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    AMMONIA DECOMPOSITION CATALYST
    3.
    发明申请
    AMMONIA DECOMPOSITION CATALYST 审中-公开
    氨基酸分解催化剂

    公开(公告)号：US20110306489A1

    公开(公告)日：2011-12-15

    申请号：US13203376

    申请日：2010-02-18

    申请人： Susumu Hikazudani ,  Takuma Mori ,  Chikashi Inazumi ,  Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Hironobu Kumagai

    发明人： Susumu Hikazudani ,  Takuma Mori ,  Chikashi Inazumi ,  Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Hironobu Kumagai

    IPC分类号： B01J21/18

    CPC分类号： C01B3/047 ,  B01J21/18 ,  B01J21/185 ,  B01J23/462 ,  B01J23/745 ,  B01J35/0046 ,  B01J35/0053 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/086 ,  B01J37/18 ,  B82Y30/00 ,  C08G14/06 ,  C08L61/04 ,  Y02E60/364

    摘要： Disclosed is an ammonia decomposition catalyst which is obtained by heat-treating a complex at a temperature of 360° C. to 900° C. in a reducing atmosphere, wherein the complex containing a polymer having a molecular weight of 1,000 to 500,000 represented by the formula [I], a transition metal coordinated with the polymer, and an activated carbon or a carbon nanotube added thereto. In a case of using the carbon nanotube, an alkali metal compound or an alkaline earth metal compound is added to the heat-treated complex. R1 represents H or hydrocarbon having 1 to 10 carbon atoms, R2 and R3 each represent H, halogen, nitro, acyl, ester, carboxyl, formyl, nitrile, sulfone, aryl, or alkyl group having 1 to 15 carbon atoms, X and Y each represent H or OH, Z represents CH or N, R4 and R5 each represent H, OH, ether, amino, aryl, or alkyl group having 1 to 15 carbon atoms, x represents a real number of 1 to 2, y represents a real number of 1 to 3, and n represents a real number of 2 to 120. The amount of the transition metal deposited on the catalyst can be increased without deteriorating the dispersion of the metal, so that the amount of the catalyst required to obtain a desired activity can be reduced.

    摘要翻译： 公开了一种氨还原催化剂，其通过在还原气氛中在360℃至900℃的温度下热处理络合物获得，其中所述络合物含有分子量为1,000至500,000的聚合物，其由 式[I]，与聚合物配位的过渡金属，和加入其中的活性炭或碳纳米管。 在使用碳纳米管的情况下，向热处理复合体中添加碱金属化合物或碱土金属化合物。 R1表示H或碳原子数1〜10的烃，R2和R3各自表示H，卤素，硝基，酰基，酯，羧基，甲酰基，腈，砜，芳基或碳原子数1〜15的烷基，X和Y 各自表示H或OH，Z表示CH或N，R 4和R 5各自表示H，OH，醚，氨基，芳基或具有1至15个碳原子的烷基，x表示1至2的实数，y表示 实数1〜3，n表示2〜120的实数。可以提高沉积在催化剂上的过渡金属的量，而不会使金属的分散性恶化，从而获得所需催化剂的量 可以减少所需的活动。

    AMMONIA OXIDATION/DECOMPOSITION CATALYST
    5.
    发明申请
    AMMONIA OXIDATION/DECOMPOSITION CATALYST 审中-公开
    氨基氧化/分解催化剂

    公开(公告)号：US20130288890A1

    公开(公告)日：2013-10-31

    申请号：US13883302

    申请日：2011-11-09

    申请人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    发明人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    IPC分类号： B01J23/83 ,  B01J23/34 ,  B01J23/28 ,  B01J23/63

    CPC分类号： C01B3/047 ,  B01J23/28 ,  B01J23/34 ,  B01J23/63 ,  B01J23/83 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/038 ,  B01J37/18 ,  H01M8/0606 ,  H01M8/222 ,  Y02E60/364

    摘要： Provided is an ammonia oxidation/decomposition catalyst which can decrease the reduction temperature of a support, which is required for the catalyst to have a property of being activated at room temperature, and also can render a property of being activated at a temperature lower than room temperature. The ammonia oxidation/decomposition catalyst of the present invention is an ammonia oxidation/decomposition catalyst, comprising: a catalyst support composed of a composite oxide of cerium oxide and zirconium oxide; and at least one metal selected from the group consisting of metals of group 6A, group 7A, group 8, and group 1B as a catalytically active metal deposited thereon, characterized in that the molar concentration of zirconium oxide in the catalyst support is from 10 to 90%.

