公开(公告)号：US5331039A

公开(公告)日：1994-07-19

申请号：US973368

申请日：1992-11-09

申请人： Harald Blum ,  Werner Kubitza ,  Joachim Probst ,  Michael Sonntag ,  Volker Schneider

发明人： Harald Blum ,  Werner Kubitza ,  Joachim Probst ,  Michael Sonntag ,  Volker Schneider

IPC分类号： C08G18/00 ,  C08G18/08 ,  C08G18/10 ,  C08G18/40 ,  C08G18/42 ,  C08G18/46 ,  C08G18/70 ,  C08L75/04 ,  C09D175/04 ,  C09D175/06 ,  C09J175/00 ,  C09J175/06 ,  H01L23/29 ,  H01L23/31 ,  C08L67/00

CPC分类号： C09D175/06 ,  C08G18/0819 ,  C08G18/10 ,  C08G18/4063 ,  C08G18/4202 ,  C08G18/706 ,  C08G2170/80

摘要： The present invention relates to a water-based binder composition containingA) an aqueous solution or dispersion of a water-dilutable organic polyol component containing a mixture of at least 5% by weight each of at least two hydroxy-functional polymers selected fromA1) polyester resins containing hydroxyl, urethane and carboxylate groups,A2) polyester resins containing hydroxyl and carboxylate groups, but no urethane or sulfonate groups,A3) polyester resins containing hydroxyl and sulfonate groups and, optionally, carboxylate groups and/or urethane groups,A4) polyacrylate resins containing hydroxyl, carboxylate and/or sulfonate groups,A5) acrylate-grafted polyester resins containing hydroxyl, carboxylate and/or sulfonate groups, andB) a polyisocyanate component which is emulsified in the aqueous solution or dispersion A), has a viscosity at 23.degree. C. of 50 to 10,000 mPa.s and contains at least one organic polyisocyanate,wherein the NCO:OH equivalent ratio, based on the isocyanate groups of component B) and the hydroxyl groups of the polyol component present in A), is 0.2:1 to 5:1.The present invention also relates to a process for the production of a coating or sealing composition containing this aqueous binder composition.

摘要翻译： 本发明涉及水性粘合剂组合物，其包含A）水可稀释有机多元醇组分的水溶液或分散体，其含有至少5重量％的至少两种羟基官能聚合物的混合物，所述羟基官能聚合物选自A1） 含有羟基，氨基甲酸酯和羧酸酯基团的聚酯树脂，A2）含有羟基和羧酸酯基团但不含氨基甲酸酯基或磺酸酯基团的聚酯树脂，A3）含有羟基和磺酸酯基团以及任选的羧酸酯基团和/或氨基甲酸酯基团的聚酯树脂，A4） 含有羟基，羧酸酯和/或磺酸酯基的聚丙烯酸酯树脂，A5）含有羟基，羧酸酯和/或磺酸酯基团的丙烯酸酯接枝的聚酯树脂，和B）在水溶液或分散体A）中乳化的多异氰酸酯组分具有粘度 在23℃下为50至10,000mPa.s并含有至少一种有机多异氰酸酯，其中NCO:OH当量比基于异氰酸酯 组分B）的组分和A）中存在的多元醇组分的羟基为0.2:1至5:1。 本发明还涉及一种生产包含该含水粘合剂组合物的涂料或密封组合物的方法。

公开(公告)号：US5412056A

公开(公告)日：1995-05-02

申请号：US286612

申请日：1994-08-05

申请人： Christian Zwiener ,  Michael Sonntag ,  Dieter Margotte ,  Pedain ,  Harald Blum ,  Volker Schneider

发明人： Christian Zwiener ,  Michael Sonntag ,  Dieter Margotte ,  Pedain ,  Harald Blum ,  Volker Schneider

IPC分类号： C07D263/04 ,  C07D269/02 ,  C08G18/28 ,  C08G18/30 ,  C08G18/32 ,  C08G18/38 ,  C08G18/65 ,  C09D175/00 ,  C09D175/04 ,  C09D175/12 ,  C08G18/34

CPC分类号： C08G18/6535 ,  C08G18/3253 ,  C08G18/3262 ,  C08G18/3296 ,  C08G18/3821 ,  C09D175/12

摘要： A coating composition in which the binding agent is a two-component system containing a) a polyisocyanate component and b) an isocyanate-reactive component and contains b1) specific ester group-containing secondary polyamines, b2) specific moisture-activatable blocked polyamines and b3) optionally other known compounds containing isocyanate-reactive groups, and a process for preparing coated substrates from this coating composition.

