61Q5/12 ,  Y10S424/04

    摘要： Composition suitable for treating the hair or skin, which conains at least one poly-(quaternary ammonium) polymer having units of the formula: ##STR1## in which A denotes an alkylene, hydroxyalkylene, alkenylene or alkynylene radical;B denotes:(a) --O--Z--O-- in which Z denotes a hydrocarbon radical or a group ##STR2## in which x and 4 denote a number from 1 to 4; (b) a bis-secondary diamine radical;(c) a radical --NH--Y--NH-- in which Y denotes a hydrocarbon radical or the radical --CH.sub.2 --CH.sub.2 --S--S--CH.sub.2 --CH.sub.2 --; or(d) a group --NH--CO--NH--;R.sub.1 denotes C.sub.1 -C.sub.4 alkyl; R.sub.2 denotes a hydrocarbon radical or two R.sub.2 radicals can complete a radical ##STR3## X denotes a halide; and n is 1 or an integer from 3 to 10. The polymers used in the composition of the invention have a good compatibility with anionic surface-active agents, are degradable and do not accumulate on the hair.

    摘要翻译： 组合物，其适用于处理头发或皮肤，其含有至少一种具有下式的单元的聚（季铵）聚合物：其中A表示亚烷基，羟基亚烷基，亚烯基或亚炔基; B表示：（a）-O-Z-O-，其中Z表示烃基或基团，其中x和4表示1至4的数; （b）二仲二胺基团; （c）基团-NH-Y-NH-，其中Y表示烃基或基团-CH2-CH2-S-S-CH2-CH2-; 或（d）基团-NH-CO-NH-; R1表示C1-C4烷基; R2表示烃基或两个R2基团可以完成基团X表示卤化物; 并且n为1或3至10的整数。本发明组合物中使用的聚合物与阴离子表面活性剂具有良好的相容性，是可降解的并且不会积聚在头发上。

    Deodorants or deodorisers and compositions containing them
    9.
    发明授权
    Deodorants or deodorisers and compositions containing them 失效
    除臭剂或除臭剂及含有它们的组合物

    公开(公告)号：US4275054A

    公开(公告)日：1981-06-23

    申请号：US69859

    申请日：1979-08-27

    申请人： Henri Sebag ,  Alexandre Zysman ,  Guy Vanlerberghe

    发明人： Henri Sebag ,  Alexandre Zysman ,  Guy Vanlerberghe

    IPC分类号： C08F8/00 ,  A61K8/00 ,  A61L9/01 ,  A61Q15/00 ,  C08F8/14 ,  C08G69/48 ,  C08G73/02 ,  C08G85/00 ,  C08L77/00 ,  C08F8/44 ,  A61K7/32 ,  A61K9/14 ,  C08F8/46

    CPC分类号： A61K8/88 ,  A61Q15/00 ,  C08G73/0233 ,  Y10S424/05

    摘要： A polyanionic polyamide salt which comprises chain units of the formula: ##STR1## in which X denotes ##STR2## R being an aliphatic radical containing 1 to 4 carbon atoms, each Y independently denotes a divalent aliphatic or cycloaliphatic radical, Z denotes a divalent radical of the formula: ##STR3## and M.sup.+ denotes a sodium or potassium ion or a quaternary ammonium ion of the formula: ##STR4## in which each of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently denotes a hydrogen atom or a methyl, ethyl, hydroxymethyl, hydroxyethyl, hydroxypropyl, methylhydroxypropyl or methyl-dihydroxypropyl radical, the viscosity of a 5% by weight aqueous solution of the salt being from 1 to 500 centipoises at a temperature of 25.degree. C., are provided which act as deodorants and deodorisers.

    摘要翻译： 一种聚阴离子聚酰胺盐，其包含下式的链单元：其中X表示R 1为含有1至4个碳原子的脂族基团，每个Y独立地表示二价脂族或脂环族基团，Z表示二价基团 其中，R 1，R 2，R 3和R 4各自独立地表示氢原子或甲基，乙基，羟甲基 羟乙基，羟丙基，甲基羟丙基或甲基 - 二羟丙基，在25℃的温度下，5重量％盐的水溶液的粘度为1至500厘泊，其用作除臭剂和除臭剂。