    摘要翻译： 提供了能够降低载体的还原温度的氨氧化/分解催化剂，催化剂具有在室温下被活化的性质，并且还可以使其在低于室温的温度下活化 温度。 本发明的氨氧化/分解催化剂是氨氧化/分解催化剂，包括：由氧化铈和氧化锆的复合氧化物构成的催化剂载体; 和选自6A，7A，8族和1B族金属中的至少一种金属作为沉积在其上的催化活性金属，其特征在于催化剂载体中氧化锆的摩尔浓度为10〜 90％。

    AMMONIA OXIDATION/DECOMPOSITION CATALYST
    6.
    发明申请
    AMMONIA OXIDATION/DECOMPOSITION CATALYST 有权
    氨基氧化/分解催化剂

    公开(公告)号：US20130156687A1

    公开(公告)日：2013-06-20

    申请号：US13819070

    申请日：2010-08-31

    申请人： Sadao Araki ,  Susumu Hikazudani ,  Takuma Mori ,  Akira Taniguchi

    发明人： Sadao Araki ,  Susumu Hikazudani ,  Takuma Mori ,  Akira Taniguchi

    IPC分类号： C01B3/04

    CPC分类号： C01B3/047 ,  B01J23/002 ,  B01J23/10 ,  B01J23/14 ,  B01J23/22 ,  B01J23/26 ,  B01J23/34 ,  B01J23/63 ,  B01J23/66 ,  B01J23/83 ,  B01J37/0201 ,  B01J37/031 ,  B01J2523/00 ,  Y02E60/364 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/22

    摘要： The present invention provides an ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon. By bringing the ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon into contact with ammonia and air at ordinary temperature, the support in a reduced state reacts with oxygen to generate oxidation heat, and the temperature of the catalyst layer is increased in a moment. Once the temperature of the catalyst layer is increased to a temperature at which ammonia and oxygen react with each other, the ammonia oxidation reaction proceeds autonomously after that. The heat generated in this exothermic reaction is used in the course of decomposing ammonia in the presence of the catalytically active metal, thereby producing hydrogen.

    摘要翻译： 本发明提供一种氨氧化/分解催化剂，其包含由可氧化还原性金属氧化物和负载在其上的催化活性金属构成的载体。 通过将包含由可氧化还原性金属氧化物构成的载体和负载有催化活性金属的氨氧化/分解催化剂在常温下与氨和空气接触，还原态的载体与氧气反应产生氧化热， 并且催化剂层的温度暂时增加。 一旦催化剂层的温度升高到氨和氧彼此反应的温度，氨氧化反应就自动进行。 在该放热反应中产生的热在催化活性金属存在下分解氨的过程中使用，从而产生氢。

    Method for synthesizing ammonia
    7.
    发明授权
    Method for synthesizing ammonia 有权
    合成氨的方法

    公开(公告)号：US08801915B2

    公开(公告)日：2014-08-12

    申请号：US13809677

    申请日：2011-06-03

    申请人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    发明人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    IPC分类号： C01C1/02

    CPC分类号： C01C1/0411 ,  B01J35/004 ,  C25B1/003 ,  Y02E60/368

    摘要： In the ammonia synthesis method, an anode and a cathode are arranged in an electrolyte phase at a predetermined interval; water (H2O) is supplied to an anode zone and light is radiated so that water is decomposed by a photoabsorption reaction to generate protons (H+), electrons (e−), and an oxygen gas (O2); a nitrogen gas (N2 ) is supplied to a cathode zone, and the electrons (e−) generated in the anode zone are allowed to transfer to the cathode zone through a lead, thereby generating N3− in the cathode zone; and ammonia (NH3 ) is synthesized through the reaction between the protons (H+) that have moved toward the cathode zone from the anode zone in the electrolyte phase and N3−.

    摘要翻译： 在氨合成方法中，阳极和阴极以预定间隔排列在电解质相中; 将水（H 2 O）供给到阳极区域，并且照射光，使得水通过光吸收反应分解以产生质子（H +），电子（e-）和氧气（O 2）; 向阴极区供给氮气（N2），通过引线使在阳极区域产生的电子（e-）转移到阴极区，从而在阴极区域产生N 3 - 并且通过在电解质相中的阳极区域和N3-之间已经向阴极区移动的质子（H +）之间的反应合成氨（NH 3）。

    METHOD FOR SYNTHESIZING AMMONIA
    8.
    发明申请
    METHOD FOR SYNTHESIZING AMMONIA 有权
    合成氨的方法

    公开(公告)号：US20130112568A1

    公开(公告)日：2013-05-09

    申请号：US13809677

    申请日：2011-06-03

    申请人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    发明人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    IPC分类号： C01C1/04

    CPC分类号： C01C1/0411 ,  B01J35/004 ,  C25B1/003 ,  Y02E60/368

    摘要： In the ammonia synthesis method, an anode and a cathode are arranged in an electrolyte phase at a predetermined interval; water (H2O) is supplied to an anode zone and light is radiated so that water is decomposed by a photoabsorption reaction to generate protons (H+), electrons (e), and an oxygen gas (O2); a nitrogen gas (N2) is supplied to a cathode zone, and the electrons (e−) generated in the anode zone are allowed to transfer to the cathode zone through a lead, thereby generating N3− in the cathode zone; and ammonia (NH3) is synthesized through the reaction between the protons (H+) that have moved toward the cathode zone from the anode zone in the electrolyte phase and N3−.