摘要翻译： 一种涂料组合物，其中所述粘合剂是包含a）多异氰酸酯组分和b）异氰酸酯反应性组分的双组分体系，并且包含b1）具体的含酯基的仲多胺，b2）特定的可湿气活化的封端多胺和b3 ）任选地其它含有异氰酸酯反应性基团的已知化合物，以及由该涂料组合物制备涂覆的基材的方法。

公开(公告)号：US4645817A

公开(公告)日：1987-02-24

申请号：US722567

申请日：1985-04-11

申请人： Joachim Probst ,  Michael Sonntag ,  Roland Richter ,  Hanns P. Muller

发明人： Joachim Probst ,  Michael Sonntag ,  Roland Richter ,  Hanns P. Muller

IPC分类号： C08G18/00 ,  C07B31/00 ,  C07B41/12 ,  C07C67/00 ,  C08F8/00 ,  C08G18/42 ,  C08G18/48 ,  C08G18/62 ,  C08G65/10 ,  C08G65/26 ,  C08G18/80 ,  C08F20/62 ,  C08G18/16 ,  C08G63/42

CPC分类号： C08G65/2645 ,  C08F8/00 ,  C08G18/6258 ,  C08G65/105 ,  C08G65/2615 ,  C08G65/2669

摘要： The present invention relates to a process for the preparation of alkoxylation products of organic carboxylic acids containing alcoholic hydroxyl groups by the reaction of any organic compounds containing at least one carboxyl group with alkylene oxides in an alkoxylation reaction in the presence of catalysts, characterized in that the catalysts used are phase transfer catalysts selected from the group consisting of(a) tetraalkylammonium or tetraalkylphosphonium halides in which the sum of carbon atoms of the alkyl groups is at least 8,(b) basic alkali metal compounds converted into complexes with crown ethers and(c) complexes of (i) basic alkali metal compounds and (ii) acyclic organic compounds containing at least 5 alkylene oxide units of the formula --R--O-- (R=C.sub.1 -C.sub.4 -alkylene) in the form of one or more polyether chains having at least 3 alkylene oxide units, said compounds having a molecular weight of at least 238 and containing a total of at least 40% by weight of alkylene oxide units of the type indicated in polyether chains having at least 3 alkylene oxide units.The present invention also relates to the use of these alkoxylation products for the production of polyurethanes by reaction with organic polyisocyanates.

摘要翻译： 本发明涉及一种在催化剂存在下通过烷氧基化反应中含有至少一个羧基的任何有机化合物与烯化氧的反应来制备含醇羟基的有机羧酸的烷氧基化产物的方法，其特征在于： 所使用的催化剂是选自（a）四烷基铵或四烷基鏻卤化物的相转移催化剂，其中烷基的碳原子总数至少为8，（b）碱基碱金属化合物与冠醚转化为络合物， （c）碱性碱金属化合物和（ii）含有至少5个式-RO-（R = C 1 -C 4 - 亚烷基）的氧化烯单元的一种或多种聚醚链形式的无环有机化合物的络合物 具有至少3个烯化氧单元，所述化合物的分子量至少为238，并且含有至少40重量％的环氧烷烃 具有至少3个氧化烯单元的聚醚链中所示类型的单元。 本发明还涉及这些烷氧基化产物通过与有机多异氰酸酯反应生产聚氨酯的用途。

公开(公告)号：US4985506A

公开(公告)日：1991-01-15

申请号：US371262

申请日：1989-06-26

申请人： Harald Blum ,  Peter Hohlein ,  Michael Sonntag ,  Wolfgang Wellner

发明人： Harald Blum ,  Peter Hohlein ,  Michael Sonntag ,  Wolfgang Wellner

IPC分类号： C08F8/14 ,  C08F8/44 ,  C08F20/02 ,  C08F22/06 ,  C08F222/00 ,  C08G81/02 ,  C09D133/00 ,  C09D133/04 ,  C09D135/00 ,  C09J133/00 ,  C09J133/04 ,  C09J135/00 ,  C09K3/10

