-
公开(公告)号：US20180148380A1
公开(公告)日：2018-05-31
申请号：US15822199
申请日：2017-11-26
IPC分类号： C04B35/56 , C09D7/12 , C09D11/101 , C09D11/102 , C09D11/03 , B33Y70/00 , B29C64/10 , B28B1/00
CPC分类号： C04B35/5603 , B28B1/001 , B29C64/10 , B29C64/129 , B29C64/379 , B29C71/02 , B29C2035/0827 , B29C2035/0838 , B29K2083/00 , B29K2105/0002 , B29K2509/04 , B29K2995/0026 , B29K2995/003 , B33Y10/00 , B33Y40/00 , B33Y70/00 , B33Y80/00 , C04B35/571 , C04B35/58 , C04B35/589 , C04B35/597 , C04B35/62218 , C04B35/62836 , C04B35/62839 , C04B35/63448 , C04B35/64 , C04B35/806 , C04B2235/3826 , C04B2235/3895 , C04B2235/483 , C04B2235/5216 , C04B2235/5436 , C04B2235/6026 , C04B2235/6562 , C04B2235/6565 , C04B2235/77 , C04B2235/96 , C08G77/18 , C08G77/20 , C08G77/28 , C08K3/34 , C08K7/00 , C08K7/10 , C08K9/04 , C08K2201/005 , C08L83/08 , C09D5/004 , C09D7/61 , C09D7/62 , C09D7/67 , C09D7/68 , C09D7/69 , C09D7/70 , C09D11/03 , C09D11/037 , C09D11/101 , C09D11/102 , C08L83/00
摘要： This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.
-
公开(公告)号：US20190077921A1
公开(公告)日：2019-03-14
申请号：US16190313
申请日：2018-11-14
发明人： Zak C. ECKEL
IPC分类号： C08G77/50 , G03F7/075 , G03F7/029 , B33Y10/00 , G03F7/027 , G03F7/025 , G03F7/004 , C04B35/632 , C04B35/622 , C04B35/597 , C04B35/589 , C04B35/583 , C08J3/28 , C04B35/64 , G03F7/00 , C04B35/515 , B28B1/00 , G03F7/031 , G03F7/038 , C04B35/56 , C04B35/571 , C04B35/58 , B33Y80/00 , B33Y70/00
摘要： This disclosure enables direct 3D printing of preceramic polymers, which can be converted to fully dense ceramics. Some variations provide a preceramic resin formulation comprising a molecule with two or more C═X double bonds or C≡X triple bonds, wherein X is selected from C, S, N, or O, and wherein the molecule further comprises at least one non-carbon atom selected from Si, B, Al, Ti, Zn, P, Ge, S, N, or O; a photoinitiator; a free-radical inhibitor; and a 3D-printing resolution agent. The disclosed preceramic resin formulations can be 3D-printed using stereolithography into objects with complex shape. The polymeric objects may be directly converted to fully dense ceramics with properties that approach the theoretical maximum strength of the base materials. Low-cost structures are obtained that are lightweight, strong, and stiff, but stable in the presence of a high-temperature oxidizing environment.
-
公开(公告)号：US20220177373A1
公开(公告)日：2022-06-09
申请号：US17682337
申请日：2022-02-28
IPC分类号： C04B35/56 , C09D11/037 , C04B35/58 , C04B35/589 , C08L83/08 , C04B35/571 , C04B35/597 , C04B35/515 , C04B35/117 , C04B35/14 , C04B35/44 , C04B35/46 , C04B35/488 , C04B35/532 , C04B35/563 , C04B35/565 , C04B35/581 , C04B35/80 , B33Y70/00 , C04B35/622 , C04B35/628 , C04B35/634 , C04B35/64 , B29C64/10 , C09D7/61 , B28B1/00 , C09D11/03 , C09D11/101 , C09D11/102 , B33Y40/00 , B33Y80/00 , B29C64/379 , C09D7/40 , C09D7/62 , C09D5/33
摘要： This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.
