利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

122 条记录 (耗时 0.039 秒)

    Substituted thioureas, isothioureas and carbodiimides
    4.
    发明授权
    Substituted thioureas, isothioureas and carbodiimides 失效
    取代硫脲，异硫脲和碳二亚胺

    公开(公告)号：US4888348A

    公开(公告)日：1989-12-19

    申请号：US91157

    申请日：1987-08-28

    申请人： Josef Ehrenfreund ,  Manfred Boger ,  Odd Kristiansen ,  Jozef Drabek ,  Haukur Kristinsson

    发明人： Josef Ehrenfreund ,  Manfred Boger ,  Odd Kristiansen ,  Jozef Drabek ,  Haukur Kristinsson

    IPC分类号： A01N47/30 ,  A01N47/32 ,  A01N47/40 ,  A01N47/42 ,  C07D207/34 ,  C07D209/32 ,  C07D231/20 ,  C07D233/70 ,  C07D235/26 ,  C07D249/12 ,  C07D257/04 ,  C07D263/38 ,  C07D263/58 ,  C07D271/10 ,  C07D271/113 ,  C07D277/20 ,  C07D277/34 ,  C07D277/68 ,  C07D285/08 ,  C07D285/12 ,  C07D285/13 ,  C07D307/58 ,  C07D333/32 ,  C07D333/34

    CPC分类号： C07D271/113 ,  A01N47/30 ,  A01N47/32 ,  A01N47/40 ,  A01N47/42 ,  C07D233/70 ,  C07D249/12 ,  C07D277/34 ,  C07D277/68 ,  C07D285/08 ,  C07D285/13

    摘要： The invention relates to novel substituted phenylthioureas, phenylisothioureas and phenylcarbodiimides of formula I ##STR1## wherein Z is ##STR2## or --N.dbd.C.dbd.N--; R.sub.1 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.10 alkenyl, C.sub.3 -C.sub.10 alkynyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.3 alkyl substituted by 1 or 2 C.sub.3 -C.sub.6 cycloalkyl radicals, or is alkoxyalkyl containing a total of 3 to 10 carbon atoms, halogen-substituted C.sub.1 -C.sub.12 alkyl, polycyclic C.sub.7 -C.sub.10 cycloalkyl, or phenyl(C.sub.1 -C.sub.5)alkyl which may be substituted in the phenyl moiety by 1 or 2 identical or different members selected from the group consisting of halogen, methoxy, ethoxy and C.sub.1 -C.sub.5 alkyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.3 is C.sub.1 -C.sub.5 alkyl or C.sub.3 -C.sub.6 cycloalkyl,R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sub.5 is a 5-membered heterocyclic radical containing 1 to 4 hetero atoms selected from the group consisting of N, O and S, which radical may be substituted at the carbon or nitrogen atoms by 1 to 3 of the substituents R.sub.6, R.sub.7 and R.sub.8, or is a 5-membered heterocyclic radical which may be fused with benzene nuclei and which contains 1 or 2 hetero atoms selected from the group consisting of N, O and S and can be substituted at the carbon or nitrogen atoms by 1 to 3 of the substituents R.sub.6, R.sub.7 and R.sub.8,R.sub.6 and R.sub.7 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, halogen-substituted C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy; halogen-substituted C.sub.1 -C.sub.4 alkoxy, phenyl, or C.sub.1 -C.sub.4 alkylthio,R.sub.8 is hydrogen or C.sub.1 -C.sub.4 alkyl, andR.sub.9 is C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.3 -C.sub.4 alkynyl, alkoxyalkyl containing a total of 10 carbon atoms, or alkylthioalkyl containing a total of 10 carbon atomsand to the salts thereof with acids and bases. The invention further relates to the preparation of these compounds and to the use thereof in pest control, and to novel intermediates.