CPC分类号： C08F8/14 ,  C08F8/44 ,  C08F2810/20 ,  C08F2810/30

摘要： Oxidatively cross-linkable, water dilutable binders suitable for lacquers, coating compositions and sealing compounds are modified co-polymers of olefinically unsaturated compounds, having a molecular weight of 6000 to 160,000 and having for each 100 grams of solids content, a total of from60 to 250 milliequivalents of chemically incorporated carboxyl groups, of which from 10 to 100% are neutralized thereby rendering the product dilutable in water andfrom 15 to 50% by weight of chemically incorporated moieties corresponding to the formula--O--RwhereinR represents an olefinically monounsaturated or polyunsaturated aliphatic hydrocarbon having a molecular weight above 166 and containing from 12 to 22 carbon atoms, are prepared by:(a) preparing a co-polymer having a molecular weight from 5000 to 80,000, determined by gel permeation chromatography, and having intramolecular carboxylic acid anhydride units corresponding to the formula ##STR1## and an anhydride equivalent weight of from 240 to 1960 by a radically initiated co-polymerization of olefinically unsaturated dicarboxylic acid anhydrides with other olefinically unsaturated monomers,(b) reacting at least 50% of the acid anhydride units present in the co-polymer from (a) with an unsaturated monohydric alcohol corresponding to the formulaR--OH with anhydride ring opening ester formation, and(c) converting the free carboxyl groups in the reaction product of (b) to an extent of 10 to 100% into carboxylate groups by neutralization of the carboxys with a base.

摘要翻译： 适用于漆，水溶性组合物和密封化合物的可氧化交联的水可稀释粘合剂是烯属不饱和化合物的改性共聚物，其分子量为6000至160,000，并且对于每100克固体含量，总共为60 至250毫当量的化学引入的羧基，其中10至100％被中和，使产物在水中可稀释，和15至50重量％的化学引入部分对应于式-OR，其中R表示烯属单不饱和或 分子量大于166且含有12至22个碳原子的多不饱和脂族烃通过以下方法制备：（a）通过凝胶渗透色谱法测定分子量为5000至80,000，并具有分子内羧酸的共聚物 对应于式“IMAGE”的酸酐单元和2当量的酸酐当量 通过烯属不饱和二羧酸酐与其它烯属不饱和单体的自由引发共聚，（b）使来自（a）的共聚物中存在的至少50％的酸酐单元与不饱和一元醇 对应于具有酸酐开环酯形成的式R-OH，和（c）通过用碱中和羧基将羧酸酯基团将（b）的反应产物中的游离羧基转化成羧酸酯基团 。

公开(公告)号：US06962953B2

公开(公告)日：2005-11-08

申请号：US10174034

申请日：2002-06-18

申请人： Joachim Probst ,  Martin Melchiors ,  Wieland Hovestadt ,  Michael Sonntag ,  Burkhard Köhler ,  Bernhard Jansen

发明人： Joachim Probst ,  Martin Melchiors ,  Wieland Hovestadt ,  Michael Sonntag ,  Burkhard Köhler ,  Bernhard Jansen

IPC分类号： C08L53/00 ,  C09D153/00 ,  C08F2/00 ,  C08L33/14 ,  C08L47/10

CPC分类号： C08L53/00 ,  C09D153/00 ,  Y10T428/31855 ,  C08L2666/04 ,  C08L2666/02

摘要： The present invention relates to heat and storage stable vinyl polymer polyol secondary dispersions containing A) at least one vinyl polymer resin having functional groups selected from hydroxyl, carboxyl and/or sulfonic acid groups and dispersed in a water/solvent mixture in the presence of a neutralizing agent, and B) at least one amphiphilic polymer built up from a hydrophobic and a hydrophilic segment. The invention also relates to a process for the preparation of the vinyl polymer polyol secondary dispersions by preparing vinyl polymer resin A) by polymerizing a mixture of ethylenically unsaturated monomers a) in the presence of an initiator b) in a water/solvent mixture and adding at least one amphiphilic polymer B), then at least partly neutralizing and dispersing the resulting product, optionally after the addition of a further amount of water.

