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    Paintable olefinic interpolymer compositions
    1.
    发明授权
    Paintable olefinic interpolymer compositions 失效
    可涂漆烯烃互聚物组合物

    公开(公告)号：US5883188A

    公开(公告)日：1999-03-16

    申请号：US926760

    申请日：1997-09-10

    申请人： Yuh-Chin Hwang ,  Stephen R. Betso ,  Thomas J. McKeand, Jr. ,  H. Craig Silvis ,  Deepak R. Parikh ,  Don J. Germano ,  Seema V. Karande

    发明人： Yuh-Chin Hwang ,  Stephen R. Betso ,  Thomas J. McKeand, Jr. ,  H. Craig Silvis ,  Deepak R. Parikh ,  Don J. Germano ,  Seema V. Karande

    IPC分类号： C08L51/06 ,  C08L51/00

    CPC分类号： C08L51/06 ,  Y10T428/31938

    摘要： Paintable thermoplastic polyolefin compositions are disclosed which comprise (i) about 20 to about 70 wt % of at least one graft-modified polypropylene, (ii) about 10 to about 40 wt % of at least one nongrafted or graft-modified homogeneously branched linear ethylene polymer, ethylene-propylene monomer rubber, ethylene-propylene-diene monomer rubber, heterogeneously branched linear ethylene polymer, styrene block copolymer, or a combination thereof and (iii) about 5 to about 50 wt % of an interpolymer of ethylene and an .alpha.,.beta.-unsaturated carbonyl copolymer, e.g. a copolymer of ethylene and acrylic acid. The polypropylene and, optionally the homogeneously branched linear ethylene polymer, ethylene-propylene monomer rubber, ethylene-propylene-diene monomer rubber, heterogeneously branched linear ethylene polymer, and styrene block copolymer are grafted with an unsaturated organic compound containing at least one site of ethylenic unsaturation and at least one carbonyl group, e.g. maleic anhydride. The compositions exhibit excellent paintability with conventional paints without prior application of a primer or surface treatment, good heat resistance, good low temperature impact resistance, and they can be recycled by melt blending the compositions with thermoplastic materials, e.g., in an extruder.

    摘要翻译： 公开了可涂覆的热塑性聚烯烃组合物，其包含（i）约20至约70重量％的至少一种接枝改性聚丙烯，（ii）约10至约40重量％的至少一种未接枝或接枝改性的均匀支化的线型乙烯 聚合物，乙烯 - 丙烯单体橡胶，乙烯 - 丙烯 - 二烯单体橡胶，非均匀支化的线性乙烯聚合物，苯乙烯嵌段共聚物或其组合，和（iii）约5-约50wt％的乙烯和α的互聚物， β-不饱和羰基共聚物，例如 乙烯和丙烯酸的共聚物。 聚丙烯和任选的均匀支化的线性乙烯聚合物，乙烯 - 丙烯单体橡胶，乙烯 - 丙烯 - 二烯单体橡胶，非均匀支化的线性乙烯聚合物和苯乙烯嵌段共聚物用含有至少一个烯属的位点的不饱和有机化合物 不饱和键和至少一个羰基，例如 马来酸酐。 组合物在常规涂料中表现出优异的可涂色性，而无需预先施用底漆或表面处理，良好的耐热性，良好的低温耐冲击性，并且它们可以通过将组合物与热塑性材料（例如在挤出机中）熔融共混来再循环。

    Polyolefin elastomer blends exhibiting improved properties
    3.
    发明授权
    Polyolefin elastomer blends exhibiting improved properties 失效
    表现出改进性能的聚烯烃弹性体共混物

    公开(公告)号：US6005053A

    公开(公告)日：1999-12-21

    申请号：US784681

    申请日：1997-01-22

    申请人： Deepak R. Parikh ,  Pak-Wing S. Chum ,  Rajen M. Patel ,  Klye G. Kummer ,  Pradeep Jain ,  Thomas J. McKeand, Jr. ,  Ronald P. Markovich ,  Timothy E. Clayfield ,  Wasif Ahmed Khan

    发明人： Deepak R. Parikh ,  Pak-Wing S. Chum ,  Rajen M. Patel ,  Klye G. Kummer ,  Pradeep Jain ,  Thomas J. McKeand, Jr. ,  Ronald P. Markovich ,  Timothy E. Clayfield ,  Wasif Ahmed Khan

    IPC分类号： C08L23/04 ,  C08L23/08 ,  C08L91/00 ,  C08L33/02

    CPC分类号： C08L23/0815 ,  C08L2205/02 ,  C08L91/00

    摘要： Polymer mixtures are disclosed which comprise at least one homogeneously branched ethylene polymer (A) and at least one ethylene polymer (B) having a crystallinity which is at least 7% greater than the crystallinity of polymer (A) with certain provisos. A process for making a molded article using the disclosed polymer mixtures is disclosed as well as films, film layers, coatings and molded articles formed from those mixtures. These mixtures have several advantages over polymer compositions of the prior art, including improved properties at elevated temperatures such as improved softening point under load, improved hardness, improved toughness, improved 100% modulus of elasticity, improved compression set, improved ability to prevent oil bleed out at lower temperatures when the mixture contains oil and reduced injection molding cycle time. The mixtures retain their performance advantages even when substantial amounts of additives such as oil and filler are incorporated into the mixture. The mixtures may also be crosslinked after they are formed into the shape of an article to form vulcanized elastomeric products. The polymer mixtures have utility in a variety of applications.