    摘要翻译： 本发明涉及式I的新的取代的苯基硫脲，苯基异硫脲和苯基碳二亚胺其中Z是或-N = C = N-; R 1是C 1 -C 12烷基，C 3 -C 10烯基，C 3 -C 10炔基，C 3 -C 8环烷基，被1或2个C 3 -C 6环烷基取代的C 1 -C 3烷基，或者是含有总共3至10个碳原子的烷氧基烷基，卤素取代的C 1 -C 12烷基 ，多环C 7 -C 10环烷基或可在苯基部分被1或2个选自卤素，甲氧基，乙氧基和C 1 -C 5烷基的相同或不同的成员取代的苯基（C 1 -C 5）烷基，R 2为氢或 C 1 -C 5烷基，R 3是C 1 -C 5烷基或C 3 -C 6环烷基，R 4是氢或C 1 -C 4烷基，R 5是含有1至4个选自N，O和S的杂原子的5元杂环基， 可以在碳原子或氮原子上被1至3个取代基R6，R7和R8取代，或者是可以与苯核稠合并且含有1或2个选自以下的杂原子的5元杂环基： 的N，O和S，并且可以在碳或氮原子上被1至3个取代 取代基R 6，R 7和R 8，R 6和R 7各自独立地为氢，卤素，C 1 -C 4烷基，卤素取代的C 1 -C 4烷基，C 1 -C 4烷氧基， 卤素取代的C1-C4烷氧基，苯基或C1-C4烷硫基，R8是氢或C1-C4烷基，R9是C1-C5烷基，C2-C5链烯基，C3-C4炔基，含有总共10个碳原子的烷氧基烷基，或含有 总共10个碳原子，并与其与酸和碱的盐反应。 本发明进一步涉及这些化合物的制备及其在病虫害防治中的应用，以及新颖的中间体。

    N-substituted tetrahydropyridines and their use as pesticides
    5.
    发明授权
    N-substituted tetrahydropyridines and their use as pesticides 失效
    N-取代四氢吡啶类及其作为农药的用途

    公开(公告)号：US06953811B2

    公开(公告)日：2005-10-11

    申请号：US10470790

    申请日：2002-02-04

    申请人： Stephan Trah ,  Josef Ehrenfreund ,  Peter Maienfisch ,  André Jeanguenat ,  Saleem Farooq

    发明人： Stephan Trah ,  Josef Ehrenfreund ,  Peter Maienfisch ,  André Jeanguenat ,  Saleem Farooq

    IPC分类号： A01N43/40 ,  C07D211/70 ,  C07D211/94 ,  C07D401/06

    CPC分类号： C07D401/06 ,  C07D211/70 ,  C07D211/94

    摘要： A description is given of compounds of the formula in which R1 and R2 independently of one another are halogen, C1-C6alkyl, halo-C1-C6alkyl, C1-C6alkoxy, halo-C1-C6alkoxy, or SF5, R3 is hydrogen, OH, halogen, C1-C6alkoxy or —O—C(═O)—C1-C6alkyl, R4 is for example hydrogen, halogen, C1-C6alkyl, halo-C1-C6alkyl, C1-C6alkoxy, halo-C1-C6alkoxy or SCN; R5 and R6 independently of one another are for example hydrogen, C1-C12alkyl, halo-C1-C12alkyl, C2-C12alkenyl, halo-C2-C12alkenyl or C2-C12alkynyl; and q is 0 or 1; and, where appropriate, E/Z isomers, E/Z isomer mixtures and/or tautomers, each in free form or in salt form; a process for the preparation of these compounds and their use, pesticide compositions whose active ingredient is selected from these compounds, or an agrochemically useable salt thereof, a process for preparing these compositions, and their use, plant propagation material treated with these compositions, and a method of combating pests.

