公开(公告)号：US5331039A

公开(公告)日：1994-07-19

申请号：US973368

申请日：1992-11-09

申请人： Harald Blum ,  Werner Kubitza ,  Joachim Probst ,  Michael Sonntag ,  Volker Schneider

发明人： Harald Blum ,  Werner Kubitza ,  Joachim Probst ,  Michael Sonntag ,  Volker Schneider

IPC分类号： C08G18/00 ,  C08G18/08 ,  C08G18/10 ,  C08G18/40 ,  C08G18/42 ,  C08G18/46 ,  C08G18/70 ,  C08L75/04 ,  C09D175/04 ,  C09D175/06 ,  C09J175/00 ,  C09J175/06 ,  H01L23/29 ,  H01L23/31 ,  C08L67/00

CPC分类号： C09D175/06 ,  C08G18/0819 ,  C08G18/10 ,  C08G18/4063 ,  C08G18/4202 ,  C08G18/706 ,  C08G2170/80

摘要： The present invention relates to a water-based binder composition containingA) an aqueous solution or dispersion of a water-dilutable organic polyol component containing a mixture of at least 5% by weight each of at least two hydroxy-functional polymers selected fromA1) polyester resins containing hydroxyl, urethane and carboxylate groups,A2) polyester resins containing hydroxyl and carboxylate groups, but no urethane or sulfonate groups,A3) polyester resins containing hydroxyl and sulfonate groups and, optionally, carboxylate groups and/or urethane groups,A4) polyacrylate resins containing hydroxyl, carboxylate and/or sulfonate groups,A5) acrylate-grafted polyester resins containing hydroxyl, carboxylate and/or sulfonate groups, andB) a polyisocyanate component which is emulsified in the aqueous solution or dispersion A), has a viscosity at 23.degree. C. of 50 to 10,000 mPa.s and contains at least one organic polyisocyanate,wherein the NCO:OH equivalent ratio, based on the isocyanate groups of component B) and the hydroxyl groups of the polyol component present in A), is 0.2:1 to 5:1.The present invention also relates to a process for the production of a coating or sealing composition containing this aqueous binder composition.

摘要翻译： 本发明涉及水性粘合剂组合物，其包含A）水可稀释有机多元醇组分的水溶液或分散体，其含有至少5重量％的至少两种羟基官能聚合物的混合物，所述羟基官能聚合物选自A1） 含有羟基，氨基甲酸酯和羧酸酯基团的聚酯树脂，A2）含有羟基和羧酸酯基团但不含氨基甲酸酯基或磺酸酯基团的聚酯树脂，A3）含有羟基和磺酸酯基团以及任选的羧酸酯基团和/或氨基甲酸酯基团的聚酯树脂，A4） 含有羟基，羧酸酯和/或磺酸酯基的聚丙烯酸酯树脂，A5）含有羟基，羧酸酯和/或磺酸酯基团的丙烯酸酯接枝的聚酯树脂，和B）在水溶液或分散体A）中乳化的多异氰酸酯组分具有粘度 在23℃下为50至10,000mPa.s并含有至少一种有机多异氰酸酯，其中NCO:OH当量比基于异氰酸酯 组分B）的组分和A）中存在的多元醇组分的羟基为0.2:1至5:1。 本发明还涉及一种生产包含该含水粘合剂组合物的涂料或密封组合物的方法。

公开(公告)号：US5336711A

公开(公告)日：1994-08-09

申请号：US973366

申请日：1992-11-09

申请人： Volker Schneider ,  Harald Blum ,  Werner Kubitza ,  Joachim Probst

发明人： Volker Schneider ,  Harald Blum ,  Werner Kubitza ,  Joachim Probst

IPC分类号： C08G18/08 ,  C08G18/42 ,  C08G18/63 ,  C08G18/70 ,  C09D151/00 ,  C09D151/08 ,  C09D175/04 ,  C09D175/06 ,  C09J151/08 ,  C09J175/04 ,  C09J175/06 ,  C09K3/10 ,  H01L23/29 ,  H01L23/31 ,  C08L67/00

