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    Process for oxidizing alkylaromatic compounds
    1.
    发明授权
    Process for oxidizing alkylaromatic compounds 失效
    氧化烷基芳族化合物的方法

    公开(公告)号：US07906686B2

    公开(公告)日：2011-03-15

    申请号：US12532388

    申请日：2008-04-07

    申请人： Helge Jaensch ,  Jihad M. Dakka ,  Francisco M. Benitez ,  Ulrich Kortz ,  Ryan Matthew Richards

    发明人： Helge Jaensch ,  Jihad M. Dakka ,  Francisco M. Benitez ,  Ulrich Kortz ,  Ryan Matthew Richards

    IPC分类号： C07C45/53 ,  C07C409/00 ,  C07C37/00

    CPC分类号： C07C409/08 ,  B01J27/1817 ,  B01J27/188 ,  C07C37/06 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/10 ,  C07C409/14 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/403 ,  C07C39/04

    摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.

    摘要翻译： 在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示氢或具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成环状 具有4至10个碳原子的基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与氧在催化剂的存在下与 产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义，并且其中多金属氧酸盐包括被至少一个其它过渡金属取代的聚氧钨酸酯。

    Process for Oxidizing Alkylaromatic Compounds
    2.
    发明申请
    Process for Oxidizing Alkylaromatic Compounds 失效
    氧化烷基芳族化合物的方法

    公开(公告)号：US20100185016A1

    公开(公告)日：2010-07-22

    申请号：US12532388

    申请日：2008-04-07

    申请人： Helge Jaensch ,  Jihad M. Dakka ,  Francisco M. Benitez ,  Ulrich Kortz ,  Ryan Matthew Richards

    发明人： Helge Jaensch ,  Jihad M. Dakka ,  Francisco M. Benitez ,  Ulrich Kortz ,  Ryan Matthew Richards

    IPC分类号： C07C45/00 ,  C07C409/08

    CPC分类号： C07C409/08 ,  B01J27/1817 ,  B01J27/188 ,  C07C37/06 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/10 ,  C07C409/14 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/403 ,  C07C39/04

    摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.

    摘要翻译： 在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示氢或具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成环状 具有4至10个碳原子的基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与氧在催化剂的存在下与 产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义，并且其中多金属氧酸盐包括被至少一个其它过渡金属取代的聚氧钨酸酯。

    Olefin oligomerization to produce hydrocarbon compositions useful as fuels
    8.
    发明申请
    Olefin oligomerization to produce hydrocarbon compositions useful as fuels 有权
    烯烃低聚产生用作燃料的烃组合物

    公开(公告)号：US20060217580A1

    公开(公告)日：2006-09-28

    申请号：US11342385

    申请日：2006-01-27

    申请人： Keith Kuechler ,  Stephen Brown ,  Helge Jaensch ,  Georges Mathys ,  Shifang Luo ,  Jane Cheng

    发明人： Keith Kuechler ,  Stephen Brown ,  Helge Jaensch ,  Georges Mathys ,  Shifang Luo ,  Jane Cheng

    IPC分类号： C07C2/02

    CPC分类号： C10G50/00 ,  C09K8/32

    摘要： In a process for producing a hydrocarbon composition, a feed comprising at least one C3 to C8 olefin and an olefinic recycle stream rich in C9− hydrocarbons is contacted with a crystalline molecular sieve catalyst having an average crystal size no greater than 0.05 micron and an alpha value between about 100 and about 600 in at least one reaction zone under olefin oligomerization conditions including an inlet temperature between about 150° C. and about 350° C., a pressure of at least 2,860 kPa and a recycle to feed weight ratio of about 0.1 to about 3.0. The contacting produces an oligomerization effluent stream, which is separated into at least a hydrocarbon product stream rich in C9+ hydrocarbons and the olefinic recycle stream.

    摘要翻译： 在制备烃组合物的方法中，包含至少一种C 3至C 8 O烯烃的进料和富含C 9 N的烯烃循环料流 烃类与结晶分子筛催化剂接触，其结晶尺寸不大于0.05微米，在至少一个反应区域的α值为约100至约600之间，在烯烃低聚条件下，包括入口温度约为150℃ 约350℃，压力至少为2860kPa，循环至饲料重量比为约0.1至约3.0。 接触产生低聚流出物流，其被分离成至少一种富含C 9+烃的烃产物流和烯烃再循环流。

    Process For Preparing N-Substituted Cyclic Imides
    10.
    发明申请
    Process For Preparing N-Substituted Cyclic Imides 失效
    N-取代的环状酰亚胺的制备方法

    公开(公告)号：US20110319635A1

    公开(公告)日：2011-12-29

    申请号：US13202128

    申请日：2010-02-01

    申请人： Helge Jaensch

    发明人： Helge Jaensch

    IPC分类号： C07D209/48

    CPC分类号： C07D209/48

    摘要： In a process for making an N-substituted phthalimide compound, an amine is contacted with a carboxylic acid anhydride and allowed to react in an aqueous solution at a pH of about 2 to about 6. Optionally, the reactants are combined with an acid to lower the pH of the reaction solution wherein the lowering of the pH optimizes the yield of the desired N-substituted phthalimide product. The N-substituted phthalimide may be, for example, N-hydroxyphthalimide, and the reactants may be phthalic anhydride and hydroxylamine or a salt thereof. The N-substituted phthalimide compound is useful for, among other things, the oxidation of various hydrocarbons.

    摘要翻译： 在制备N-取代的邻苯二甲酰亚胺化合物的方法中，胺与羧酸酐接触，并使其在约2至约6的pH下在水溶液中反应。任选地，将反应物与酸组合以降低 其中降低pH的反应溶液的pH优化所需N-取代的邻苯二甲酰亚胺产物的产率。 N-取代邻苯二甲酰亚胺可以是例如N-羟基邻苯二甲酰亚胺，反应物可以是邻苯二甲酸酐和羟胺或其盐。 N-取代的邻苯二甲酰亚胺化合物尤其可用于各种烃的氧化。