    摘要翻译： 给出下式的化合物，其中R 1和R 2彼此独立地是卤素，C 1 -C 3 C 6 -C 6烷基，卤代C 1 -C 6烷基，C 1 -C 6烷基，C 1 -C 6烷基，C 1 -C 6烷基， 烷氧基，卤代-C 1 -C 6烷氧基或SF 5，R 3是氢，OH， 卤素，C 1 -C 6烷氧基或-OC（-O）-C 1 -C 6 -C 6烷基 R 4是例如氢，卤素，C 1 -C 6烷基，卤代C 1 -C 4烷基， C 1 -C 6烷基，C 1 -C 6烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6烷基， 烷氧基或SCN; R 5和R 6彼此独立地是例如氢，C 1 -C 12 - 烷基，卤代 C 1 -C 12烷基，C 2 -C 12链烯基，卤代-C 2烷基，C 1 -C 12烷基，C 2 -C 12 - C 12 -C 12链烯基或C 2 -C 12 - 炔基; q为0或1; 和/或互变异构体，各自为游离形式或盐形式的E / Z异构体，E / Z异构体混合物和/或互变异构体; 制备这些化合物及其用途的方法，其活性成分选自这些化合物的农药组合物或其农业上可用的盐，这些组合物的制备方法及其用途，用这些组合物处理的植物繁殖材料，以及 一种防治害虫的方法。

    Microbiocidal (E.G. fungicidal) 1,2,3-triazole derivatives
    8.
    发明授权
    Microbiocidal (E.G. fungicidal) 1,2,3-triazole derivatives 有权
    杀微生物剂（E.G.杀真菌剂）1,2,3-三唑衍生物

    公开(公告)号：US07956194B2

    公开(公告)日：2011-06-07

    申请号：US12463449

    申请日：2009-05-11

    申请人： Josef Ehrenfreund ,  Hans Tobler ,  Harald Walter

    发明人： Josef Ehrenfreund ,  Hans Tobler ,  Harald Walter

    IPC分类号： C07D403/00 ,  C07C211/60

    CPC分类号： C07D401/12 ,  A01N43/647 ,  A01N55/00 ,  C07D249/04 ,  C07D333/36 ,  C07D405/12 ,  C07D409/12 ,  C07D409/14 ,  C07D411/12 ,  C07D413/12 ,  C07D417/12 ,  C07D487/08 ,  C07D493/08 ,  C07D495/08

    摘要： A compound of formula (I): where A is an ortho-substituted ring selected from a number of specified rings; R1 is halogen, cyano, nitro, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 haloalkoxy or optionally substituted C2-4 alkenyl, optionally substituted C2-4 alkynyl or optionally substituted SO2(C1-4)alkyl (where the optionally substituted moieties may each have up to 3 substituents, each independently selected from halogen and C1-4 alkoxy); R2 is C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy(C1-4)alkyl or C1-4 alkylthio(C1-4)alkyl or [optionally substituted aryl](C1-4)alkyl- or [optionally substituted aryl]oxy(C1-4)alkyl-(where the optionally substituted aryl moieties may each have up to 3 substituents, each independently selected from halogen and C1-4 alkoxy); R3 is hydrogen, CH2C≡CR4, CH2CR4═C(H)R4, CH═C═CH2 or COR5 or optionally substituted C1-4 alkyl, optionally substituted C1-4 alkoxy or optionally substituted (C1-4) alkylC(═O)O (where the optionally substituted moieties may each have up to 3 substituents, each independently selected from halogen and C1-4 alkoxy, C1-4 alkyl, C1-2 haloalkoxy, hydroxy, cyano, carboxyl, methoxycarbonyl, ethoxycarbonyl, methylsulfonyl and ethylsulfonyl); each R4 is, independently, hydrogen, halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 alkoxy(C1-4)alkyl; and R5 is hydrogen or optionally substituted C1-6 alkyl, optionally substituted C1-4 alkoxy, optionally substituted C1-4 alkoxy(C1-4)alkyl, optionally substituted C1-4 alkylthio(C1-4)alkyl or optionally substituted aryl (where the optionally substituted moieties may each have up to 3 substituents, each independently selected from halogen, C1-6 alkoxy, C1-6 haloalkoxy, cyano, hydroxy, methoxycarbonyl and ethoxycarbonyl).