CPC分类号： C08G18/4288 ,  C08G18/0823 ,  C08G18/631 ,  C08G18/635 ,  C08G18/638 ,  C08G18/706 ,  C09D175/06 ,  C09J175/06

摘要： The present invention relates to an aqueous binder composition containingA) an aqueous solution or dispersion of a water-dilutable organic polyol component containing at least one polyester resin having carboxylate and hydroxyl groups and grafted with vinyl monomers andB) a polyisocyanate component which is emulsified in the aqueous solution or dispersion A), has a viscosity at 23.degree. C. of 50 to 10,000 mPa.s and contains at least one organic polyisocyanate,wherein the binder composition has an NCO/OH equivalent ratio of 0.5:1 to 5:1, based on the isocyanate groups of component B) and the alcoholic hydroxyl groups of component A).The present invention also relates to a process for the production of a coating or sealing composition containing this aqueous binder composition.

摘要翻译： 本发明涉及一种水性粘合剂组合物，其包含A）含有至少一种具有羧酸酯和羟基并与乙烯基单体接枝的聚酯树脂的水可稀释有机多元醇组分的水溶液或分散体，以及B）乳化的多异氰酸酯组分 在水溶液或分散体A）中，在23℃下的粘度为50至10,000mPa.s，并含有至少一种有机多异氰酸酯，其中粘合剂组合物的NCO / OH当量比为0.5:1至5:1。 1，基于组分B）的异氰酸酯基团和组分A）的醇羟基。 本发明还涉及一种生产包含该含水粘合剂组合物的涂料或密封组合物的方法。

公开(公告)号：US5412056A

公开(公告)日：1995-05-02

申请号：US286612

申请日：1994-08-05

申请人： Christian Zwiener ,  Michael Sonntag ,  Dieter Margotte ,  Pedain ,  Harald Blum ,  Volker Schneider

发明人： Christian Zwiener ,  Michael Sonntag ,  Dieter Margotte ,  Pedain ,  Harald Blum ,  Volker Schneider

IPC分类号： C07D263/04 ,  C07D269/02 ,  C08G18/28 ,  C08G18/30 ,  C08G18/32 ,  C08G18/38 ,  C08G18/65 ,  C09D175/00 ,  C09D175/04 ,  C09D175/12 ,  C08G18/34

CPC分类号： C08G18/6535 ,  C08G18/3253 ,  C08G18/3262 ,  C08G18/3296 ,  C08G18/3821 ,  C09D175/12

摘要： A coating composition in which the binding agent is a two-component system containing a) a polyisocyanate component and b) an isocyanate-reactive component and contains b1) specific ester group-containing secondary polyamines, b2) specific moisture-activatable blocked polyamines and b3) optionally other known compounds containing isocyanate-reactive groups, and a process for preparing coated substrates from this coating composition.

摘要翻译： 一种涂料组合物，其中所述粘合剂是包含a）多异氰酸酯组分和b）异氰酸酯反应性组分的双组分体系，并且包含b1）具体的含酯基的仲多胺，b2）特定的可湿气活化的封端多胺和b3 ）任选地其它含有异氰酸酯反应性基团的已知化合物，以及由该涂料组合物制备涂覆的基材的方法。

公开(公告)号：US6166111A

公开(公告)日：2000-12-26

申请号：US504610

申请日：1995-07-20

申请人： Volker Schneider ,  Harald Blum ,  Lothar Kahl ,  Hans-Gunter Schmitz ,  Nusret Yuva

发明人： Volker Schneider ,  Harald Blum ,  Lothar Kahl ,  Hans-Gunter Schmitz ,  Nusret Yuva

IPC分类号： C09D5/02 ,  C09D5/00 ,  C09D155/00 ,  C09D167/06 ,  C09D161/20 ,  C09D175/06

CPC分类号： C09D167/06 ,  C08L2666/36 ,  C08L61/20

摘要： An aqueous binder composition having a reduced tendency to yellow containingA) 20 to 95 wt-% of a water-dilutable organic polyol component that is present in the form of an aqueous solution or dispersion, contains one or more polymer-modified polyester resins which contain carboxylate groups and hydroxyl groups and has been prepared by the polymerization of olefinically unsaturated monomers in the presence of an unsaturated polyester resin that is copolymerized with the monomers andB) 5 to 80 wt-% of at least one heat-activatable cross-linking resin,wherein the percentages are based on the solids contents of components A) and B) and add up to 100%; and their use in heat-curable coating compositions.

