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    Paintable olefinic interpolymer compositions
    4.
    发明授权
    Paintable olefinic interpolymer compositions 失效
    可涂漆烯烃互聚物组合物

    公开(公告)号：US5883188A

    公开(公告)日：1999-03-16

    申请号：US926760

    申请日：1997-09-10

    申请人： Yuh-Chin Hwang ,  Stephen R. Betso ,  Thomas J. McKeand, Jr. ,  H. Craig Silvis ,  Deepak R. Parikh ,  Don J. Germano ,  Seema V. Karande

    发明人： Yuh-Chin Hwang ,  Stephen R. Betso ,  Thomas J. McKeand, Jr. ,  H. Craig Silvis ,  Deepak R. Parikh ,  Don J. Germano ,  Seema V. Karande

    IPC分类号： C08L51/06 ,  C08L51/00

    CPC分类号： C08L51/06 ,  Y10T428/31938

    摘要： Paintable thermoplastic polyolefin compositions are disclosed which comprise (i) about 20 to about 70 wt % of at least one graft-modified polypropylene, (ii) about 10 to about 40 wt % of at least one nongrafted or graft-modified homogeneously branched linear ethylene polymer, ethylene-propylene monomer rubber, ethylene-propylene-diene monomer rubber, heterogeneously branched linear ethylene polymer, styrene block copolymer, or a combination thereof and (iii) about 5 to about 50 wt % of an interpolymer of ethylene and an .alpha.,.beta.-unsaturated carbonyl copolymer, e.g. a copolymer of ethylene and acrylic acid. The polypropylene and, optionally the homogeneously branched linear ethylene polymer, ethylene-propylene monomer rubber, ethylene-propylene-diene monomer rubber, heterogeneously branched linear ethylene polymer, and styrene block copolymer are grafted with an unsaturated organic compound containing at least one site of ethylenic unsaturation and at least one carbonyl group, e.g. maleic anhydride. The compositions exhibit excellent paintability with conventional paints without prior application of a primer or surface treatment, good heat resistance, good low temperature impact resistance, and they can be recycled by melt blending the compositions with thermoplastic materials, e.g., in an extruder.

    摘要翻译： 公开了可涂覆的热塑性聚烯烃组合物，其包含（i）约20至约70重量％的至少一种接枝改性聚丙烯，（ii）约10至约40重量％的至少一种未接枝或接枝改性的均匀支化的线型乙烯 聚合物，乙烯 - 丙烯单体橡胶，乙烯 - 丙烯 - 二烯单体橡胶，非均匀支化的线性乙烯聚合物，苯乙烯嵌段共聚物或其组合，和（iii）约5-约50wt％的乙烯和α的互聚物， β-不饱和羰基共聚物，例如 乙烯和丙烯酸的共聚物。 聚丙烯和任选的均匀支化的线性乙烯聚合物，乙烯 - 丙烯单体橡胶，乙烯 - 丙烯 - 二烯单体橡胶，非均匀支化的线性乙烯聚合物和苯乙烯嵌段共聚物用含有至少一个烯属的位点的不饱和有机化合物 不饱和键和至少一个羰基，例如 马来酸酐。 组合物在常规涂料中表现出优异的可涂色性，而无需预先施用底漆或表面处理，良好的耐热性，良好的低温耐冲击性，并且它们可以通过将组合物与热塑性材料（例如在挤出机中）熔融共混来再循环。

    Block copolymer compositions containing substantially inert thermoelastic extenders
    7.
    发明授权
    Block copolymer compositions containing substantially inert thermoelastic extenders 有权
    含有基本上惰性的热弹性增量剂的嵌段共聚物组合物

    公开(公告)号：US06403710B1

    公开(公告)日：2002-06-11

    申请号：US09690039

    申请日：2000-10-16

    申请人： Wasif K. Ahmed ,  Stephen R. Betso ,  Antonio Batistini ,  Martin J. Guest ,  Thoi H. Ho ,  Deepak R. Parikh ,  George W. Knight ,  Rajen M. Patel

    发明人： Wasif K. Ahmed ,  Stephen R. Betso ,  Antonio Batistini ,  Martin J. Guest ,  Thoi H. Ho ,  Deepak R. Parikh ,  George W. Knight ,  Rajen M. Patel

    IPC分类号： C08L900

    CPC分类号： C09D153/02 ,  C08L23/0815 ,  C08L53/02 ,  C08L2314/06 ,  C08L2666/02 ,  C08L2666/04 ,  C09J153/02

    摘要： The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.

    摘要翻译： 本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物，其中组合物与组合物未未改性的未稀释（纯）嵌段共聚物部分具有基本上相同的比较弹性，高温可使用性和硬度。 该组合物还显示出增强的热稳定性和加工性，并且非常适用于制造弹性模制品，薄膜和纤维，以及用沥青，粘合剂和密封剂配制。 新型热塑性弹性体组合物包含（a）约50至约99重量％的至少一种嵌段共聚物和（b）约1至约50重量％的至少一种乙烯互聚物，其密度约为0.855克/ cc至约0.905g / cc，其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂，组合物进一步表征为具有： 在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2，ii。 在-26℃下的储能模量与24℃下的储能模量的比小于约4，和iii。 在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。

    Extrudable polymeric compositions
    8.
    发明授权
    Extrudable polymeric compositions 失效
    可挤压聚合物组合物

    公开(公告)号：US4937279A

    公开(公告)日：1990-06-26

    申请号：US230932

    申请日：1988-08-11

    申请人： Stephen R. Betso ,  Duane F. Foye ,  G. Edwin Vrieland

    发明人： Stephen R. Betso ,  Duane F. Foye ,  G. Edwin Vrieland

    IPC分类号： C08K3/32

    CPC分类号： C08K3/32 ,  Y10T428/1321

    摘要： The present invention is a polymeric composition with improved extrudability comprising a vinylidene chloride interpolymer and a Group IIA alkaline-earth hydroxyphosphate, which is incorporated with the vinylidene chloride interpolymer by advance addition, polymer slurry addition or, finally, by dry blending addition. The Group IIA alkaline-earth hydroxyphosphate will be present in an amount of between about 0.01 to about 5 weight percent, said weight percents being based on the total weight of the polymeric composition.

    摘要翻译： 本发明是一种具有改进的挤出性的聚合物组合物，其包含偏二氯乙烯互聚物和IIA型碱土金属羟基磷酸酯，其通过预先添加加入偏二氯乙烯互聚物，加入聚合物浆料，或最后通过干混添加。 IIA族碱土金属羟基磷酸酯的存在量为约0.01至约5重量％，所述重量百分比基于聚合物组合物的总重量。