    摘要翻译： 式（I）的化合物：其中A是选自多个指定环的邻位取代的环; R 1是卤素，氰基，硝基，C 1-4烷基，C 1-4卤代烷基，C 1-4烷氧基或C 1-4卤代烷氧基或任选取代的C 2-4烯基，任选取代的C 2-4炔基或任选取代的SO 2（C 1-4） 烷基（其中任选取代的部分可各自具有至多3个取代基，各自独立地选自卤素和C 1-4烷氧基）; R 2是C 1-4烷基，C 1-4卤代烷基，C 1-4烷氧基（C 1-4）烷基或C 1-4烷硫基（C 1-4）烷基或[任意取代的芳基]（C 1-4）烷基 - 或[ 芳基]氧基（C 1-4）烷基 - （其中任选取代的芳基部分可各自具有至多3个取代基，各自独立地选自卤素和C 1-4烷氧基）; R 3是氢，CH 2C≡CR4，CH 2 CR 4 = C（H）R 4，CH = C = CH 2或COR 5或任选取代的C 1-4烷基，任选取代的C 1-4烷氧基或任选取代的（C 1-4）烷基C（= O（其中任选取代的部分可以各自具有至多3个取代基，各自独立地选自卤素和C 1-4烷氧基，C 1-4烷基，C 1-2卤代烷氧基，羟基，氰基，羧基，甲氧基羰基，乙氧基羰基，甲基磺酰基和乙基磺酰基） ; 每个R 4独立地是氢，卤素，C 1-4烷基，C 1-4卤代烷基，C 1-4烷氧基或C 1-4烷氧基（C 1-4）烷基; 并且R 5为氢或任选取代的C 1-6烷基，任选取代的C 1-4烷氧基，任选取代的C 1-4烷氧基（C 1-4）烷基，任选取代的C 1-4烷硫基（C 1-4）烷基或任选取代的芳基（其中 任选取代的部分各自可具有至多3个取代基，各自独立地选自卤素，C 1-6烷氧基，C 1-6卤代烷氧基，氰基，羟基，甲氧基羰基和乙氧基羰基）。

    Process for the production of anilines
    9.
    发明授权
    Process for the production of anilines 有权
    生产苯胺的方法

    公开(公告)号：US07737301B2

    公开(公告)日：2010-06-15

    申请号：US12065304

    申请日：2006-08-28

    申请人： Harald Walter ,  Camilla Corsi ,  Josef Ehrenfreund ,  Hans Tobler

    发明人： Harald Walter ,  Camilla Corsi ,  Josef Ehrenfreund ,  Hans Tobler

    IPC分类号： C07C209/62 ,  C07C209/10 ,  C07C211/45 ,  C07C211/48

    CPC分类号： C07C209/10 ,  C07C209/62 ,  C07C2601/02 ,  C07C211/45 ,  C07C211/48

    摘要： The present invention relates to a process for the preparation of compounds of formula wherein R1, R2 and R3 are each independently of the others hydrogen or C1-C4alkyl, by a) reacting compounds of formula (II) wherein R1, R2 and R3 are as defined for formula (I) and X is bromine or chlorine, with a compound of formula (III) wherein R4 is hydrogen or C1-C4alkyl, in the presence of a base and catalytic amounts of at least one palladium complex compound, to form compounds of formula (IV) wherein R1, R2, R3 and R4 are as defined for formula (I), and b) converting those compounds, using a reducing agent, into compounds of formula (I).

    摘要翻译： 本发明涉及制备下式化合物的方法，其中R 1，R 2和R 3各自独立地为氢或C 1 -C 4烷基，通过a）使式（Ⅱ）化合物（其中R 1，R 2和R 3为 与式（Ⅲ）化合物（其中R 4是氢或C 1 -C 4烷基）在碱和催化量的至少一种钯络合物的存在下形成化合物（I），X是溴或氯， 其中R 1，R 2，R 3和R 4如式（I）所定义，并且b）使用还原剂将这些化合物转化为式（I）化合物。

    Heterocyclic amide derivatives useful as microbiocides
    10.
    发明授权
    Heterocyclic amide derivatives useful as microbiocides 有权
    用作杀微生物剂的杂环酰胺衍生物