摘要翻译： 具有降低的黄色倾向的水性粘合剂组合物含有A）20至95重量％的以水溶液或分散体形式存在的水可稀释的有机多元醇组分含有一种或多种聚合物改性的聚酯树脂， 含有羧酸酯基和羟基，并且通过在与单体共聚的不饱和聚酯树脂的存在下烯属不饱和单体的聚合制备，B）5-80重量％的至少一种可热激活的交联 树脂，其中百分比基于组分A）和B）的固体含量，并加起来至100％; 以及它们在可热固化涂料组合物中的用途。

公开(公告)号：US5516853A

公开(公告)日：1996-05-14

申请号：US424923

申请日：1995-04-19

申请人： Volker Schneider ,  Eberhard Arning ,  Harald Blum ,  Christian Wamprecht

发明人： Volker Schneider ,  Eberhard Arning ,  Harald Blum ,  Christian Wamprecht

IPC分类号： C08F8/08 ,  C08F8/14 ,  C08F8/42 ,  C08F8/44 ,  C08F220/04 ,  C08F220/10 ,  C08F220/14 ,  C08F222/04 ,  C09D133/04 ,  C09D133/12

CPC分类号： C08F8/14 ,  C08F2800/20

摘要： The present invention relates to a process for the production of oxidatively crosslinkable, water-dilutable binders bya) forming a copolymer having intramolecular carboxylic anhydride groups by copolymerizing anhydride-functional compounds, other olefinically unsaturated monomers and 5 to 50% by weight, based on the weight of the olefinically unsaturated monomers used for the production of the copolymers a), of monomers which cannot be homopolymerized under the reaction conditions,b) subsequently reacting by ring-opening esterification at least 50% of the anhydride groups present in the copolymer with one or more unsaturated monohydric alcohols,c) reacting by ring-opening esterification up to 50% of the anhydride groups with monohydric saturated alcohols having a molecular weight of 32 to 200 either before, during or after step b),d) optionally reacting 1 to 70% of the carboxyl groups formed in steps b) and c) with organic epoxide compounds ande) neutralizing at least a portion of the carboxyl groups formed in steps b) and c).The present invention also relates to the binders obtained by this process and to their use in water-dilutable lacquers and coating compositions.

摘要翻译： 本发明涉及通过以下方式制备可氧化交联的水可稀释粘合剂的方法：a）通过以下方式形成具有分子内羧酸酐基团的共聚物：通过将酐官能化合物，其它烯属不饱和单体和5-50重量％ 用于生产共聚物a）的烯属不饱和单体的重量，在反应条件下不能均聚的单体，b）随后通过开环酯化反应使共聚物中存在的至少50％的酸酐基团与 一种或多种不饱和一元醇，c）在步骤b）之前，期间或之后，通过开环酯化至多50％酸酐基与分子量为32至200的一元饱和醇反应，d）任选地使1 至70％的步骤b）和c）中形成的羧基与有机环氧化合物反应，e）中和至少一部分 在步骤b）和c）中形成的羧基。 本发明还涉及通过该方法获得的粘合剂及其在水可稀释漆和涂料组合物中的用途。

公开(公告)号：US5688859A

公开(公告)日：1997-11-18

申请号：US586051

申请日：1996-01-16

申请人： Volker Schneider ,  Harald Blum ,  Armin Sickert

发明人： Volker Schneider ,  Harald Blum ,  Armin Sickert

IPC分类号： C08G18/00 ,  C08G18/08 ,  C08G18/40 ,  C08G18/42 ,  C08G18/62 ,  C09D175/04 ,  C08J3/00 ,  C08G63/48 ,  C08K3/20 ,  C08L75/00

CPC分类号： C08G18/4063 ,  C08G18/0823 ,  C08G18/6254

摘要： The present invention relates to a process for preparing aqueous binders for aqueous coating compositions by reacting a mixture of A) 9.9 to 85 wt. % of a hydroxy- and acid-functional poly(meth)acrylate andB) 14.9 to 90 wt. % of a hydroxy-functional, fatty acid-modified polyester with C) 0.1 to 20 wt. % of a diisocyanate having a molecular weight of 140 to 318, to form urethane groups and then dissolving or dispersing the reaction product in water with prior or simultaneous neutralization of at least a portion of the carboxyl groups present, wherein the sum of the percentages of A) to C) add up to 100. The present invention also relates to the aqueous binders obtained by this process and their use, optionally combined with other oxidatively drying lacquer resins, in air- and/or heat-drying, two-component coating compositions, preferably aqueous polyurethane coating compositions, or in combination with optionally blocked polyisocyanates and/or amino cross-linking agents in aqueous heat-curing coating compositions.