摘要翻译： 本发明涉及储存稳定的乙烯基聚合物多元醇二次分散体，其包含A）至少一种具有选自羟基，羧基和/或磺酸基团的官能团的乙烯基聚合物树脂，并分散在水/溶剂混合物中 中和剂，和B）由疏水和亲水链段构成的至少一种两亲性聚合物。 本发明还涉及通过制备乙烯基聚合物多元醇二次分散体来制备乙烯基聚合物多元醇二次分散体的方法，其通过在引发剂b）存在下在水/溶剂混合物中聚合烯键式不饱和单体a）的混合物并加入 至少一种两亲聚合物B），然后至少部分地中和和分散所得产物，任选地在加入另外量的水之后。

公开(公告)号：US4293661A

公开(公告)日：1981-10-06

申请号：US108349

申请日：1979-12-31

申请人： Joachim Probst ,  Michael Sonntag ,  Gunter Kolb

发明人： Joachim Probst ,  Michael Sonntag ,  Gunter Kolb

IPC分类号： C08F8/00 ,  C08F8/32 ,  C08G18/00 ,  C08G18/62 ,  C08G59/12 ,  C08G59/14 ,  C09D175/04 ,  C08F8/08

CPC分类号： C08G18/6237 ,  C08F8/32 ,  C08F2800/20

摘要： A reaction product of an acrylate resin containing glycidyl groups and secondary mono-amines containing hydroxyl groups, obtained by reacting of said acrylate resin of copolymerized, statistically distributed units of(A) 3 to 30% by weight of the glycidyl ester of (meth)acrylic acid and/or of vinyl glycidyl ether;(B) 0 to 20% by weight of at least a hydroxy C.sub.2 -C.sub.4 alkyl ester of (meth)acrylic acid;(C) 5 to 80% by weight of at least an optionally substituted styrene, methyl methacrylate, (meth)acrylonitrile or any mixture thereof;(D) 5 to 70% by weight of an acrylic acid C.sub.1 -C.sub.12 -alkyl-or of a methacrylic acid C.sub.2 -C.sub.12 -alkyl ester or any mixture thereof; and(E) 0 to 10% by weight of an .alpha.,.beta.-mono-olefinically unsaturated monocarboxylic or dicarboxylic acid containing from 3 to 5 carbon atoms or of a maleic acid C.sub.2 -C.sub.14 -mono ester or any mixture thereof,with at least one secondary mono-amine containing at least one secondary hydroxyl group. The reaction products are useful for crosslinking polyisocyanates.

摘要翻译： 由（A）3〜30重量％的（甲基）丙烯酸缩水甘油酯的共聚统计分布单位的所述丙烯酸酯树脂与所述含有缩水甘油基的丙烯酸酯树脂和含有羟基的二次一元胺反应， 丙烯酸和/或乙烯基缩水甘油醚; （B）0〜20重量％的（甲基）丙烯酸的至少羟基C 2 -C 4烷基酯; （C）5至80重量％的至少任选取代的苯乙烯，甲基丙烯酸甲酯，（甲基）丙烯腈或其任何混合物; （D）5-70重量％的丙烯酸C 1 -C 12烷基或甲基丙烯酸C 2 -C 12烷基酯或其任何混合物; 和（E）0至10重量％的含有3至5个碳原子的α，β-单烯属不饱和单羧酸或二羧酸或马来酸C2-C14-单酯或其任何混合物，至少具有 一个含有至少一个仲羟基的二次单胺。 反应产物可用于交联多异氰酸酯。

公开(公告)号：US4945137A

公开(公告)日：1990-07-31

申请号：US415863

申请日：1989-10-02

申请人： Walter Schafer ,  Hans Rudolph ,  Rolf Dhein ,  Hanns-Peter Muller ,  Michael Sonntag ,  Christian Wamprecht ,  Harald Blum ,  Walter Krauss

发明人： Walter Schafer ,  Hans Rudolph ,  Rolf Dhein ,  Hanns-Peter Muller ,  Michael Sonntag ,  Christian Wamprecht ,  Harald Blum ,  Walter Krauss

IPC分类号： C08L33/06 ,  C03C25/10 ,  C08F8/32 ,  C08K3/28 ,  C08K5/17 ,  C08K5/353 ,  C08K13/02 ,  C08L33/04 ,  C08L35/00 ,  C08L101/00 ,  C08L101/08 ,  C09D7/12 ,  C09D201/08