-
公开(公告)号：US20190002353A1
公开(公告)日：2019-01-03
申请号：US15946680
申请日：2018-04-05
发明人： Zak C. ECKEL , Jacob M. HUNDLEY , Robert MONE
IPC分类号： C04B35/589 , C04B35/524 , B28B1/00
CPC分类号： C04B35/589 , B28B1/001 , B33Y70/00 , C01B21/0648 , C01P2004/03 , C04B35/524 , C04B35/571 , C04B35/583 , C04B35/597 , C04B35/63452 , C04B2235/483 , C04B2235/486 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/77 , C04B2235/96 , C08G77/20 , C08G77/28 , C08L83/02 , C08L83/04 , C08L83/08 , C08L83/00 , C08K5/07
摘要： Resins for 3D printing of a preceramic composition loaded with a solid polymer filler, followed by converting the preceramic composition to a 3D-printed ceramic material, are described. Some variations provide a preceramic composition containing a radiation-curable liquid resin formulation and a solid polymer filler dispersed within the liquid resin formulation. The liquid resin formulation is compatible with stereolithography, UV curing, and/or 3D printing. The solid polymer filler may be an organic polymer, an inorganic polymer, or a combination thereof. The solid polymer filler may itself be an inorganic preceramic polymer, which may have the same composition as a polymerized variant of the liquid resin formulation, or a different composition. Many compositions are disclosed as options for the liquid resin formulation and the solid polymer filler.
-
公开(公告)号：US20180148379A1
公开(公告)日：2018-05-31
申请号：US15822197
申请日：2017-11-26
IPC分类号： C04B35/56 , C04B35/80 , C04B35/628 , C04B35/622 , C04B35/634 , C04B35/64 , B33Y70/00 , B29C64/129 , B29C71/02
摘要： This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.
-
公开(公告)号：US20230080459A1
公开(公告)日：2023-03-16
申请号：US17990915
申请日：2022-11-21
IPC分类号： C04B35/56 , C09D11/037 , C04B35/58 , C04B35/589 , C08L83/08 , C04B35/571 , C04B35/597 , C04B35/515 , C04B35/117 , C04B35/14 , C04B35/44 , C04B35/46 , C04B35/488 , C04B35/532 , C04B35/563 , C04B35/565 , C04B35/581 , C04B35/80 , B33Y40/20 , B33Y70/10 , B33Y40/10 , C04B35/622 , C04B35/628 , C04B35/634 , C04B35/64 , B29C64/10 , C09D7/61 , B28B1/00 , C09D11/03 , C09D11/101 , C09D11/102 , B33Y80/00 , B29C64/379 , C09D7/40 , C09D7/62 , C09D5/33
摘要： This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.
-
公开(公告)号：US20200290931A1
公开(公告)日：2020-09-17
申请号：US16888724
申请日：2020-05-30
发明人： Zak C. ECKEL , Andrew P. NOWAK , Ashley M. DUSTIN , April R. RODRIGUEZ , Phuong BUI , Tobias A. SCHAEDLER
IPC分类号： C04B35/571 , B33Y70/00 , B33Y80/00 , B28B1/00 , C08G77/50
摘要： This disclosure provides resin formulations which may be used for 3D printing and thermally treating to produce a ceramic material. The disclosure provides direct, free-form 3D printing of a preceramic polymer, followed by converting the preceramic polymer to a 3D-printed ceramic composite with potentially complex 3D shapes. A wide variety of chemical compositions is disclosed, and several experimental examples are included to demonstrate reduction to practice. For example, preceramic resin formulations may contain a carbosilane in which there is at least one functional group selected from vinyl, allyl, ethynyl, unsubstituted or substituted alkyl, ester group, amine, hydroxyl, vinyl ether, vinyl ester, glycidyl, glycidyl ether, vinyl glycidyl ether, vinyl amide, vinyl triazine, vinyl isocyanurate, acrylate, methacrylate, alkacrylate, alkyl alkacrylate, phenyl, halide, thiol, cyano, cyanate, or thiocyanate. The resin formulations may contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material.