摘要翻译： 本发明涉及一种制备水性涂料组合物的水性粘合剂的方法，该方法是将A）9.9至85wt。 ％的羟基和酸官能的聚（甲基）丙烯酸酯和B）14.9至90wt。 ％的羟基官能的脂肪酸改性聚酯，C）0.1〜20wt。 ％的分子量为140至318的二异氰酸酯，以形成氨基甲酸酯基团，然后将反应产物溶解或分散在水中，同时中和至少一部分存在的羧基，其中总和的百分比 A）至C）加到100上。本发明还涉及通过该方法获得的水性粘合剂及其用途，任选地与其它氧化干燥的漆树脂组合，在空气和/或加热干燥的双组分涂料 组合物，优选水性聚氨酯涂料组合物，或与水性热固化涂料组合物中任选封闭的多异氰酸酯和/或氨基交联剂组合。

公开(公告)号：US5134188A

公开(公告)日：1992-07-28

申请号：US675388

申请日：1991-03-26

申请人： Harald Blum ,  Volker Schneider ,  Peter Hohlein

发明人： Harald Blum ,  Volker Schneider ,  Peter Hohlein

IPC分类号： C08F8/30 ,  C08F8/32 ,  C08F8/44 ,  C08F220/00 ,  C08F220/04 ,  C08F220/10 ,  C08F222/00 ,  C08F222/02 ,  C08F222/38 ,  C08F222/40

CPC分类号： C08F8/44

摘要： The present invention relates to aqueous solutions or dispersions of hydroxy-functional copolymers containing imide structural units corresponding to the formula ##STR1## The present invention also relates to a process for the production of these aqueous solutions or dispersions of hydroxy-functional copolymers containing imide structural units by reacting anhydride-functional and optionally carboxyl-functional copolymers corresponding to the hydroxy-functional copolymers with aminoalcohols and optionally aminocarboxylic acids. In a further embodiment of the process the hydroxy-functional copolymers may be reacted with lactones resulting in ring opening and the formation of ester groups.

摘要翻译： 本发明涉及包含对应于式（I）的酰亚胺结构单元的羟基官能共聚物的水溶液或分散体本发明还涉及一种制备这些羟基官能共聚物的水溶液或分散体的方法 通过将对应于羟基官能团共聚物的酸酐官能团和任选的羧基官能团共聚物与氨基醇和任选的氨基羧酸反应来制备含酰亚胺结构单元。 在该方法的另一个实施方案中，羟基官能共聚物可以与内酯反应，导致开环和酯基的形成。

公开(公告)号：US6146133A

公开(公告)日：2000-11-14

申请号：US147348

申请日：1999-01-29

申请人： Helmut S. Erhard ,  Volker Schneider ,  Paul Korf

发明人： Helmut S. Erhard ,  Volker Schneider ,  Paul Korf

IPC分类号： C02F11/00 ,  C04B7/44 ,  F27B15/00

CPC分类号： C04B7/4423 ,  Y02P40/126

摘要： The present invention concerns a process for the production of cement clinker in rotary kilns with substitution of primary raw materials and fuels by use of residual materials containing minerals and combustible parts with moisture contents of up to about 65% without predrying. The process makes possible a material and/or thermal utilisation of residual materials in the case of saving of the clay and fuel sources and relief of dumping with simultaneous lowering of the emissions, above all NO.sub.x, in the cement rotary kiln.