    摘要翻译： 公开了包含至少一种均匀支化的乙烯聚合物（A）和至少一种乙烯聚合物（B）的聚合物混合物，其结晶度比聚合物（A）的结晶度大至少7％，具有某些条件。 公开了使用所公开的聚合物混合物制备模塑制品的方法以及由这些混合物形成的薄膜，薄膜层，涂层和模塑制品。 这些混合物具有优于现有技术的聚合物组合物的几个优点，包括在升高的温度下改进的性能，例如负载下改进的软化点，改进的硬度，改进的韧性，改进的100％弹性模量，改进的压缩永久变形，改进的防止油渗出的能力 当混合物含有油和降低注塑周期时，在较低的温度下出来。 即使将大量的添加剂如油和填料加入到混合物中，混合物也保持其性能优势。 在混合物形成制品的形状以形成硫化的弹性体产品之后，它们也可以交联。 聚合物混合物可用于各种应用。

    Block copolymer compositions containing substantially inert thermoelastic extenders
    4.
    发明授权
    Block copolymer compositions containing substantially inert thermoelastic extenders 有权
    含有基本上惰性的热弹性增量剂的嵌段共聚物组合物

    公开(公告)号：US06403710B1

    公开(公告)日：2002-06-11

    申请号：US09690039

    申请日：2000-10-16

    申请人： Wasif K. Ahmed ,  Stephen R. Betso ,  Antonio Batistini ,  Martin J. Guest ,  Thoi H. Ho ,  Deepak R. Parikh ,  George W. Knight ,  Rajen M. Patel

    发明人： Wasif K. Ahmed ,  Stephen R. Betso ,  Antonio Batistini ,  Martin J. Guest ,  Thoi H. Ho ,  Deepak R. Parikh ,  George W. Knight ,  Rajen M. Patel

    IPC分类号： C08L900

    CPC分类号： C09D153/02 ,  C08L23/0815 ,  C08L53/02 ,  C08L2314/06 ,  C08L2666/02 ,  C08L2666/04 ,  C09J153/02

    摘要： The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.

    摘要翻译： 本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物，其中组合物与组合物未未改性的未稀释（纯）嵌段共聚物部分具有基本上相同的比较弹性，高温可使用性和硬度。 该组合物还显示出增强的热稳定性和加工性，并且非常适用于制造弹性模制品，薄膜和纤维，以及用沥青，粘合剂和密封剂配制。 新型热塑性弹性体组合物包含（a）约50至约99重量％的至少一种嵌段共聚物和（b）约1至约50重量％的至少一种乙烯互聚物，其密度约为0.855克/ cc至约0.905g / cc，其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂，组合物进一步表征为具有： 在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2，ii。 在-26℃下的储能模量与24℃下的储能模量的比小于约4，和iii。 在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。

    Block copolymer compositions containing substantially inert thermoelastic extenders
    5.
    发明授权
    Block copolymer compositions containing substantially inert thermoelastic extenders 失效
    含有基本上惰性的热弹性增量剂的嵌段共聚物组合物

    公开(公告)号：US06184290B2

    公开(公告)日：2001-02-06

    申请号：US08979388

    申请日：1997-11-26

    申请人： Wasif K. Ahmed ,  Antonio Batistini ,  Stephen R. Betso ,  Martin J. Guest ,  Thoi H. Ho ,  George W. Knight ,  Deepak R. Parikh ,  Rajen M. Patel

    发明人： Wasif K. Ahmed ,  Antonio Batistini ,  Stephen R. Betso ,  Martin J. Guest ,  Thoi H. Ho ,  George W. Knight ,  Deepak R. Parikh ,  Rajen M. Patel

    IPC分类号： C08L4700

    CPC分类号： C09D153/02 ,  C08L23/0815 ,  C08L53/02 ,  C08L2314/06 ,  C08L2666/02 ,  C08L2666/04 ,  C09J153/02

    摘要： The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.

    摘要翻译： 本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物，其中组合物与组合物未未改性的未稀释（纯）嵌段共聚物部分具有基本上相同的比较弹性，高温可使用性和硬度。 该组合物还显示出增强的热稳定性和加工性，并且非常适用于制造弹性模制品，薄膜和纤维，以及用沥青，粘合剂和密封剂配制。 新型热塑性弹性体组合物包含（a）约50至约99重量％的至少一种嵌段共聚物和（b）约1至约50重量％的至少一种乙烯互聚物，其密度约为0.855克/ cc至约0.905g / cc，其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂，组合物进一步表征为具有： 在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2，ii。 在-26℃下的储能模量与24℃下的储能模量的比小于约4，和iii。 在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。