    公开(公告)号：US07732469B2

    公开(公告)日：2010-06-08

    申请号：US12091189

    申请日：2006-10-23

    申请人： Hans Tobler ,  Harald Walter ,  Josef Ehrenfreund ,  Camilla Corsi

    发明人： Hans Tobler ,  Harald Walter ,  Josef Ehrenfreund ,  Camilla Corsi

    IPC分类号： A01N43/78 ,  C07D277/56 ,  C07C205/11 ,  A01P1/00

    CPC分类号： C07C205/06 ,  A01N43/32 ,  A01N43/36 ,  A01N43/40 ,  A01N43/56 ,  A01N43/647 ,  A01N43/76 ,  A01N43/78 ,  C07C205/11 ,  C07C205/12 ,  C07C205/37 ,  C07C205/45 ,  C07C211/61 ,  C07C2603/66 ,  C07D207/34 ,  C07D207/46 ,  C07D213/89 ,  C07D231/14 ,  C07D249/04 ,  C07D263/34 ,  C07D277/56 ,  C07D327/06

    摘要： The invention relates to a fungicidally active compound of formula (I): where Het is a 5- or 6-membered heterocyclic ring containing one to three heteroatoms, each independently selected from oxygen, nitrogen and sulphur, the ring being substituted by the groups R6, R7 and R8; R1 is hydrogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy, C1-4 haloalkoxy, CH2 C≡CR9, CH2 CR10═CHR11, CH═C═CH2 or COR12; R2 and R3 are each, independently, hydrogen, halo, C1-4 alkyl, C1-4 alkoxy, C1-4 haloalkyl or C1-4 haloalkoxy; R4 and R5 are each independently selected from halo, cyano and nitro; or one of R4 and R5 is hydrogen and the other is selected from halo, cyano and nitro; R6, R7 and R8 are each, independently, hydrogen, halo, cyano, nitro, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy(C1-4)alkyl, C1-4 haloalkoxy(C1-4)alkyl or C1-4 haloalkoxy, provided that at least one of R6, R7 and R8 is not hydrogen; R9, R10 and R11 are each, independently, hydrogen, halo, C1-4 alkyl, C1-4 haloalkyl or C1-4 alkoxy(C1-4)alkyl; and R12 is hydrogen, C1-6 alkyl, C1-6 haloalkyl, C1-4 alkoxy(C1-4)alkyl, C1-4 alkylthio(C1-4)-alkyl, C1-4 alkoxy or aryl; to the preparation of these compounds, to novel intermediates used in the preparation of these compounds, to agrochemical compositions which comprise at least one of the novel compounds as active ingredient, to the preparation of the compositions mentioned and to the use of the active ingredients or compositions in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.

    摘要翻译： 本发明涉及式（I）的杀真菌活性化合物：其中Het是含有一至三个杂原子的5-或6-元杂环，各自独立地选自氧，氮和硫，该环被R6基团取代 ，R7和R8; R 1是氢，C 1-4烷基，C 1-4卤代烷基，C 1-4烷氧基，C 1-4卤代烷氧基，CH 2C≡CR9，CH 2 CR 10 = CHR 11，CH = C = CH 2或COR 12; R 2和R 3各自独立地为氢，卤素，C 1-4烷基，C 1-4烷氧基，C 1-4卤代烷基或C 1-4卤代烷氧基; R4和R5各自独立地选自卤素，氰基和硝基; 或者R4和R5之一是氢，另一个选自卤素，氰基和硝基; R 6，R 7和R 8各自独立地为氢，卤素，氰基，硝基，C 1-4烷基，C 1-4卤代烷基，C 1-4烷氧基（C 1-4）烷基，C 1-4卤代烷氧基（C 1-4）烷基或 C 1-4卤代烷氧基，条件是R 6，R 7和R 8中的至少一个不是氢; R 9，R 10和R 11各自独立地为氢，卤素，C 1-4烷基，C 1-4卤代烷基或C 1-4烷氧基（C 1-4）烷基; 和R 12是氢，C 1-6烷基，C 1-6卤代烷基，C 1-4烷氧基（C 1-4）烷基，C 1-4烷硫基（C 1-4） - 烷基，C 1-4烷氧基或芳基; 涉及这些化合物的制备，用于制备这些化合物的新型中间体，包括至少一种新化合物作为活性成分的农用化学组合物，所述组合物的制备以及使用活性成分或 用于通过植物病原微生物，优选真菌控制或预防植物感染的农业或园艺成分。