摘要翻译： PCT No.PCT / EP97 / 02539 Sec。 371日期1999年1月29日第 102（e）1999年1月29日PCT PCT 1997年5月17日PCT公布。 公开号WO97 / 46496 日期1997年12月11日本发明涉及一种用于在回转窑中生产水泥熟料的方法，其中使用含有矿物的残余材料和水分含量高达约65％的可燃部件替代初级原料和燃料，而无需预干燥。 在保存粘土和燃料源的情况下，这种方法可以使材料和/或热利用残留材料成为可能，同时在水泥回转窑中同时降低NOx排放物的排放。

公开(公告)号：US5344851A

公开(公告)日：1994-09-06

申请号：US54931

申请日：1993-04-28

申请人： Wieland Hovestadt ,  Jochen Bruck ,  Volker Schneider

发明人： Wieland Hovestadt ,  Jochen Bruck ,  Volker Schneider

IPC分类号： B29B17/00 ,  C08J11/00 ,  C08J11/04 ,  C09D5/46 ,  C09D7/00 ,  C09D175/00 ,  C09D175/04 ,  C08G18/14

CPC分类号： C08J11/00 ,  C09D7/008 ,  C08J2375/04

摘要： The present invention relates to a process for recovering and recycling the organic binder components accumulating as overspray during the spraying of a solvent-containing, two-component polyurethane lacquer or a solvent-containing, moisture-curing, one-component polyurethane lacquer byi) washing the overspray out of the exhaust air of a coating plant with the aid of an aqueous medium which a) contains in dissolved or dispersed form compounds that exhibit greater reactivity towards isocyanate groups than either water or the isocyanate-reactive groups present in two-component polyurethane lacquers, and b) may contain emulsifiers,ii) isolating the chemically modified overspray formed in step (i) in the form of lacquer sludge by treatment with coagulating agents, which may be present in the aqueous medium,iii) mixing the lacquer sludge, containing fully reacted lacquer constituents, coagulating agents and water, optionally after a portion of the water is removed, with an organic solvent andiv) separating the organic phase accumulating in step iii) from the aqueous phase and insoluble-constituents which may be present and recovering the solution of modified organic binder components dissolved in the organic phase.

摘要翻译： 本发明涉及在喷雾含溶剂的双组分聚氨酯漆或含溶剂的湿固化单组分聚氨酯漆时，通过i）回收和再循环累积为过喷的有机粘合剂组分的方法， 通过水性介质的水性介质，以溶解或分散的形式含有对异氰酸酯基团具有更大反应性的化合物，从而存在于双组分中的水或异氰酸酯反应性基团， 聚氨酯漆，和b）可以含有乳化剂，ii）通过用可能存在于水性介质中的凝结剂进行处理，以漆油污泥的形式分离步骤（i）中形成的化学改性的过喷剂，iii）将漆污泥 ，含有完全反应的漆组分，凝结剂和水，任选地在一部分水被除去后，用有机溶剂 t和iv）将步骤iii）中积聚的有机相与水相和可能存在的不溶组分分离并回收溶解在有机相中的改性有机粘合剂组分的溶液。

公开(公告)号：US08765401B2

公开(公告)日：2014-07-01

申请号：US12341710

申请日：2008-12-22

申请人： Christoph Schmitt ,  Volker Schneider

发明人： Christoph Schmitt ,  Volker Schneider

IPC分类号： G01N1/30 ,  G01N33/48 ,  C12M1/00 ,  B26D7/06 ,  G01N1/06

CPC分类号： G01N1/06 ,  Y10S83/9155 ,  Y10S83/922 ,  Y10T83/207 ,  Y10T83/6508

摘要： A method and apparatus for producing histological sections by means of a microtome are suggested. A histological section of predefined thickness is produced with a microtome from a block comprising a tissue sample. A carrier material is applied with an application apparatus onto the block prior to before production of the histological section. To ensure that the histological sections do not roll up, and to enable improved downline processing of the histological sections as compared with a carrier material embodied in the form of an endless strip and that the carrier material is cut out prior to application to a size and/or a shape that corresponds substantially to the cross-sectional area of the block; and that the cut-out carrier material is then applied onto the block. The suggested apparatus is designed to apply the carrier material onto a histological section to be prepared by a microtome.

摘要翻译： 提出了通过切片机生产组织切片的方法和装置。 使用来自包含组织样品的块的切片机产生预定厚度的组织切片。 载体材料在生成组织切片之前在施用装置上施用施用装置。 为了确保组织切片不会卷起，并且与以环形带形式体现的载体材料相比，能够改进组织切片的下划线加工，并且在施加到尺寸和尺寸之前切割载体材料， /或基本上对应于块的横截面积的形状; 然后将切出的载体材料施加到块上。 所建议的装置被设计成将载体材料施加到由切片机制备的组织切片上。