    摘要翻译： 在氨合成方法中，阳极和阴极以预定间隔排列在电解质相中; 将水（H 2 O）供给到阳极区域，并且照射光，使得水通过光吸收反应分解以产生质子（H +），电子（e）和氧气（O 2）; 向阴极区供给氮气（N2），通过引线使在阳极区域产生的电子（e-）转移到阴极区，从而在阴极区域产生N 3 - 并且通过在电解质相中的阳极区域和N3-之间已经向阴极区移动的质子（H +）之间的反应合成氨（NH 3）。

    Method of producing hydrogen from ammonia
    9.
    发明授权
    Method of producing hydrogen from ammonia 失效
    从氨生产氢气的方法

    公开(公告)号：US08722011B2

    公开(公告)日：2014-05-13

    申请号：US13822041

    申请日：2011-07-06

    申请人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    发明人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    IPC分类号： H01M8/06 ,  B01J7/00 ,  C01B3/04 ,  F02B43/10

    CPC分类号： C01B3/06 ,  C01B3/047 ,  C01B21/26 ,  Y02E60/364 ,  Y02P20/129

    摘要： In a method by which hydrogen supplied as a combustion aid to an ammonia combustion engine is produced from ammonia, the filling amount of a decomposition catalyst in an ammonia decomposition apparatus is reduced. The method includes an ammonia decomposition apparatus that produces hydrogen as a combustion aid and an ammonia oxidation apparatus that allows a part of introduced ammonia to react with oxygen for combustion by action of an oxidation catalyst in order to supply the heat needed for the ammonia decomposition reaction, wherein the amount of ammonia and the amount of air introduced into the oxidation apparatus are controlled in accordance with the entrance temperature of an ammonia oxidation catalyst layer, so as to set the ammonia decomposition ratio in the ammonia decomposition apparatus to be 40 to 60% at all times.

    摘要翻译： 在由氨制造作为燃烧助燃剂的氢气供给的氢的方法中，氨分解装置中的分解催化剂的填充量减少。 该方法包括产生作为燃烧助剂的氢的氨分解装置和氨氧化装置，其允许一部分引入的氨与氧气反应以通过氧化催化剂的作用进行燃烧以提供氨分解反应所需的热量 其中，根据氨氧化催化剂层的入口温度来控制氨的量和引入氧化装置的空气量，以将氨分解装置中的氨分解比设定为40〜60％ 每时每刻。

    METHOD OF PRODUCING HYDROGEN FROM AMMONIA
    10.
    发明申请
    METHOD OF PRODUCING HYDROGEN FROM AMMONIA 失效
    从氨生产氢的方法

    公开(公告)号：US20130266506A1

    公开(公告)日：2013-10-10

    申请号：US13822041

    申请日：2011-07-06

    申请人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    发明人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

    IPC分类号： C01B3/06

    CPC分类号： C01B3/06 ,  C01B3/047 ,  C01B21/26 ,  Y02E60/364 ,  Y02P20/129

    摘要： In a method by which hydrogen supplied as a combustion aid to an ammonia combustion engine is produced from ammonia, the filling amount of a decomposition catalyst in an ammonia decomposition apparatus is reduced. The method includes an ammonia decomposition apparatus that produces hydrogen as a combustion aid and an ammonia oxidation apparatus that allows a part of introduced ammonia to react with oxygen for combustion by action of an oxidation catalyst in order to supply the heat needed for the ammonia decomposition reaction, wherein the amount of ammonia and the amount of air introduced into the oxidation apparatus are controlled in accordance with the entrance temperature of an ammonia oxidation catalyst layer, so as to set the ammonia decomposition ratio in the ammonia decomposition apparatus to be 40 to 60% at all times.

    摘要翻译： 在由氨制造作为燃烧助燃剂的氢气供给的氢的方法中，氨分解装置中的分解催化剂的填充量减少。 该方法包括产生作为燃烧助剂的氢的氨分解装置和氨氧化装置，其允许一部分引入的氨与氧气反应以通过氧化催化剂的作用进行燃烧以提供氨分解反应所需的热量 其中，根据氨氧化催化剂层的入口温度来控制氨的量和引入氧化装置的空气量，以将氨分解装置中的氨分解比设定为40〜60％ 每时每刻。