Nanopastes for use as patterning compositions
    1.
    发明授权
    Nanopastes for use as patterning compositions 失效
    用作图案化组合物的纳米磷

    公开(公告)号:US07217502B2

    公开(公告)日:2007-05-15

    申请号:US11444740

    申请日:2006-06-01

    IPC分类号: G03C5/00

    摘要: The present invention provides methods of imagewise exposing a thermally sensitive composition formed from a nanopaste comprising inorganic nanoparticles, a carrier, and preferably certain polymeric binders. The composition has been applied to a substrate and treated to improve adhesion. Exposure affects the solubility of exposed portions of the applied and treated layer relative to unexposed portions of the applied layer. The imaged layer is then developed on-press with a fountain solution, lithographic ink, or both, to remove the exposed portions or unexposed portions of the layer to form an image in a printing plate.

    摘要翻译: 本发明提供了成像曝光由包含无机纳米颗粒,载体和优选某些聚合物粘合剂的纳米糊料形成的热敏组合物的方法。 将该组合物施用于基材并进行处理以提高粘合性。 暴露影响施加和处理的层相对于施加层的未曝光部分的暴露部分的溶解度。 然后,利用润版液,平版印刷油墨或两者在印刷机上显影成像层,以去除该层的曝光部分或未曝光部分,以在印版中形成图像。

    Infrared-sensitive composition containing a metallocene derivative
    2.
    发明授权
    Infrared-sensitive composition containing a metallocene derivative 失效
    含有茂金属衍生物的红外敏感组合物

    公开(公告)号:US06936384B2

    公开(公告)日:2005-08-30

    申请号:US10210508

    申请日:2002-08-01

    摘要: The present invention provides an initiator system including an infrared-absorbing compound that exhibits an electronic transition band in the near-infrared region, an initiator, and a metallocene compound. Upon exposure to infrared radiation, the initiator system is capable of producing radicals sufficient to initiate a photopolymerization reaction. Suitable infrared-absorbing compounds include indocyanine dyes, for example. Trihalomethyl triazine compounds and onium compounds are suitable initiators. Suitable metallocene compounds include ferrocenes and titanocenes. The present invention also provides an infrared-sensitive composition including an ethylenically unsaturated polymerizable component, an infrared-absorbing compound that exhibits an electronic transition band in the near-infrared region, an initiator, and a metallocene compound. The infrared-sensitive composition provides improved photospeed and sensitivity in some embodiments. A printing plate precursor including an infrared-sensitive coating is also provided. The printing plate precursor exhibits enhanced shelf life in some embodiments. A method of making a printing plate precursor and a method for making a printable lithographic printing plate are further provided by the invention.

    摘要翻译: 本发明提供了包含在近红外区域呈现电子跃迁带的红外线吸收性化合物,引发剂和金属茂化合物的引发剂体系。 在暴露于红外线辐射下,引发剂体系能够产生足以引发光聚合反应的自由基。 合适的红外线吸收化合物例如包括靛蓝染料。 三卤甲基三嗪化合物和鎓化合物是合适的引发剂。 合适的茂金属化合物包括二茂铁和二茂钛。 本发明还提供了包含烯属不饱和可聚合组分,在近红外区域表现出电子跃迁带的红外线吸收化合物,引发剂和茂金属化合物的红外线敏感性组合物。 在一些实施方案中,红外敏感组合物提供改进的感光速度和灵敏度。 还提供了包括红外线感光涂层的印版前体。 在一些实施方案中,印版前体表现出增强的保存期限。 本发明还提供了一种制备印版前体的方法和制备可印版的平版印刷版的方法。

    Preparation of solvent-resistant binder for an imageable element
    7.
    发明授权
    Preparation of solvent-resistant binder for an imageable element 有权
    制备用于可成像元件的耐溶剂粘合剂

    公开(公告)号:US07172850B2

    公开(公告)日:2007-02-06

    申请号:US10891727

    申请日:2004-07-15

    摘要: The present invention provides an imageable element including a lithographic substrate and an imageable layer disposed on the substrate. The imageable layer includes a radically polymerizable component, an initiator system capable of generating radicals sufficient to initiate a polymerization reaction upon exposure to imaging radiation, and a polymeric binder having a hydrophobic backbone and including both constitutional units having a pendant cyano group attached directly to the hydrophobic backbone, and constitutional units having a pendant group including a hydrophilic poly(alkylene oxide) segment. The invention also provides a method for preparing a suitable polymeric binder. The method comprises contacting a combination of co-monomers in a solvent mixture consisting essentially of a (C1–C6) alkanol and water.

    摘要翻译: 本发明提供一种可成像元件,包括平版印刷基板和设置在基板上的可成像层。 可成像层包括可自由基聚合的组分,能够产生足以在暴露于成像辐射时引发聚合反应的自由基的引发剂体系,以及具有疏水骨架的聚合物粘合剂,并且包括具有氰基侧基的两个结构单元直接连接到 疏水骨架和具有包括亲水性聚(环氧烷)链段)侧基的结构单元。 本发明还提供了制备合适的聚合物粘合剂的方法。 该方法包括将基本上由(C 1 -C 12 -C 6)烷醇组成的溶剂混合物中的共聚单体的组合与水接触。