-
公开(公告)号：US20180148585A1
公开(公告)日：2018-05-31
申请号：US15822203
申请日：2017-11-26
IPC分类号： C09D7/12 , C09D5/33 , C09D11/101 , C09D11/03 , C09D11/102 , C04B35/56 , B33Y70/00 , B33Y80/00 , B33Y40/00 , B29C64/379
CPC分类号： C04B35/5603 , B28B1/001 , B29C64/10 , B29C64/129 , B29C64/379 , B29C71/02 , B29C2035/0827 , B29C2035/0838 , B29K2083/00 , B29K2105/0002 , B29K2509/04 , B29K2995/0026 , B29K2995/003 , B33Y10/00 , B33Y40/00 , B33Y70/00 , B33Y80/00 , C04B35/571 , C04B35/58 , C04B35/589 , C04B35/597 , C04B35/62218 , C04B35/62836 , C04B35/62839 , C04B35/63448 , C04B35/64 , C04B35/806 , C04B2235/3826 , C04B2235/3895 , C04B2235/483 , C04B2235/5216 , C04B2235/5436 , C04B2235/6026 , C04B2235/6562 , C04B2235/6565 , C04B2235/77 , C04B2235/96 , C08G77/18 , C08G77/20 , C08G77/28 , C08K3/34 , C08K7/00 , C08K7/10 , C08K9/04 , C08K2201/005 , C08L83/08 , C09D5/004 , C09D7/61 , C09D7/62 , C09D7/67 , C09D7/68 , C09D7/69 , C09D7/70 , C09D11/03 , C09D11/037 , C09D11/101 , C09D11/102 , C08L83/00
摘要： This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.
-
公开(公告)号：US20240190775A1
公开(公告)日：2024-06-13
申请号：US18585284
申请日：2024-02-23
发明人： Zak C. ECKEL , Andrew P. NOWAK , Ashley M. DUSTIN , April R. RODRIGUEZ , Phuong BUI , Tobias A. SCHAEDLER
IPC分类号： C04B35/571 , B28B1/00 , B33Y70/00 , B33Y80/00 , C08G77/50
CPC分类号： C04B35/571 , B28B1/001 , B33Y70/00 , B33Y80/00 , C08G77/50 , C04B2235/5252 , C04B2235/665
摘要： This disclosure provides resin formulations which may be used for 3D printing and thermally treating to produce a ceramic material. The disclosure provides direct, free-form 3D printing of a preceramic polymer, followed by converting the preceramic polymer to a 3D-printed ceramic composite with potentially complex 3D shapes. A wide variety of chemical compositions is disclosed, and several experimental examples are included to demonstrate reduction to practice. For example, preceramic resin formulations may contain a carbosilane in which there is at least one functional group selected from vinyl, allyl, ethynyl, unsubstituted or substituted alkyl, ester group, amine, hydroxyl, vinyl ether, vinyl ester, glycidyl, glycidyl ether, vinyl glycidyl ether, vinyl amide, vinyl triazine, vinyl isocyanurate, acrylate, methacrylate, alkyl acrylate, alkyl methacrylate, phenyl, halide, thiol, cyano, cyanate, or thiocyanate. The resin formulations may contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material.
-
公开(公告)号：US20240124364A1
公开(公告)日：2024-04-18
申请号：US18393913
申请日：2023-12-22
发明人： Zak C. ECKEL , Andrew P. NOWAK , Ashley M. DUSTIN , April R. RODRIGUEZ , Phuong BUI , Tobias A. SCHAEDLER
IPC分类号： C04B35/571 , B28B1/00 , B33Y70/00 , B33Y80/00 , C08G77/50
CPC分类号： C04B35/571 , B28B1/001 , B33Y70/00 , B33Y80/00 , C08G77/50 , C04B2235/5252 , C04B2235/665
摘要： This disclosure provides resin formulations which may be used for 3D printing and thermally treating to produce a ceramic material. The disclosure provides direct, free-form 3D printing of a preceramic polymer, followed by converting the preceramic polymer to a 3D-printed ceramic composite with potentially complex 3D shapes. A wide variety of chemical compositions is disclosed, and several experimental examples are included to demonstrate reduction to practice. For example, preceramic resin formulations may contain a carbosilane in which there is at least one functional group selected from vinyl, allyl, ethynyl, unsubstituted or substituted alkyl, ester group, amine, hydroxyl, vinyl ether, vinyl ester, glycidyl, glycidyl ether, vinyl glycidyl ether, vinyl amide, vinyl triazine, vinyl isocyanurate, acrylate, methacrylate, alkacrylate, alkyl alkacrylate, phenyl, halide, thiol, cyano, cyanate, or thiocyanate. The resin formulations may contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material.
-
-
-
-
-
-
-
-
-
搜索结果
11 条记录 (耗时 0.016 秒)