CPC分类号： C08K5/17 ,  C08F8/32 ,  C08K3/28 ,  C08K5/353

摘要： A binder for a coating composition is a combination of(a) polymers containing intramolecular carboxylic anhydride groups and having an average molecular weight of from 500 to 25,000 and(b) organic compounds containing 4,5-dihydrooxazole groups in a quantity corresponding to an equivalent ratio of carboxylic anhydride groups to 4,5-dihydrooxazole groups of from 0.5:1 to 2:1, and contains from 0.005 to 5% by weight, based on the weight of components (a) and (b), of ammonia, a primary amine or secondary amine.

摘要翻译： 用于涂料组合物的粘合剂是（a）含有分子内羧酸酐基团并且平均分子量为500至25,000的聚合物和（b）含有相当于当量的4,5-二氢恶唑基团的有机化合物的组合 羧酸酐基团与4,5-二氢恶唑基团的比例为0.5:1至2:1，并且基于组分（a）和（b）的重量，含有0.005至5重量％的氨， 伯胺或仲胺。

公开(公告)号：US5089565A

公开(公告)日：1992-02-18

申请号：US358448

申请日：1989-05-30

申请人： Harald Blum ,  Christian Wamprecht ,  Josef Pedain ,  Michael Sonntag

发明人： Harald Blum ,  Christian Wamprecht ,  Josef Pedain ,  Michael Sonntag

IPC分类号： C08L35/00 ,  C08F20/02 ,  C08F22/06 ,  C08K5/35 ,  C09D133/02 ,  C09D135/00

CPC分类号： C09D135/00 ,  C08K5/35

摘要： A moisture-curing binder composition useful in paints and other coating compositions is prepared by mixing or mixing with spontaneous reaction in the absence of moistureA) 30 to 99 parts by weight of at least one compound containing at least two intramolecular carboxylic anhydride groups andB) 1 to 70 parts by weight of organic compounds having blocked amino groups, wherein B)comprises organic compounds containing hydrogen atoms which are reactive to acid anhydride groups and containing bicyclic amide acetal or bicyclic amide groups or both, wherein the ratios of the amounts of the individual components are chosen such that, by taking into account the addition reaction which occurs spontaneously between components A) and B) in the absence of moisture, in the resulting mixture 0.25 to 50 anhydride groups are present per bicyclic amide acetal and bicyclic amide aminal group.

摘要翻译： 用于油漆和其他涂料组合物的湿固化粘合剂组合物通过在不存在水分的情况下与自发反应混合或混合制备A）30至99重量份的至少一种含有至少两个分子内羧酸酐基团的化合物和B ）1至70重量份具有封闭氨基的有机化合物，其中B）包含含有与酸酐基团反应并含有双环酰胺缩醛或双环酰胺基团或两者的氢原子的有机化合物，其中， 选择各个组分使得通过考虑到在不存在水分的情况下在组分A）和B）之间自发发生的加成反应，在所得混合物中，每双酰胺缩醛和双环酰胺缩醛存在0.25至50个酸酐基团 组。

公开(公告)号：US4975493A

公开(公告)日：1990-12-04

申请号：US223803

申请日：1988-07-25

申请人： Harald Blum ,  Josef Pedain ,  Christian Wamprecht ,  Michael Sonntag

发明人： Harald Blum ,  Josef Pedain ,  Christian Wamprecht ,  Michael Sonntag

IPC分类号： C08L23/00 ,  C08F8/32 ,  C08K5/35 ,  C09D133/04 ,  C09D135/00

CPC分类号： C08K5/35 ,  C08F8/32 ,  C09D135/00 ,  C08F2800/20

摘要： A moisture-hardening binder composition for lacquer of coating compositions is prepared by mixing(A) 50 to 97 parts by weight of copolymers of maleic anhydride with olefinically unsaturated monomers, said copolymers containing succinic anhydride units and having molecular weights Mw of 1,500 to 75,000 with(B) 3 to 50 parts by weight oxazolanes having a molecular weight Mw of 87 to 10,000,the quantitative ratios of (A) to (B) being such that the composition contains 0.25 to 10 anhydride groups for every oxazolane group,wherein component (A) consists essentially of copolymers of(a) 4.5 to 45 parts by weight of maleic anhydride,(b) 5 to 80 parts by weight of monomers of the formulae ##STR1## or both, and (c) 15 to 92 parts by weight of monomers of the formula ##STR2## wherein, R.sub.1 and R.sub.4 is each, independent of the other, an aliphatic or cycloaliphatic C.sub.1 -C.sub.12 hydrocarbon radical with or without oxygen, sulfur or nitrogen as a heteratom, R.sub.2 is hydrogen, methyl, ethyl, chlorine or fluorine,R.sub.3 is a C.sub.2 -C.sub.15 aliphatic hydrocarbon radical, a C.sub.5 -C.sub.10 cycloaliphatic hydrocarbon radical, a C.sub.7 -C.sub.18 araliphatic hydrocarbon radical, a C.sub.6 -C.sub.12 aromatic hydrocarbon radical, chlorine, fluorine, nitrile or a C.sub.2 -C.sub.18 hydrocarbon radical containing one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen in the form of ether, ester, amide, urethane, urea, thioester, oxirane, ketone, lactam or lactone groups.

摘要翻译： 通过混合（A）50至97重量份的马来酸酐与烯属不饱和单体的共聚物，所述共聚物含有琥珀酸酐单元并具有1500至75,000的分子量Mw，制备用于涂料组合物漆的湿润硬化粘合剂组合物， （B）3〜50重量份的分子量Mw为87〜10,000的恶唑烷，（A）〜（B）的定量比为每个恶唑烷基组成含有0.25〜10个酸酐基，其中组分（ A）基本上由（a）4.5至45重量份马来酸酐的共聚物组成，（b）5-80重量份式（IMAGE）或两者的单体，和（c）15至92重量份 具有下式的单体：其中，R 1和R 4各自独立地为具有或不具有氧，硫或氮作为杂原子的脂族或脂环族C 1 -C 12烃基，R 2为氢，甲基，乙基， 氯或氟 ne，R 3是C 2 -C 15脂族烃基，C 5 -C 10脂环族烃基，C 7 -C 18芳脂族烃基，C 6 -C 12芳烃基，氯，氟，腈或含有一个的C 2 -C 18烃基 或更多选自醚，酯，酰胺，氨基甲酸酯，脲，硫酯，环氧乙烷，酮，内酰胺或内酯基团的氧，硫和氮的杂原子。

公开(公告)号：US06423816B1

公开(公告)日：2002-07-23

申请号：US08583167

申请日：1996-01-04

申请人： Christian Wamprecht ,  Michael Sonntag

发明人： Christian Wamprecht ,  Michael Sonntag

IPC分类号： C08G6312

CPC分类号： C09D175/14 ,  C08G18/68 ,  C08G63/52 ,  C09D167/06 ,  C08L2666/36

摘要： The present invention relates to polyester polyols having a hydroxyl number of 60 to 400, which are esterification products of a) an alcohol component containing one or more aliphatic or cycloaliphatic alcohols having at least 3 hydroxyl groups and 3 to 8 carbon atoms with b) a carboxylic acid component containing itaconic acid, maleic acid, their anhydrides and/or fumaric acid, provided that at least 10 mole % of either component a) or component b) is an aliphatic or cycloaliphatic, saturated or unsaturated monoalcohol or monocarboxylic acid having 1 to 18 carbon atoms. The present invention also relates to two-component polyurethane coating compositions containing these polyester polyols and lacquer polyisocyanates as the binder and to their use for coating substrates, in particular automotive substrates.

摘要翻译： 本发明涉及羟基数为60〜400的聚酯多元醇，它们是a）含有一个或多个具有至少3个羟基和3至8个碳原子的脂族或脂环族醇的醇组分与b）羧酸的酯化产物 含有衣康酸的组分，马来酸，它们的酸酐和/或富马酸，条件是至少10摩尔％的组分a）或组分b）是具有1至18个碳原子的脂族或脂环族饱和或不饱和的一元醇或一元羧酸 原子 本发明还涉及含有这些聚酯多元醇和漆多异氰酸酯作为粘合剂的双组分聚氨酯涂料组合物，以及它们用于涂覆基材，特别是汽车基材的用途。